Nephelium lappaceum Extract as an Organic Inhibitor to Control the Corrosion of Carbon Steel Weldment in the Acidic Environment
Organic inhibitors have been considered as an effective way to control the corrosion of carbon steel weldment in an acidic environment. This work proposes a new green organic inhibitor made of extract of rambutan fruit (Nephelium lappaceum) peel and aims at analyzing its corrosion inhibitor properti...
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| Veröffentlicht in: | Sustainability 2021-11, Vol.13 (21), p.12135, Article 12135 |
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| creator | Gapsari, Femiana Darmadi, Djarot B. Setyarini, Putu H. Izzuddin, Hubby Madurani, Kartika A. Tanji, Ayoub Hermawan, Hendra |
| description | Organic inhibitors have been considered as an effective way to control the corrosion of carbon steel weldment in an acidic environment. This work proposes a new green organic inhibitor made of extract of rambutan fruit (Nephelium lappaceum) peel and aims at analyzing its corrosion inhibitor properties and protection mechanism. Specimens of carbon steel weldment were tested for their corrosion by using electrochemical and immersion methods in 1 M HCl solution containing 0 to 6 g/L of Nephelium peel (NP) extract. Results showed that, in the same solution, the corrosion rate was measured to be higher on the weld metal zone than that of base metal zone, which could be related to the coarser grain of the weld metal zone and the stability of the formed oxide layer. The addition of NP extract was found to increase the stability of the oxide layer, thus increasing the corrosion resistance of the specimens. The maximum inhibition efficiency of the NP extract was reached at 97% for weld metal with 5 g/L of extract, at 80% for the heat affected zone with 5 g/L, and at 70% for base metal with 4 g/L. This work reveals the particularity of different weldment zones to the different needs of inhibitor concentration for obtaining the optimum corrosion protection. |
| doi_str_mv | 10.3390/su132112135 |
| format | Article |
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This work proposes a new green organic inhibitor made of extract of rambutan fruit (Nephelium lappaceum) peel and aims at analyzing its corrosion inhibitor properties and protection mechanism. Specimens of carbon steel weldment were tested for their corrosion by using electrochemical and immersion methods in 1 M HCl solution containing 0 to 6 g/L of Nephelium peel (NP) extract. Results showed that, in the same solution, the corrosion rate was measured to be higher on the weld metal zone than that of base metal zone, which could be related to the coarser grain of the weld metal zone and the stability of the formed oxide layer. The addition of NP extract was found to increase the stability of the oxide layer, thus increasing the corrosion resistance of the specimens. The maximum inhibition efficiency of the NP extract was reached at 97% for weld metal with 5 g/L of extract, at 80% for the heat affected zone with 5 g/L, and at 70% for base metal with 4 g/L. This work reveals the particularity of different weldment zones to the different needs of inhibitor concentration for obtaining the optimum corrosion protection.</description><identifier>ISSN: 2071-1050</identifier><identifier>EISSN: 2071-1050</identifier><identifier>DOI: 10.3390/su132112135</identifier><language>eng</language><publisher>BASEL: Mdpi</publisher><subject><![CDATA[Adsorption ; Base metal ; Carbon steel ; Chemical inhibitors ; Chloride ; Corrosion ; Corrosion mechanisms ; Corrosion prevention ; Corrosion rate ; Corrosion resistance ; Corrosion resistant steels ; Corrosion tests ; Efficiency ; Electrochemistry ; Electrodes ; Environmental Sciences ; Environmental Sciences & Ecology ; Environmental Studies ; Grain size ; Green & Sustainable Science & Technology ; Heat affected zone ; Immersion tests (corrosion) ; Life Sciences & Biomedicine ; Metal industry ; Metals ; Molecular weight ; Nephelium lappaceum ; Retention ; Science & Technology ; Science & Technology - Other Topics ; Spectrum analysis ; Stability ; Steel ; Weld metal ; Welding ; Weldments]]></subject><ispartof>Sustainability, 2021-11, Vol.13 (21), p.12135, Article 12135</ispartof><rights>COPYRIGHT 2021 MDPI AG</rights><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>12</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000719013000001</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c371t-381243ba425afe23da959127c903757a8a5f61e1de4938a2de007adad7bc34543</citedby><cites>FETCH-LOGICAL-c371t-381243ba425afe23da959127c903757a8a5f61e1de4938a2de007adad7bc34543</cites><orcidid>0000-0003-2772-102X ; 0000-0002-5596-9949 ; 0000-0003-3641-8372 ; 0000-0002-8694-9000</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930,39262,39263</link.rule.ids></links><search><creatorcontrib>Gapsari, Femiana</creatorcontrib><creatorcontrib>Darmadi, Djarot B.</creatorcontrib><creatorcontrib>Setyarini, Putu H.</creatorcontrib><creatorcontrib>Izzuddin, Hubby</creatorcontrib><creatorcontrib>Madurani, Kartika A.</creatorcontrib><creatorcontrib>Tanji, Ayoub</creatorcontrib><creatorcontrib>Hermawan, Hendra</creatorcontrib><title>Nephelium lappaceum Extract as an Organic Inhibitor to Control the Corrosion of Carbon Steel Weldment in the Acidic Environment</title><title>Sustainability</title><addtitle>SUSTAINABILITY-BASEL</addtitle><description>Organic inhibitors have been considered as an effective way to control the corrosion of carbon steel weldment in an acidic environment. This work proposes a new green organic inhibitor made of extract of rambutan fruit (Nephelium lappaceum) peel and aims at analyzing its corrosion inhibitor properties and protection mechanism. Specimens of carbon steel weldment were tested for their corrosion by using electrochemical and immersion methods in 1 M HCl solution containing 0 to 6 g/L of Nephelium peel (NP) extract. Results showed that, in the same solution, the corrosion rate was measured to be higher on the weld metal zone than that of base metal zone, which could be related to the coarser grain of the weld metal zone and the stability of the formed oxide layer. The addition of NP extract was found to increase the stability of the oxide layer, thus increasing the corrosion resistance of the specimens. The maximum inhibition efficiency of the NP extract was reached at 97% for weld metal with 5 g/L of extract, at 80% for the heat affected zone with 5 g/L, and at 70% for base metal with 4 g/L. This work reveals the particularity of different weldment zones to the different needs of inhibitor concentration for obtaining the optimum corrosion protection.</description><subject>Adsorption</subject><subject>Base metal</subject><subject>Carbon steel</subject><subject>Chemical inhibitors</subject><subject>Chloride</subject><subject>Corrosion</subject><subject>Corrosion mechanisms</subject><subject>Corrosion prevention</subject><subject>Corrosion rate</subject><subject>Corrosion resistance</subject><subject>Corrosion resistant steels</subject><subject>Corrosion tests</subject><subject>Efficiency</subject><subject>Electrochemistry</subject><subject>Electrodes</subject><subject>Environmental Sciences</subject><subject>Environmental Sciences & Ecology</subject><subject>Environmental Studies</subject><subject>Grain size</subject><subject>Green & Sustainable Science & Technology</subject><subject>Heat affected zone</subject><subject>Immersion tests (corrosion)</subject><subject>Life Sciences & Biomedicine</subject><subject>Metal industry</subject><subject>Metals</subject><subject>Molecular weight</subject><subject>Nephelium lappaceum</subject><subject>Retention</subject><subject>Science & Technology</subject><subject>Science & Technology - Other Topics</subject><subject>Spectrum analysis</subject><subject>Stability</subject><subject>Steel</subject><subject>Weld