Stereochemistry of Polymerization

Isotactic and syndiotactic polymers are stereoregular structures obtained in the polymerization of propene and other carbon–carbon double bond monomers. Atactic polymer is the irregular structure. Stereoregular polymers are more crystalline, stronger, and more useful polymers than atactic polymers....

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Format:	Buchkapitel
Sprache:	eng
Schlagworte:	atactic Bernoullian model catalyst site control chain transfer cis commercial polymers configuration coordination mechanism diastereotopic dyad enantiotopic homotopic initiator symmetry (C2n, C2, meso‐CS, CS, C1) isoselective isotactic Markov model metallocene initiator polymer chain end control post‐metallocene initiator statistical propagation models stereocenter stereoregular polymer stereoselective polymerization syndioselective syndiotactic termination trans triad Ziegler–Natta initiator
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