Investigation on Mass Spectral Fragmentation Mechanism of C2-Symmetric Chiral Bis(oxazoline) and Bis(thiazoline)

The electron impact mass spectra of ten new C2‐symmetric chiral bis(oxazoline) and bis(thiazoline) have been studied. Bis(thiazoline) and bis(oxazoline) possess the same fragmentation mechanism under EI conditions. An unusual fragmentation pathway has been found in the compounds studied. Due to the...

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Veröffentlicht in:Chinese journal of chemistry 2005-06, Vol.23 (6), p.720-724
Hauptverfasser: Hui, Chen, Da-Ming, Du, Bin, Fu, Mei-Yu, He
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creator Hui, Chen
Da-Ming, Du
Bin, Fu
Mei-Yu, He
description The electron impact mass spectra of ten new C2‐symmetric chiral bis(oxazoline) and bis(thiazoline) have been studied. Bis(thiazoline) and bis(oxazoline) possess the same fragmentation mechanism under EI conditions. An unusual fragmentation pathway has been found in the compounds studied. Due to the presence of phenyl group, compounds 6 and 10 undergo a new fragmentation pathway except for the common way as the other eight compounds. Mass analyzed ion kinetic energy spectra experiments and high resolution accurate mass measurement were conducted to confirm the proposed fragmentation pathways.
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subjects bis(oxazoline)
bis(thiazoline)
fragmentation
high resolution accurate mass
mass analyzed ion kinetic energy spectra
title Investigation on Mass Spectral Fragmentation Mechanism of C2-Symmetric Chiral Bis(oxazoline) and Bis(thiazoline)
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