In7Cl9-A New "Old" Compound in the System In-Cl
Neither In3Cl4 nor In4Cl5 accurately defines a phase whose existence was predicted by thermoanalytic methods. In fact a more apt formula is In7Cl9, for the phase which is prepared from InCl/InCl3 mixtures by sintering for 14 days at 220–250°C. The structure of the compound (part of which is shown on...
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| Veröffentlicht in: | Angewandte Chemie International Edition 1991-07, Vol.30 (7), p.824-825 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Beck, Horst Philipp Wilhelm, Doris |
| description | Neither In3Cl4 nor In4Cl5 accurately defines a phase whose existence was predicted by thermoanalytic methods. In fact a more apt formula is In7Cl9, for the phase which is prepared from InCl/InCl3 mixtures by sintering for 14 days at 220–250°C. The structure of the compound (part of which is shown on the right—In: small circles; Cl: large circles) reveals interesting crystallographic relationships to that of α‐InCl and is important in the discussion on stereochemical activity of cations with ns2 configuration. |
| doi_str_mv | 10.1002/anie.199108241 |
| format | Article |
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| title | In7Cl9-A New "Old" Compound in the System In-Cl |
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