Bromide-Assisted Oxidation of Substituted Phenols with Hydrogen Peroxide to the Corresponding p-Quinol and p-Quinol Ethers over WO42−-Exchanged Layered Double Hydroxides
A simple and efficient one‐pot synthesis of p‐quinols and their ethers occurs over tungstate‐exchanged layered double hydroxides (WO42−‐LDHs), which catalyze the bromide‐assisted oxidation of substituted phenols to the corresponding 4‐alkoxy‐ and 4‐hydroxycyclohexa‐2,5‐dienones in high yields (see s...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2005-01, Vol.44 (2), p.310-313 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Sels, B. F. De Vos, D. E. Jacobs, P. A. |
| description | A simple and efficient one‐pot synthesis of p‐quinols and their ethers occurs over tungstate‐exchanged layered double hydroxides (WO42−‐LDHs), which catalyze the bromide‐assisted oxidation of substituted phenols to the corresponding 4‐alkoxy‐ and 4‐hydroxycyclohexa‐2,5‐dienones in high yields (see scheme). |
| doi_str_mv | 10.1002/anie.200461555 |
| format | Article |
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A.</creatorcontrib><title>Bromide-Assisted Oxidation of Substituted Phenols with Hydrogen Peroxide to the Corresponding p-Quinol and p-Quinol Ethers over WO42−-Exchanged Layered Double Hydroxides</title><title>Angewandte Chemie International Edition</title><addtitle>Angewandte Chemie International Edition</addtitle><description>A simple and efficient one‐pot synthesis of p‐quinols and their ethers occurs over tungstate‐exchanged layered double hydroxides (WO42−‐LDHs), which catalyze the bromide‐assisted oxidation of substituted phenols to the corresponding 4‐alkoxy‐ and 4‐hydroxycyclohexa‐2,5‐dienones in high yields (see scheme).</description><subject>heterogeneous catalysis</subject><subject>hydroxycyclohexadienones</subject><subject>oxidation</subject><subject>peroxides</subject><subject>tungsten</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><recordid>eNpFkE1OwzAQhSMEEr9b1r6AIY5_uyyltEilBfG3tJx40hpKXNkptDdgzTW4FSchUVFZzTzN--ZJL0lOSXpG0jQ7N5WDsyxNmSCc853kgPCMYCol3W12RimWipP95DDGl8avVCoOku-L4N-cBdyN0cUaLJqsnDW18xXyJbpf5rF29bI93M6g8vOIPlw9Q8O1DX4KFbqF4BsCUO1RPQPU8yFAXPjKumqKFvhu6RoKmcr-i35jDBH5dwjoecKyn88v3F8VM1NNm5yRWUNo5qVf5nPYJLUJ8TjZK808wsnfPEoer_oPvSEeTQbXve4IOyIpx7yETAiWdTIlqBGWZQUDmUuipKHMmLzMoegUQjFVqBwIN6VloiwEswbyTkmPks7m74ebw1ovgnszYa1Jqtuedduz3vasu-Pr_lY1LN6wbZmrLWvCqxaSSq6fxwN9Q9T4iY2f9JD-AqWPiK0</recordid><startdate>20050101</startdate><enddate>20050101</enddate><creator>Sels, B. 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| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | heterogeneous catalysis hydroxycyclohexadienones oxidation peroxides tungsten |
| title | Bromide-Assisted Oxidation of Substituted Phenols with Hydrogen Peroxide to the Corresponding p-Quinol and p-Quinol Ethers over WO42−-Exchanged Layered Double Hydroxides |
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