Properties of C-doped CrTiN films on the 316L stainless steel bipolar plate for PEMFC
C doped CrTiN films were deposited on 316L stainless steel by magnetron sputtering technology to investigate corrosion resistance and electrical conductivity. The sputtering current of the C target alter to obtain various C contents. The carbon target currents are 0 A, 3 A and 6 A, respectively. The...
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Veröffentlicht in: | International journal of hydrogen energy 2021-09, Vol.46 (64), p.32645-32654 |
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creator | Mi, Baosen Chen, Zhuo Wang, Quan Li, Yifeifei Qin, Ziwei Wang, Hongbin |
description | C doped CrTiN films were deposited on 316L stainless steel by magnetron sputtering technology to investigate corrosion resistance and electrical conductivity. The sputtering current of the C target alter to obtain various C contents. The carbon target currents are 0 A, 3 A and 6 A, respectively. The result of SEM confirms that deposited films have a dense and uniform microstructure. CrTiN coating consist of Cr, CrN and TiN phases. With the increase of C carbon target currents, Cr crystal structure vanishes, and the amorphous carbon and carbides appear. The result of the potentiodynamic polarization test in the simulate PEMFC environment reveals that C doped CrTiN coating can improve samples’ corrosion resistance. At 1.1 V (vs. SHE) potentiostatic tests, the C-6A has the lowest current density, 6.09 × 10−7 A/cm2. Interfacial contact resistance decreases with the addition of C atoms. The C-6A coated sample has the lowest interfacial contact resistance values, 5.5 mΩ cm2.
•C doped CrTiN films with different C contents is deposited on stainless steel.•Cr crystal structure vanishes, and the amorphous carbon and carbides appear.•C doped CrTiN coating can improve samples' corrosion resistance.•Interfacial contact resistance decreases with C incorporation. |
doi_str_mv | 10.1016/j.ijhydene.2021.07.109 |
format | Article |
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•C doped CrTiN films with different C contents is deposited on stainless steel.•Cr crystal structure vanishes, and the amorphous carbon and carbides appear.•C doped CrTiN coating can improve samples' corrosion resistance.•Interfacial contact resistance decreases with C incorporation.</description><identifier>ISSN: 0360-3199</identifier><identifier>EISSN: 1879-3487</identifier><identifier>DOI: 10.1016/j.ijhydene.2021.07.109</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Bipolar plate ; C doped CrTiN film ; Corrosion resistance ; Interfacial contact resistance ; Magnetron sputtering</subject><ispartof>International journal of hydrogen energy, 2021-09, Vol.46 (64), p.32645-32654</ispartof><rights>2021 Hydrogen Energy Publications LLC</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c312t-666b5493d4b693036179cd9ec45abc0bb3808fc81f84eaa5148226c2595008b83</citedby><cites>FETCH-LOGICAL-c312t-666b5493d4b693036179cd9ec45abc0bb3808fc81f84eaa5148226c2595008b83</cites><orcidid>0000-0002-4298-3282</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.ijhydene.2021.07.109$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Mi, Baosen</creatorcontrib><creatorcontrib>Chen, Zhuo</creatorcontrib><creatorcontrib>Wang, Quan</creatorcontrib><creatorcontrib>Li, Yifeifei</creatorcontrib><creatorcontrib>Qin, Ziwei</creatorcontrib><creatorcontrib>Wang, Hongbin</creatorcontrib><title>Properties of C-doped CrTiN films on the 316L stainless steel bipolar plate for PEMFC</title><title>International journal of hydrogen energy</title><description>C doped CrTiN films were deposited on 316L stainless steel by magnetron sputtering technology to investigate corrosion resistance and electrical conductivity. The sputtering current of the C target alter to obtain various C contents. The carbon target currents are 0 A, 3 A and 6 A, respectively. The result of SEM confirms that deposited films have a dense and uniform microstructure. CrTiN coating consist of Cr, CrN and TiN phases. With the increase of C carbon target currents, Cr crystal structure vanishes, and the amorphous carbon and carbides appear. The result of the potentiodynamic polarization test in the simulate PEMFC environment reveals that C doped CrTiN coating can improve samples’ corrosion resistance. At 1.1 V (vs. SHE) potentiostatic tests, the C-6A has the lowest current density, 6.09 × 10−7 A/cm2. Interfacial contact resistance decreases with the addition of C atoms. The C-6A coated sample has the lowest interfacial contact resistance values, 5.5 mΩ cm2.
