Dirhenioethin (OC)5Re–CC–Re(CO)5 als Baustein zum Aufbau von Carbonyl‐Metall‐Clusterverbindungen
Dirhenioethyne (OC)5Re–CC–Re(CO)5 as Building Block for the Synthesis of Carbonyl Metal Clusters The dimetallated ethyne (OC)5Re–CC–Re(CO)5 (1) reacts with (Ph3P)2Pt(η2‐C2H4), Fe2(CO)9, and Co2(CO)8 to give the acetylide‐bridged complexes PtRe2(μ3‐η1:η1:η2‐CC)(CO)9‐(PPh3)2 (2), FeRe2(μ3‐μ1:η1:η2‐...
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| Veröffentlicht in: | Chemische Berichte 1991-06, Vol.124 (6), p.1363-1368 |
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| container_title | Chemische Berichte |
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| creator | Weidmann, Torsten Weinrich, Volker Wagner, Barbara Robl, Christian Beck, Wolfgang |
| description | Dirhenioethyne (OC)5Re–CC–Re(CO)5 as Building Block for the Synthesis of Carbonyl Metal Clusters
The dimetallated ethyne (OC)5Re–CC–Re(CO)5 (1) reacts with (Ph3P)2Pt(η2‐C2H4), Fe2(CO)9, and Co2(CO)8 to give the acetylide‐bridged complexes PtRe2(μ3‐η1:η1:η2‐CC)(CO)9‐(PPh3)2 (2), FeRe2(μ3‐μ1:η1:η2‐CC)(CO)13 (3), and Co2Re2‐(μ4‐η1:η1:η2:η2‐CC)(CO)14 (4), resp., whose structures have been determined by X‐ray diffraction. These reactions of (CO)5Re–CC–Re(CO)5 proceed similarly to those of the isolobal organic acetylenes, but with formation of metal‐metal bonds. |
| doi_str_mv | 10.1002/cber.19911240609 |
| format | Article |
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The dimetallated ethyne (OC)5Re–CC–Re(CO)5 (1) reacts with (Ph3P)2Pt(η2‐C2H4), Fe2(CO)9, and Co2(CO)8 to give the acetylide‐bridged complexes PtRe2(μ3‐η1:η1:η2‐CC)(CO)9‐(PPh3)2 (2), FeRe2(μ3‐μ1:η1:η2‐CC)(CO)13 (3), and Co2Re2‐(μ4‐η1:η1:η2:η2‐CC)(CO)14 (4), resp., whose structures have been determined by X‐ray diffraction. These reactions of (CO)5Re–CC–Re(CO)5 proceed similarly to those of the isolobal organic acetylenes, but with formation of metal‐metal bonds.</description><identifier>ISSN: 0009-2940</identifier><identifier>EISSN: 1099-0682</identifier><identifier>DOI: 10.1002/cber.19911240609</identifier><language>eng ; jpn</language><publisher>Weinheim: WILEY‐VCH Verlag</publisher><subject>Acetylide‐bridged carbonyl metal clusters ; Cobalt carbonyl complexes ; Iron carbonyl complexes ; Platinum carbonyl complexes ; μ‐(Ethynediyl)bis(pentacarbonylrhenium)</subject><ispartof>Chemische Berichte, 1991-06, Vol.124 (6), p.1363-1368</ispartof><rights>Copyright © 1991 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1679-f9a83c63ede432205243be536c166ed5e5e35e085f14e85a98279d0b4e3da8623</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcber.19911240609$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcber.19911240609$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27903,27904,45553,45554</link.rule.ids></links><search><creatorcontrib>Weidmann, Torsten</creatorcontrib><creatorcontrib>Weinrich, Volker</creatorcontrib><creatorcontrib>Wagner, Barbara</creatorcontrib><creatorcontrib>Robl, Christian</creatorcontrib><creatorcontrib>Beck, Wolfgang</creatorcontrib><title>Dirhenioethin (OC)5Re–CC–Re(CO)5 als Baustein zum Aufbau von Carbonyl‐Metall‐Clusterverbindungen</title><title>Chemische Berichte</title><description>Dirhenioethyne (OC)5Re–CC–Re(CO)5 as Building Block for the Synthesis of Carbonyl Metal Clusters
