Concave Double-Walled AgAuPd Nanocubes for Surface-Enhanced Raman Spectroscopy Detection and Catalysis Applications
Herein, we develop a series etching and atom codeposition process to fabricate concave double-shell AgAu (CD-AgAu) and CD-AgAu:Pd nanocubes. High surface area and edge activity from the CD nanostructure consisting of a single hole appear in the central area, and 12 concave structures exhibit superio...
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| Veröffentlicht in: | ACS applied nano materials 2021-10, Vol.4 (10), p.10103-10115 |
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| container_title | ACS applied nano materials |
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| creator | Huang, Tzu-Chi Tsai, Hsiao-Chieh Chin, Yu-Cheng Huang, Wei-Shan Chiu, Yi-Chun Hsu, Tzu-Chun Chia, Zi-Chun Hung, Tzu-Chiao Huang, Chih-Chia Hsieh, Yi-Ting |
| description | Herein, we develop a series etching and atom codeposition process to fabricate concave double-shell AgAu (CD-AgAu) and CD-AgAu:Pd nanocubes. High surface area and edge activity from the CD nanostructure consisting of a single hole appear in the central area, and 12 concave structures exhibit superior surface-enhanced Raman scattering (SERS). As investigating the Pd dopants at the CD surface with SERS and electrochemistry, we demonstrate that the 2.8% Pd-doped CD-AgAu nanocubes perform impressive catalysis at ≤30 s of the hydrogenation reaction by lowering the activation energy. Furthermore, the CD-AgAu:4.6%Pd nanocubes act as a superior catalyst for glycerol electrooxidation and could retain their high-index facets after a long-term durability test. Our work will help to motivate future efforts for the deliberate incorporation of a low content of noble metals into CD nanostructures to develop chemical sensing devices in interfacial reactions and clean energy conversion technology. |
| doi_str_mv | 10.1021/acsanm.1c01534 |
| format | Article |
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High surface area and edge activity from the CD nanostructure consisting of a single hole appear in the central area, and 12 concave structures exhibit superior surface-enhanced Raman scattering (SERS). As investigating the Pd dopants at the CD surface with SERS and electrochemistry, we demonstrate that the 2.8% Pd-doped CD-AgAu nanocubes perform impressive catalysis at ≤30 s of the hydrogenation reaction by lowering the activation energy. Furthermore, the CD-AgAu:4.6%Pd nanocubes act as a superior catalyst for glycerol electrooxidation and could retain their high-index facets after a long-term durability test. Our work will help to motivate future efforts for the deliberate incorporation of a low content of noble metals into CD nanostructures to develop chemical sensing devices in interfacial reactions and clean energy conversion technology.</description><identifier>ISSN: 2574-0970</identifier><identifier>EISSN: 2574-0970</identifier><identifier>DOI: 10.1021/acsanm.1c01534</identifier><language>eng</language><publisher>WASHINGTON: American Chemical Society</publisher><subject>Materials Science ; Materials Science, Multidisciplinary ; Nanoscience & Nanotechnology ; Science & Technology ; Science & Technology - Other Topics ; Technology</subject><ispartof>ACS applied nano materials, 2021-10, Vol.4 (10), p.10103-10115</ispartof><rights>2021 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>21</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000711030600014</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-a274t-ffb3c1ea9b7f192c26e298b664357edad3a35aeaafff4ed5db466ed791f27e0a3</citedby><cites>FETCH-LOGICAL-a274t-ffb3c1ea9b7f192c26e298b664357edad3a35aeaafff4ed5db466ed791f27e0a3</cites><orcidid>0000-0001-6462-9009 ; 0000-0002-9486-8665 ; 0000-0003-4635-6574 ; 0000-0002-0302-7925</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acsanm.1c01534$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acsanm.1c01534$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>315,781,785,2766,27081,27929,27930,39263,56743,56793</link.rule.ids></links><search><creatorcontrib>Huang, Tzu-Chi</creatorcontrib><creatorcontrib>Tsai, Hsiao-Chieh</creatorcontrib><creatorcontrib>Chin, Yu-Cheng</creatorcontrib><creatorcontrib>Huang, Wei-Shan</creatorcontrib><creatorcontrib>Chiu, Yi-Chun</creatorcontrib><creatorcontrib>Hsu, Tzu-Chun</creatorcontrib><creatorcontrib>Chia, Zi-Chun</creatorcontrib><creatorcontrib>Hung, Tzu-Chiao</creatorcontrib><creatorcontrib>Huang, Chih-Chia</creatorcontrib><creatorcontrib>Hsieh, Yi-Ting</creatorcontrib><title>Concave Double-Walled AgAuPd Nanocubes for Surface-Enhanced Raman Spectroscopy Detection and Catalysis Applications</title><title>ACS applied nano materials</title><addtitle>ACS APPL NANO MATER</addtitle><addtitle>ACS Appl. Nano Mater</addtitle><description>Herein, we