Harnessing Shape Complementarity for Upgraded Cyclohexane Purification through Adaptive Bottlenecked Pores in an Imidazole‐Containing MOF

Shape complementarity is a biological craft for precisely binding substrates at protein–protein interfaces. An analogy to such a function can be drawn conceptually for crystalline porous solids; yet the manifested entities are rare in reticular chemistry. The bottleneck‐shaped pores carved out of a...

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Veröffentlicht in:	Angewandte Chemie International Edition 2021-10, Vol.60 (44), p.23590-23595
Hauptverfasser:	Ye, Chun‐Rong, Wang, Wen‐Jian, Chen, Wei, Xiao, Yonghong, Zhang, Hai‐Feng, Dai, Bing‐Ling, Chen, Si‐Han, Wu, Xu‐Dong, Li, Mian, Huang, Xiao‐Chun
Format:	Artikel
Sprache:	eng
Schlagworte:	adaptive crystals Benzene Binding Chemistry Chemistry, Multidisciplinary Complementarity Computer applications Crystals Cyclohexane Cyclohexanes - chemistry Cyclohexanes - isolation & purification host–guest chemistry Imidazole Imidazoles - chemistry Interfaces Metal-Organic Frameworks - chemistry metal–organic frameworks Models, Molecular Particle Size Physical Sciences Pores porous materials Proteins Purity Science & Technology Selectivity separation Substrates Zinc
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