Mechanism of 8‑Aminoquinoline-Directed Ni-Catalyzed C(sp3)–H Functionalization: Paramagnetic Ni(II) Species and the Deleterious Effect of Carbonate as a Base

Studies into the mechanism of 8-aminoquinoline-directed nickel-catalyzed C­(sp3)–H arylation with iodoarenes were carried out, to determine the catalyst resting state and optimize catalytic performance. Paramagnetic complexes undergo the key C–H activation step. The ubiquitous base Na2CO3 is found t...

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Veröffentlicht in:	Organometallics 2021-09, Vol.40 (17), p.2970-2982
Hauptverfasser:	Liu, Junyang, Johnson, Samuel A
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry, Inorganic & Nuclear Chemistry, Organic Physical Sciences Science & Technology
Online-Zugang:	Volltext
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