develop a series etching and atom codeposition process to fabricate concave double-shell AgAu (CD-AgAu) and CD-AgAu:Pd nanocubes. High surface area and edge activity from the CD nanostructure consisting of a single hole appear in the central area, and 12 concave structures exhibit superior surface-enhanced Raman scattering (SERS). As investigating the Pd dopants at the CD surface with SERS and electrochemistry, we demonstrate that the 2.8% Pd-doped CD-AgAu nanocubes perform impressive catalysis at ≤30 s of the hydrogenation reaction by lowering the activation energy. Furthermore, the CD-AgAu:4.6%Pd nanocubes act as a superior catalyst for glycerol electrooxidation and could retain their high-index facets after a long-term durability test. Our work will help to motivate future efforts for the deliberate incorporation of a low content of noble metals into CD nanostructures to develop chemical sensing devices in interfacial reactions and clean energy conversion technology.</description><subject>Materials Science</subject><subject>Materials Science, Multidisciplinary</subject><subject>Nanoscience & Nanotechnology</subject><subject>Science & Technology</subject><subject>Science & Technology - Other Topics</subject><subject>Technology</subject><issn>2574-0970</issn><issn>2574-0970</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><recordid>eNqNkM9LwzAYhosoOOaunnNWOpOmbdZj6eYPGCpO8Vi-pl-0o0tK0yr7703tEC-CpyR87xPe7_G8c0bnjAbsCqQFvZszSVnEwyNvEkQi9Gki6PGv-6k3s3ZLKWUJizmlE89mRkv4QLI0fVGj_wp1jSVJ39L-sST3oI3sC7REmZZs-laBRH-l30FLl3qCHWiyaVB2rbHSNHuyxM69KqMJ6JJk0EG9t5UladPUlYRhYs-8EwW1xdnhnHov16vn7NZfP9zcZenah0CEna9UwSVDSAqhWBLIIMYgWRRxHPJIYAklBx4BAiilQiyjsgjjGEuRMBUIpMCn3nz8V7p2tkWVN221g3afM5oP1vLRWn6w5oDLEfjEwigrK3Rr_kBOm2CMchoPAof04v_prOq-l89MrzuHXoyoK5BvTd9q5-GvVl_ORpKL</recordid><startdate>20211022</startdate><enddate>20211022</enddate><creator>Huang, Tzu-Chi</creator><creator>Tsai, Hsiao-Chieh</creator><creator>Chin, Yu-Cheng</creator><creator>Huang, Wei-Shan</creator><creator>Chiu, Yi-Chun</creator><creator>Hsu, Tzu-Chun</creator><creator>Chia, Zi-Chun</creator><creator>Hung, Tzu-Chiao</creator><creator>Huang, Chih-Chia</creator><creator>Hsieh, Yi-Ting</creator><general>American Chemical Society</general><general>Amer Chemical Soc</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-6462-9009</orcidid><orcidid>https://orcid.org/0000-0002-9486-8665</orcidid><orcidid>https://orcid.org/0000-0003-4635-6574</orcidid><orcidid>https://orcid.org/0000-0002-0302-7925</orcidid></search><sort><creationdate>20211022</creationdate><title>Concave Double-Walled AgAuPd Nanocubes for Surface-Enhanced Raman Spectroscopy Detection and Catalysis Applications</title><author>Huang, Tzu-Chi ; Tsai, Hsiao-Chieh ; Chin, Yu-Cheng ; Huang, Wei-Shan ; Chiu, Yi-Chun ; Hsu, Tzu-Chun ; Chia, Zi-Chun ; Hung, Tzu-Chiao ; Huang, Chih-Chia ; Hsieh, Yi-Ting</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a274t-ffb3c1ea9b7f192c26e298b664357edad3a35aeaafff4ed5db466ed791f27e0a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Materials Science</topic><topic>Materials Science, Multidisciplinary</topic><topic>Nanoscience & Nanotechnology</topic><topic>Science & Technology</topic><topic>Science & Technology - Other Topics</topic><topic>Technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Tzu-Chi</creatorcontrib><creatorcontrib>Tsai, Hsiao-Chieh</creatorcontrib><creatorcontrib>Chin, Yu-Cheng</creatorcontrib><creatorcontrib>Huang, Wei-Shan</creatorcontrib><creatorcontrib>Chiu, Yi-Chun</creatorcontrib><creatorcontrib>Hsu, Tzu-Chun</creatorcontrib><creatorcontrib>Chia, Zi-Chun</creatorcontrib><creatorcontrib>Hung, Tzu-Chiao</creatorcontrib><creatorcontrib>Huang, Chih-Chia</creatorcontrib><creatorcontrib>Hsieh, Yi-Ting</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 2021</collection><collection>CrossRef</collection><jtitle>ACS applied nano materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Tzu-Chi</au><au>Tsai, Hsiao-Chieh</au><au>Chin, Yu-Cheng</au><au>Huang, Wei-Shan</au><au>Chiu, Yi-Chun</au><au>Hsu, Tzu-Chun</au><au>Chia, Zi-Chun</au><au>Hung, Tzu-Chiao</au><au>Huang, Chih-Chia</au><au>Hsieh, Yi-Ting</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Concave Double-Walled AgAuPd Nanocubes for Surface-Enhanced Raman Spectroscopy Detection and Catalysis Applications</atitle><jtitle>ACS applied nano materials</jtitle><stitle>ACS APPL NANO MATER</stitle><addtitle>ACS Appl. 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| subjects | Materials Science Materials Science, Multidisciplinary Nanoscience & Nanotechnology Science & Technology Science & Technology - Other Topics Technology |
| title | Concave Double-Walled AgAuPd Nanocubes for Surface-Enhanced Raman Spectroscopy Detection and Catalysis Applications |
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