Noncovalent Interactions in Organic Radicals: Pancake, σ‑Hole, and H‑Bonding in F2HbimDTDA

The solid-state structure of neutral thiazyl radical 4-[2′-(5,6-difluorobenzimidazolyl)]-1,2,3,5-dithiadiazolyl (F2H­bim­DTDA) is the result of a combination of structure-directing intermolecular interactions. Pancake bonding of radical molecules leads to stacks of [F2HbimDTDA]2 pairs along [100]. P...

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Veröffentlicht in:	Crystal growth & design 2021-10, Vol.21 (10), p.5669-5677
Hauptverfasser:	Mills, Michelle B, Young, Harrison K. S, Wehrle, Gabriele, Verduyn, Willem R, Feng, Xibo, Boyle, Paul D, Dechambenoit, Pierre, Johnson, Erin R, Preuss, Kathryn E
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry, Multidisciplinary Crystallography Materials Science Materials Science, Multidisciplinary Physical Sciences Science & Technology Technology
Online-Zugang:	Volltext
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