On dielectric saturation modeling in a continuum solvent

The linear Poisson-Boltzmann equation is solved with a variable dielectric constant to account for dielectric saturation. Two different spatially dependent forms of the dielectric constant are compared. It is shown that the electrostatic repulsion between two flat plates is decreased by dielectric s...

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Veröffentlicht in:Journal of colloid and interface science 1992-11, Vol.154 (1), p.289-294
Hauptverfasser: Curry, Joan E, McQuarrie, Donald A
Format: Artikel
Sprache:eng
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Zusammenfassung:The linear Poisson-Boltzmann equation is solved with a variable dielectric constant to account for dielectric saturation. Two different spatially dependent forms of the dielectric constant are compared. It is shown that the electrostatic repulsion between two flat plates is decreased by dielectric saturation and that it depends in a complicated way on both the dielectric constant and the electric field.
ISSN:0021-9797
1095-7103
DOI:10.1016/0021-9797(92)90102-R