•C doped CrTiN films with different C contents is deposited on stainless steel.•Cr crystal structure vanishes, and the amorphous carbon and carbides appear.•C doped CrTiN coating can improve samples' corrosion resistance.•Interfacial contact resistance decreases with C incorporation.</description><subject>Bipolar plate</subject><subject>C doped CrTiN film</subject><subject>Corrosion resistance</subject><subject>Interfacial contact resistance</subject><subject>Magnetron sputtering</subject><issn>0360-3199</issn><issn>1879-3487</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkFFLwzAUhYMoOKd_QfIHWm-aNk3elLKpMHUP23NI01uW0rUlKcL-vRnTZ5_uuR-cw-EQ8sggZcDEU5e67nBqcMA0g4ylUEaursiCyVIlPJflNVkAF5BwptQtuQuhA2Al5GpB9ls_Tuhnh4GOLa2SJr4NrfzOfdLW9ceIBzofkHImNjTMxg09hhAVYk9rN4298XTqzYy0HT3drj7W1T25aU0f8OH3Lsl-vdpVb8nm6_W9etkklrNsToQQdZEr3uS1UDxWZKWyjUKbF6a2UNdcgmytZK3M0ZiC5TLLhM0KVQDIWvIlEZdc68cQPLZ68u5o_Ekz0OdxdKf_xtHncTSUkatofL4YMbb7duh1sA4Hi43zaGfdjO6_iB8MGW9y</recordid><startdate>20210916</startdate><enddate>20210916</enddate><creator>Mi, Baosen</creator><creator>Chen, Zhuo</creator><creator>Wang, Quan</creator><creator>Li, Yifeifei</creator><creator>Qin, Ziwei</creator><creator>Wang, Hongbin</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-4298-3282</orcidid></search><sort><creationdate>20210916</creationdate><title>Properties of C-doped CrTiN films on the 316L stainless steel bipolar plate for PEMFC</title><author>Mi, Baosen ; Chen, Zhuo ; Wang, Quan ; Li, Yifeifei ; Qin, Ziwei ; Wang, Hongbin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c312t-666b5493d4b693036179cd9ec45abc0bb3808fc81f84eaa5148226c2595008b83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Bipolar plate</topic><topic>C doped CrTiN film</topic><topic>Corrosion resistance</topic><topic>Interfacial contact resistance</topic><topic>Magnetron sputtering</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mi, Baosen</creatorcontrib><creatorcontrib>Chen, Zhuo</creatorcontrib><creatorcontrib>Wang, Quan</creatorcontrib><creatorcontrib>Li, Yifeifei</creatorcontrib><creatorcontrib>Qin, Ziwei</creatorcontrib><creatorcontrib>Wang, Hongbin</creatorcontrib><collection>CrossRef</collection><jtitle>International journal of hydrogen energy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mi, Baosen</au><au>Chen, Zhuo</au><au>Wang, Quan</au><au>Li, Yifeifei</au><au>Qin, Ziwei</au><au>Wang, Hongbin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Properties of C-doped CrTiN films on the 316L stainless steel bipolar plate for PEMFC</atitle><jtitle>International journal of hydrogen energy</jtitle><date>2021-09-16</date><risdate>2021</risdate><volume>46</volume><issue>64</issue><spage>32645</spage><epage>32654</epage><pages>32645-32654</pages><issn>0360-3199</issn><eissn>1879-3487</eissn><abstract>C doped CrTiN films were deposited on 316L stainless steel by magnetron sputtering technology to investigate corrosion resistance and electrical conductivity. The sputtering current of the C target alter to obtain various C contents. The carbon target currents are 0 A, 3 A and 6 A, respectively. The result of SEM confirms that deposited films have a dense and uniform microstructure. CrTiN coating consist of Cr, CrN and TiN phases. With the increase of C carbon target currents, Cr crystal structure vanishes, and the amorphous carbon and carbides appear. The result of the potentiodynamic polarization test in the simulate PEMFC environment reveals that C doped CrTiN coating can improve samples’ corrosion resistance. At 1.1 V (vs. SHE) potentiostatic tests, the C-6A has the lowest current density, 6.09 × 10−7 A/cm2. Interfacial contact resistance decreases with the addition of C atoms. The C-6A coated sample has the lowest interfacial contact resistance values, 5.5 mΩ cm2.
•C doped CrTiN films with different C contents is deposited on stainless steel.•Cr crystal structure vanishes, and the amorphous carbon and carbides appear.•C doped CrTiN coating can improve samples' corrosion resistance.•Interfacial contact resistance decreases with C incorporation.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.ijhydene.2021.07.109</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0002-4298-3282</orcidid></addata></record> |
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source | ScienceDirect Journals (5 years ago - present) |
subjects | Bipolar plate C doped CrTiN film Corrosion resistance Interfacial contact resistance Magnetron sputtering |
title | Properties of C-doped CrTiN films on the 316L stainless steel bipolar plate for PEMFC |
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