The dimetallated ethyne (OC)5Re–CC–Re(CO)5 (1) reacts with (Ph3P)2Pt(η2‐C2H4), Fe2(CO)9, and Co2(CO)8 to give the acetylide‐bridged complexes PtRe2(μ3‐η1:η1:η2‐CC)(CO)9‐(PPh3)2 (2), FeRe2(μ3‐μ1:η1:η2‐CC)(CO)13 (3), and Co2Re2‐(μ4‐η1:η1:η2:η2‐CC)(CO)14 (4), resp., whose structures have been determined by X‐ray diffraction. These reactions of (CO)5Re–CC–Re(CO)5 proceed similarly to those of the isolobal organic acetylenes, but with formation of metal‐metal bonds.</description><subject>Acetylide‐bridged carbonyl metal clusters</subject><subject>Cobalt carbonyl complexes</subject><subject>Iron carbonyl complexes</subject><subject>Platinum carbonyl complexes</subject><subject>μ‐(Ethynediyl)bis(pentacarbonylrhenium)</subject><issn>0009-2940</issn><issn>1099-0682</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpNkDtOw0AYhFcIJEKgp3SZFA7_PuMtKJIlPKSgSBHU1jr-TQzOBq3joFDlCEgcgXNwmVyAK2ALilQzoxlN8RFyTqFHAdjFLEHfo1pTygQo0AekRUHrEFTEDkkLAHTItIBjclKWzwBc9BVvkZer3M_R5UtczXMXdCamK6e4236an69vU-sUO2bSlYEtymBoq3KF9ey9WgSDKktsFayXLjDWJ0u3KXbbj3tc2aIxpmi2fo0-yV1auSd0p-Qoq2_w7F_b5PF69GBuw_Hk5s4MxuGMqr4OM20jPlMcUxScMZBM8AQlV3WtMJUokUuESGZUYCStjlhfp5AI5KmNFONtcvn3-5YXuIlffb6wfhNTiBtScUMq3iMVm-Foupf5L0F0ZOE</recordid><startdate>199106</startdate><enddate>199106</enddate><creator>Weidmann, Torsten</creator><creator>Weinrich, Volker</creator><creator>Wagner, Barbara</creator><creator>Robl, Christian</creator><creator>Beck, Wolfgang</creator><general>WILEY‐VCH Verlag</general><scope/></search><sort><creationdate>199106</creationdate><title>Dirhenioethin (OC)5Re–CC–Re(CO)5 als Baustein zum Aufbau von Carbonyl‐Metall‐Clusterverbindungen</title><author>Weidmann, Torsten ; Weinrich, Volker ; Wagner, Barbara ; Robl, Christian ; Beck, Wolfgang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1679-f9a83c63ede432205243be536c166ed5e5e35e085f14e85a98279d0b4e3da8623</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>1991</creationdate><topic>Acetylide‐bridged carbonyl metal clusters</topic><topic>Cobalt carbonyl complexes</topic><topic>Iron carbonyl complexes</topic><topic>Platinum carbonyl complexes</topic><topic>μ‐(Ethynediyl)bis(pentacarbonylrhenium)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Weidmann, Torsten</creatorcontrib><creatorcontrib>Weinrich, Volker</creatorcontrib><creatorcontrib>Wagner, Barbara</creatorcontrib><creatorcontrib>Robl, Christian</creatorcontrib><creatorcontrib>Beck, Wolfgang</creatorcontrib><jtitle>Chemische Berichte</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Weidmann, Torsten</au><au>Weinrich, Volker</au><au>Wagner, Barbara</au><au>Robl, Christian</au><au>Beck, Wolfgang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dirhenioethin (OC)5Re–CC–Re(CO)5 als Baustein zum Aufbau von Carbonyl‐Metall‐Clusterverbindungen</atitle><jtitle>Chemische Berichte</jtitle><date>1991-06</date><risdate>1991</risdate><volume>124</volume><issue>6</issue><spage>1363</spage><epage>1368</epage><pages>1363-1368</pages><issn>0009-2940</issn><eissn>1099-0682</eissn><abstract>Dirhenioethyne (OC)5Re–CC–Re(CO)5 as Building Block for the Synthesis of Carbonyl Metal Clusters
The dimetallated ethyne (OC)5Re–CC–Re(CO)5 (1) reacts with (Ph3P)2Pt(η2‐C2H4), Fe2(CO)9, and Co2(CO)8 to give the acetylide‐bridged complexes PtRe2(μ3‐η1:η1:η2‐CC)(CO)9‐(PPh3)2 (2), FeRe2(μ3‐μ1:η1:η2‐CC)(CO)13 (3), and Co2Re2‐(μ4‐η1:η1:η2:η2‐CC)(CO)14 (4), resp., whose structures have been determined by X‐ray diffraction. These reactions of (CO)5Re–CC–Re(CO)5 proceed similarly to those of the isolobal organic acetylenes, but with formation of metal‐metal bonds.</abstract><cop>Weinheim</cop><pub>WILEY‐VCH Verlag</pub><doi>10.1002/cber.19911240609</doi><tpages>6</tpages></addata></record> |
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| ispartof | Chemische Berichte, 1991-06, Vol.124 (6), p.1363-1368 |
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| language | eng ; jpn |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Acetylide‐bridged carbonyl metal clusters Cobalt carbonyl complexes Iron carbonyl complexes Platinum carbonyl complexes μ‐(Ethynediyl)bis(pentacarbonylrhenium) |
| title | Dirhenioethin (OC)5Re–CC–Re(CO)5 als Baustein zum Aufbau von Carbonyl‐Metall‐Clusterverbindungen |
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