metal</subject><subject>Welding</subject><subject>Weldments</subject><issn>2071-1050</issn><issn>2071-1050</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>GIZIO</sourceid><sourceid>HGBXW</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqNkUFv1DAQhSNEJarSE3_AEieEtnjsZB0fV9ECK1VUakEco4kz2XWVtYPtlHLir-NlEW1vtQ9-Gn9vRppXFG-AX0ip-Yc4gxQAAmT1ojgVXMECeMVfPtKvivMYb3k-UoKG5Wnx-wtNOxrtvGcjThMaymp9nwKaxDAydOwqbNFZwzZuZzubfGDJs8a7FPzI0o6yDsFH6x3zA2swdFndJKKRfaex35NLzLq_5MrYPndauzsbvDv8vC5OBhwjnf97z4pvH9dfm8-Ly6tPm2Z1uTBSQVrIGkQpOyxFhQMJ2aOuNAhlNJeqUlhjNSyBoKdSyxpFT5wr7LFXnZFlVcqz4u2x7xT8j5liam_9HFwe2YpKL_lSKK0zdXGktjhSa93gD4vIt6e9Nd7RYHN9VUOluNC6zoZ3TwyZSXSftjjH2G5urp-y74-syduKgYZ2CnaP4VcLvD0k2D5KMNP1kf5JnR-iseQM_XfkBBVoDvKQJYfGJkw5gMbPLj0Meo5V_gGeYK1p</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Gapsari, Femiana</creator><creator>Darmadi, Djarot B.</creator><creator>Setyarini, Putu H.</creator><creator>Izzuddin, Hubby</creator><creator>Madurani, Kartika A.</creator><creator>Tanji, Ayoub</creator><creator>Hermawan, Hendra</creator><general>Mdpi</general><general>MDPI AG</general><scope>17B</scope><scope>BLEPL</scope><scope>DTL</scope><scope>DVR</scope><scope>EGQ</scope><scope>GIZIO</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>4U-</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0003-2772-102X</orcidid><orcidid>https://orcid.org/0000-0002-5596-9949</orcidid><orcidid>https://orcid.org/0000-0003-3641-8372</orcidid><orcidid>https://orcid.org/0000-0002-8694-9000</orcidid></search><sort><creationdate>20211101</creationdate><title>Nephelium lappaceum Extract as an Organic Inhibitor to Control the Corrosion of Carbon Steel Weldment in the Acidic Environment</title><author>Gapsari, Femiana ; 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This work proposes a new green organic inhibitor made of extract of rambutan fruit (Nephelium lappaceum) peel and aims at analyzing its corrosion inhibitor properties and protection mechanism. Specimens of carbon steel weldment were tested for their corrosion by using electrochemical and immersion methods in 1 M HCl solution containing 0 to 6 g/L of Nephelium peel (NP) extract. Results showed that, in the same solution, the corrosion rate was measured to be higher on the weld metal zone than that of base metal zone, which could be related to the coarser grain of the weld metal zone and the stability of the formed oxide layer. The addition of NP extract was found to increase the stability of the oxide layer, thus increasing the corrosion resistance of the specimens. The maximum inhibition efficiency of the NP extract was reached at 97% for weld metal with 5 g/L of extract, at 80% for the heat affected zone with 5 g/L, and at 70% for base metal with 4 g/L. This work reveals the particularity of different weldment zones to the different needs of inhibitor concentration for obtaining the optimum corrosion protection.</abstract><cop>BASEL</cop><pub>Mdpi</pub><doi>10.3390/su132112135</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-2772-102X</orcidid><orcidid>https://orcid.org/0000-0002-5596-9949</orcidid><orcidid>https://orcid.org/0000-0003-3641-8372</orcidid><orcidid>https://orcid.org/0000-0002-8694-9000</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Adsorption Base metal Carbon steel Chemical inhibitors Chloride Corrosion Corrosion mechanisms Corrosion prevention Corrosion rate Corrosion resistance Corrosion resistant steels Corrosion tests Efficiency Electrochemistry Electrodes Environmental Sciences Environmental Sciences & Ecology Environmental Studies Grain size Green & Sustainable Science & Technology Heat affected zone Immersion tests (corrosion) Life Sciences & Biomedicine Metal industry Metals Molecular weight Nephelium lappaceum Retention Science & Technology Science & Technology - Other Topics Spectrum analysis Stability Steel Weld metal Welding Weldments |
| title | Nephelium lappaceum Extract as an Organic Inhibitor to Control the Corrosion of Carbon Steel Weldment in the Acidic Environment |
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