Bu4NHSO4‐Catalyzed Direct N‐Allylation of Pyrazole and its Derivatives with Allylic Alcohols in Water: A Metal‐Free, Recyclable and Sustainable System

Allylic amines are valuable and functional building blocks. Direct N‐allylation of pyrazole and its derivatives as an atom economic strategy to provide allylic amines has been achieved only using commercial Bu4NHSO4 as the metal‐free catalyst and water as the solvent without any additives. 11–93% is...

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Veröffentlicht in:	Advanced synthesis & catalysis 2021-12, Vol.363 (24), p.5461-5472
Hauptverfasser:	Zhuang, Hongfeng, Lu, Nan, Ji, Na, Han, Feng, Miao, Chengxia
Format:	Artikel
Sprache:	eng
Schlagworte:	Additives Alcohols Allyl compounds Allylation Allylic Alcohols Amines Bu4NHSO4 Catalysts Catalytic activity Chemical reactions Chemistry Chemistry, Applied Chemistry, Organic Density functional theory Hydrogen bonding Physical Sciences Pyrazole Pyrazole and its Derivatives Science & Technology Solvents Substrates Water
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