Metal–Ligand Cooperativity of the Calix[4]pyrrolato Aluminate: Triggerable C−C Bond Formation and Rate Control in Catalysis

Metal‐ligand cooperativity (MLC) had a remarkable impact on transition metal chemistry and catalysis. By use of the calix[4]pyrrolato aluminate, [1]−, which features a square‐planar AlIII, we transfer this concept into the p‐block and fully elucidate its mechanisms by experiment and theory. Compleme...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-09, Vol.59 (39), p.17118-17124
Hauptverfasser:	Ebner, Fabian, Sigmund, Lukas Maximilian, Greb, Lutz
Format:	Artikel
Sprache:	eng
Schlagworte:	aluminum calixpyrrole Chemistry Chemistry, Multidisciplinary dynamic covalent chemistry metal-ligand cooperativity Physical Sciences Science & Technology structural constraint
Online-Zugang:	Volltext
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