Kohlenwasserstoffverbrückte Metallkomplexe, XXII1) Addition von anionischen Fischer‐Carben‐Komplexen an koordinierte ungesättigte Kohlenwasserstoffe unter C – C‐Kupplung
Hydrocarbon‐Bridged Metal Complexes, XXII1). – Addition of Anionic Fischer Carbene Complexes to Coordinated Unsaturated Hydrocarbons with C – C Coupling The addition of [(OC)5MC(OMe)CH2]– (M = Cr,W) to the cationic complexes [(OC)5Re(C2H4)]+ and [(OC)3M' (λ7‐C7H7)]+ (M' = Cr, Mo) affords t...
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Veröffentlicht in: | Chemische Berichte 1991-11, Vol.124 (11), p.2431-2434 |
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creator | Breimair, Josef Weidmann, Torsten Wagner, Barbara Beck, Wolfgang |
description | Hydrocarbon‐Bridged Metal Complexes, XXII1). – Addition of Anionic Fischer Carbene Complexes to Coordinated Unsaturated Hydrocarbons with C – C Coupling
The addition of [(OC)5MC(OMe)CH2]– (M = Cr,W) to the cationic complexes [(OC)5Re(C2H4)]+ and [(OC)3M' (λ7‐C7H7)]+ (M' = Cr, Mo) affords the bimetallic hydrocarbon‐bridged complexes (OC)5M = C(OMe)CH2CH2CH2Re(CO)5 (1) and (OC)5M = C(OMe)CH2C7H7 – λ6 – M'(CO)3 (2), respectively. The structures of 1a and 2d have been determined by X‐ray diffraction. |
doi_str_mv | 10.1002/cber.19911241110 |
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The addition of [(OC)5MC(OMe)CH2]– (M = Cr,W) to the cationic complexes [(OC)5Re(C2H4)]+ and [(OC)3M' (λ7‐C7H7)]+ (M' = Cr, Mo) affords the bimetallic hydrocarbon‐bridged complexes (OC)5M = C(OMe)CH2CH2CH2Re(CO)5 (1) and (OC)5M = C(OMe)CH2C7H7 – λ6 – M'(CO)3 (2), respectively. The structures of 1a and 2d have been determined by X‐ray diffraction.</description><identifier>ISSN: 0009-2940</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/cber.19911241110</identifier><language>eng</language><publisher>Weinheim: WILEY‐VCH Verlag</publisher><subject>Carbene, methoxy(pentacarbonylrheniopropyl) ; Chromium complexes ; Fischer carbene complexes, anionic ; Molybdenum complexes ; Rhenium complexes ; Tungsten complexes</subject><ispartof>Chemische Berichte, 1991-11, Vol.124 (11), p.2431-2434</ispartof><rights>Copyright © 1991 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcber.19911241110$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcber.19911241110$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Breimair, Josef</creatorcontrib><creatorcontrib>Weidmann, Torsten</creatorcontrib><creatorcontrib>Wagner, Barbara</creatorcontrib><creatorcontrib>Beck, Wolfgang</creatorcontrib><title>Kohlenwasserstoffverbrückte Metallkomplexe, XXII1) Addition von anionischen Fischer‐Carben‐Komplexen an koordinierte ungesättigte Kohlenwasserstoffe unter C – C‐Kupplung</title><title>Chemische Berichte</title><description>Hydrocarbon‐Bridged Metal Complexes, XXII1). – Addition of Anionic Fischer Carbene Complexes to Coordinated Unsaturated Hydrocarbons with C – C Coupling
The addition of [(OC)5MC(OMe)CH2]– (M = Cr,W) to the cationic complexes [(OC)5Re(C2H4)]+ and [(OC)3M' (λ7‐C7H7)]+ (M' = Cr, Mo) affords the bimetallic hydrocarbon‐bridged complexes (OC)5M = C(OMe)CH2CH2CH2Re(CO)5 (1) and (OC)5M = C(OMe)CH2C7H7 – λ6 – M'(CO)3 (2), respectively. The structures of 1a and 2d have been determined by X‐ray diffraction.