A ruthenium cis-dihydride with 2-phosphinophosphinine ligands catalyses the acceptorless dehydrogenation of benzyl alcohol

The first ruthenium dihydride complex featuring a phosphinine ligand cis-[Ru(H)(2)(2-PPh2-3-Me-6-SiMe3-PC5H2)(2)] was synthesised exclusively as the cis-isomer. When formed in situ from the reaction of cis-[Ru(Cl)(2)(2-PPh2-3-Me-6-SiMe3-PC5H2)(2)] with two equivalents of Na[BHEt3], as demonstrated b...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2021-10, Vol.50 (38), p.13407-13411
Hauptverfasser:	Trodden, Elizabeth C., Delve, Matthew P., Luz, Christian, Newland, Robert J., Andresen, John M., Mansell, Stephen M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Benzoates Benzyl alcohol Chemistry Chemistry, Inorganic & Nuclear Coordination compounds Dehydrogenation Dihydrides Ligands NMR spectroscopy Physical Sciences Ruthenium Science & Technology
Online-Zugang:	Volltext
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