Mechanistic Study of Metal–Ligand Cooperativity in Mn(II)-Catalyzed Hydroborations: Hemilabile SNS Ligand Enables Metal Hydride-Free Reaction Pathway

Mechanistic Study of Metal–Ligand Cooperativity in Mn(II)-Catalyzed Hydroborations: Hemilabile SNS Ligand Enables Metal Hydride-Free Reaction Pathway

A combined experimental and mechanistic study of the chemoselective hydroboration of carbonyls by the paramagnetic bis-amido Mn­[SMeNSMe]2 complex (1) is described. The catalyst allows for room-temperature hydroboration of carbonyls at low catalyst loadings (0.1 mol %) and reaction times (

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Veröffentlicht in:ACS catalysis 2021-08, Vol.11 (15), p.9043-9051
Hauptverfasser: Elsby, Matthew R, Son, Mina, Oh, Changjin, Martin, Jessica, Baik, Mu-Hyun, Baker, R. Tom
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creator Elsby, Matthew R
Son, Mina
Oh, Changjin
Martin, Jessica
Baik, Mu-Hyun
Baker, R. Tom
description A combined experimental and mechanistic study of the chemoselective hydroboration of carbonyls by the paramagnetic bis-amido Mn­[SMeNSMe]2 complex (1) is described. The catalyst allows for room-temperature hydroboration of carbonyls at low catalyst loadings (0.1 mol %) and reaction times (
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Tom</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mechanistic Study of Metal–Ligand Cooperativity in Mn(II)-Catalyzed Hydroborations: Hemilabile SNS Ligand Enables Metal Hydride-Free Reaction Pathway</atitle><jtitle>ACS catalysis</jtitle><stitle>ACS CATAL</stitle><addtitle>ACS Catal</addtitle><date>2021-08-06</date><risdate>2021</risdate><volume>11</volume><issue>15</issue><spage>9043</spage><epage>9051</epage><pages>9043-9051</pages><issn>2155-5435</issn><eissn>2155-5435</eissn><abstract>A combined experimental and mechanistic study of the chemoselective hydroboration of carbonyls by the paramagnetic bis-amido Mn­[SMeNSMe]2 complex (1) is described. The catalyst allows for room-temperature hydroboration of carbonyls at low catalyst loadings (0.1 mol %) and reaction times (&lt;30 min). 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subjects Chemistry
Chemistry, Physical
Physical Sciences
Science & Technology
title Mechanistic Study of Metal–Ligand Cooperativity in Mn(II)-Catalyzed Hydroborations: Hemilabile SNS Ligand Enables Metal Hydride-Free Reaction Pathway
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