A Combined Spectroscopic, Photophysical and Theoretical (DFT) Study of the Electronically Excited Inorganometallic Complexes [Ru(E)(E′)(CO)2(iPr-DAB)] (ECl, Me, SnPh3, PbPh3; E′GePh3, SnR3, PbR3 (RMe, Ph); iPr-DAB=N,N'-diisopropyl-1,4-diaza-1,3-butadiene): Evidence of an Exceptionally Long-Lived 3σπ Excited State for [Ru(SnPh3)2(CO)2(iPr-DAB)]

The photophysical properties of the metal–metal bonded complexes [Ru‐(E)(E′)(CO)2(iPr–DAB)] (ECl, E′SnPh3, PbPh3; EMe, E′SnPh3, PbPh3; ESnPh3, E′SnMe3, SnPh3, GePh3; EPbPh3, E′PbMe3, PbPh3, GePh3; iPr–DAB=N,N'‐diisopropyl‐1,4‐diaza‐1,3‐butadiene) have been studied. According to time‐res...

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Veröffentlicht in:	Chemistry : a European journal 1996-12, Vol.2 (12), p.1556-1565
Hauptverfasser:	Aarnts, Maxim P., Stufkens, Derk J., Wilms, Maikel P., Baerends, Evert Jan, Vlček Jr, Antonín, Clark, Ian P., George, Michael W., Turner, James J.
Format:	Artikel
Sprache:	eng
Schlagworte:	density functional calculations IR spectroscopy ruthenium complexes time-resolved spectroscopy vis spectroscopy
Online-Zugang:	Volltext
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