$Asymmetrical Platinum and Rhodium Dinuclear Complex Strongly Bound to Filled d z2 ${{_{{\rm z}{^{2}}}}}$ Complexes by Unbridged Pt−Metal Bonds: Toward Heterometallic‐Extended Metal Atom Chains$

Asymmetrical Platinum and Rhodium Dinuclear Complex Strongly Bound to Filled d z2 ${{_{{\rm z}{^{2}}}}}$ Complexes by Unbridged Pt−Metal Bonds: Toward Heterometallic‐Extended Metal Atom Chains

Heterometallic extended metal atom chains (EMACs) aligned with three types of metal were rationally synthesized by forming unbridged metal−metal bonds based on the interactions between highest occupied and lowest unoccupied molecular orbitals at the d z2 ${{_{{\rm z}{^{2}}}$ orbital. These chains fo...

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Veröffentlicht in:	Chemistry : a European journal 2023-03, Vol.29 (16), p.n/a
Hauptverfasser:	Uemura, Kazuhiro, Ikeda, Yuya, Takamori, Atsushi, Takeyama, Tomoyuki, Iwatsuki, Satoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	chain structures donor-acceptor systems heterometallic complexes metal−metal interactions platinum
Online-Zugang:	Volltext
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