</description><subject>Carbene, methoxy(pentacarbonylrheniopropyl)</subject><subject>Chromium complexes</subject><subject>Fischer carbene complexes, anionic</subject><subject>Molybdenum complexes</subject><subject>Rhenium complexes</subject><subject>Tungsten complexes</subject><issn>0009-2940</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqlUL1OwzAYtBBIhJ-d0SsSLZ-TqOCBAaJWVBULYugWOcmX1sR1Ittt6dZHQOIVeANWtr5JnwQHdajEyPDp7qS706cj5IJBlwGE13mGpss4ZyyMGWNwQAIGnHegdxsekgAAeCfkMRyTE2tfAaL4phcF5GtUTxXqpbAWjXV1WS7QZGbznVcO6RM6oVRVzxqFb3hFx-PhkF3S-6KQTtaaLvwJ7Zm0-RQ1Hfyi2a7fE2Ey1J6MduHWSKu6NoXUEo0vn-sJ2s2nc3Li1Z8_WoNDQxO6XX_QpK2aN43yqTNyVApl8XyHp-Ru0H9JHjtLqXCVNkbOhFmlDNJ2mbRdJt1bJk0e-s97Ovpv_gd5K30m</recordid><startdate>199111</startdate><enddate>199111</enddate><creator>Breimair, Josef</creator><creator>Weidmann, Torsten</creator><creator>Wagner, Barbara</creator><creator>Beck, Wolfgang</creator><general>WILEY‐VCH Verlag</general><scope/></search><sort><creationdate>199111</creationdate><title>Kohlenwasserstoffverbrückte Metallkomplexe, XXII1) Addition von anionischen Fischer‐Carben‐Komplexen an koordinierte ungesättigte Kohlenwasserstoffe unter C – C‐Kupplung</title><author>Breimair, Josef ; Weidmann, Torsten ; Wagner, Barbara ; Beck, Wolfgang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-wiley_primary_10_1002_cber_19911241110_CBER199112411103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1991</creationdate><topic>Carbene, methoxy(pentacarbonylrheniopropyl)</topic><topic>Chromium complexes</topic><topic>Fischer carbene complexes, anionic</topic><topic>Molybdenum complexes</topic><topic>Rhenium complexes</topic><topic>Tungsten complexes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Breimair, Josef</creatorcontrib><creatorcontrib>Weidmann, Torsten</creatorcontrib><creatorcontrib>Wagner, Barbara</creatorcontrib><creatorcontrib>Beck, Wolfgang</creatorcontrib><jtitle>Chemische Berichte</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Breimair, Josef</au><au>Weidmann, Torsten</au><au>Wagner, Barbara</au><au>Beck, Wolfgang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Kohlenwasserstoffverbrückte Metallkomplexe, XXII1) Addition von anionischen Fischer‐Carben‐Komplexen an koordinierte ungesättigte Kohlenwasserstoffe unter C – C‐Kupplung</atitle><jtitle>Chemische Berichte</jtitle><date>1991-11</date><risdate>1991</risdate><volume>124</volume><issue>11</issue><spage>2431</spage><epage>2434</epage><pages>2431-2434</pages><issn>0009-2940</issn><eissn>1099-0682</eissn><abstract>Hydrocarbon‐Bridged Metal Complexes, XXII1). – Addition of Anionic Fischer Carbene Complexes to Coordinated Unsaturated Hydrocarbons with C – C Coupling
The addition of [(OC)5MC(OMe)CH2]– (M = Cr,W) to the cationic complexes [(OC)5Re(C2H4)]+ and [(OC)3M' (λ7‐C7H7)]+ (M' = Cr, Mo) affords the bimetallic hydrocarbon‐bridged complexes (OC)5M = C(OMe)CH2CH2CH2Re(CO)5 (1) and (OC)5M = C(OMe)CH2C7H7 – λ6 – M'(CO)3 (2), respectively. The structures of 1a and 2d have been determined by X‐ray diffraction.</abstract><cop>Weinheim</cop><pub>WILEY‐VCH Verlag</pub><doi>10.1002/cber.19911241110</doi><tpages>4</tpages></addata></record> |
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source | Wiley Online Library Journals Frontfile Complete |
subjects | Carbene, methoxy(pentacarbonylrheniopropyl) Chromium complexes Fischer carbene complexes, anionic Molybdenum complexes Rhenium complexes Tungsten complexes |
title | Kohlenwasserstoffverbrückte Metallkomplexe, XXII1) Addition von anionischen Fischer‐Carben‐Komplexen an koordinierte ungesättigte Kohlenwasserstoffe unter C – C‐Kupplung |
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