Kohlenwasserstoffverbrückte Metallkomplexe, XXII1) Addition von anionischen Fischer‐Carben‐Komplexen an koordinierte ungesättigte Kohlenwasserstoffe unter C – C‐Kupplung

Hydrocarbon‐Bridged Metal Complexes, XXII1). – Addition of Anionic Fischer Carbene Complexes to Coordinated Unsaturated Hydrocarbons with C – C Coupling The addition of [(OC)5MC(OMe)CH2]– (M = Cr,W) to the cationic complexes [(OC)5Re(C2H4)]+ and [(OC)3M' (λ7‐C7H7)]+ (M' = Cr, Mo) affords t...

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Veröffentlicht in:Chemische Berichte 1991-11, Vol.124 (11), p.2431-2434
Hauptverfasser: Breimair, Josef, Weidmann, Torsten, Wagner, Barbara, Beck, Wolfgang
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creator Breimair, Josef
Weidmann, Torsten
Wagner, Barbara
Beck, Wolfgang
description Hydrocarbon‐Bridged Metal Complexes, XXII1). – Addition of Anionic Fischer Carbene Complexes to Coordinated Unsaturated Hydrocarbons with C – C Coupling The addition of [(OC)5MC(OMe)CH2]– (M = Cr,W) to the cationic complexes [(OC)5Re(C2H4)]+ and [(OC)3M' (λ7‐C7H7)]+ (M' = Cr, Mo) affords the bimetallic hydrocarbon‐bridged complexes (OC)5M = C(OMe)CH2CH2CH2Re(CO)5 (1) and (OC)5M = C(OMe)CH2C7H7 – λ6 – M'(CO)3 (2), respectively. The structures of 1a and 2d have been determined by X‐ray diffraction.
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source Wiley Online Library Journals Frontfile Complete
subjects Carbene, methoxy(pentacarbonylrheniopropyl)
Chromium complexes
Fischer carbene complexes, anionic
Molybdenum complexes
Rhenium complexes
Tungsten complexes
title Kohlenwasserstoffverbrückte Metallkomplexe, XXII1) Addition von anionischen Fischer‐Carben‐Komplexen an koordinierte ungesättigte Kohlenwasserstoffe unter C – C‐Kupplung
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