Synthesis of Al/Cu core–shell particles through optimization of galvanic replacement method in alkaline solution
In this work, Al/Cu core–shell particles were successfully synthesized through an optimized galvanic replacement method. For this purpose, a uniform and dense copper layer was deposited on aluminum particles in an alkaline solution. The effects of four deposition factors, i. e. (i) molar ratio EDTA-...
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| Veröffentlicht in: | International journal of materials research 2021-05, Vol.112 (6), p.439-447 |
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| container_title | International journal of materials research |
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| creator | Ali, Rashid Ali, Fahad Zahoor, Aqib Nawaz Shahid, Rub ul HaqTariq, Naeem Ullah, Saad Mahmood, Arshad Shah, Attaullah Bin Awais, Hasan |
| description | In this work, Al/Cu core–shell particles were successfully synthesized through an optimized galvanic replacement method. For this purpose, a uniform and dense copper layer was deposited on aluminum particles in an alkaline solution. The effects of four deposition factors, i. e. (i) molar ratio EDTA-2Na/CuSO
· 5H
O, (ii) molar ratio CuCl
/Al powder, (iii)
and (iv) temperature were systematically studied and optimized using the Taguchi orthogonal (L9) method. It was observed that molar ratio EDTA-2Na/CuSO
· 5H
O and temperature are the most affecting factors in the deposition process. By increasing their levels, copper deposition increases within a specified time. The X-ray diffraction and scanning electron microscopy/ energy-dispersive X-ray spectroscopy results revealed the formation of homogeneous nanostructured Cu shells around Al particles. The results revealed that to achieve maximum copper deposition on Al powder; molar ratio EDTA-2Na. 2H
O/CuSO
. 5H
O, molar ratio CuCl
/Al powder,
and temperature of the deposition bath should be 2.0, 0.05, 8.8 and 55 °C, respectively. |
| doi_str_mv | 10.1515/ijmr-2020-8167 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_webof</sourceid><recordid>TN_cdi_webofscience_primary_000672580000002</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2553566206</sourcerecordid><originalsourceid>FETCH-LOGICAL-c320t-2237d9f39d7061f7ddb2ca5e162e3693557b64ab3a5e095dd566aa35e275da413</originalsourceid><addsrcrecordid>eNqNkMtu1DAUQC1EJYa2W9YWW5TWj7GTLFhUEY9KlVhA15bHuZl4cOxgO6BhxT_wh3xJnU7FDglvbF2dY10dhF5RckUFFdf2MMWKEUaqhsr6Gdow2oqqEUI-RxvaSFYJ1rAX6GVKB0JEYdgGxc9Hn0dINuEw4Bt33S3YhAh_fv1OIziHZx2zNQ4SzmMMy37EYc52sj91tsGv0l6779pbgyPMThuYwGc8QR5Dj63H2n3VznrAKbhldS7Q2aBdgsun-xzdv3_3pftY3X36cNvd3FWGM5IrxnjdtwNv-5pIOtR9v2NGC6CSAZctF6Leya3e8TIjreh7IaXWXACrRa-3lJ-j16d_5xi-LZCyKguGmJNiQvBCMyILdHWCTAwpRRjUHO2k41FRotasas2q1qxqzVqENyfhB-zCkIwFb-CvRAgpWUVDHg8rdPP_dGfzY9QuLD4X9e2Tql2G2MM-LsfyUIewRF_C_WNDSpnc8pY_AIyjovk</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2553566206</pqid></control><display><type>article</type><title>Synthesis of Al/Cu core–shell particles through optimization of galvanic replacement method in alkaline solution</title><source>Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /></source><source>De Gruyter journals</source><creator>Ali, Rashid ; Ali, Fahad ; Zahoor, Aqib ; Nawaz Shahid, Rub ; ul HaqTariq, Naeem ; Ullah, Saad ; Mahmood, Arshad ; Shah, Attaullah ; Bin Awais, Hasan</creator><creatorcontrib>Ali, Rashid ; Ali, Fahad ; Zahoor, Aqib ; Nawaz Shahid, Rub ; ul HaqTariq, Naeem ; Ullah, Saad ; Mahmood, Arshad ; Shah, Attaullah ; Bin Awais, Hasan</creatorcontrib><description>In this work, Al/Cu core–shell particles were successfully synthesized through an optimized galvanic replacement method. For this purpose, a uniform and dense copper layer was deposited on aluminum particles in an alkaline solution. The effects of four deposition factors, i. e. (i) molar ratio EDTA-2Na/CuSO
· 5H
O, (ii) molar ratio CuCl
/Al powder, (iii)
and (iv) temperature were systematically studied and optimized using the Taguchi orthogonal (L9) method. It was observed that molar ratio EDTA-2Na/CuSO
· 5H
O and temperature are the most affecting factors in the deposition process. By increasing their levels, copper deposition increases within a specified time. The X-ray diffraction and scanning electron microscopy/ energy-dispersive X-ray spectroscopy results revealed the formation of homogeneous nanostructured Cu shells around Al particles. The results revealed that to achieve maximum copper deposition on Al powder; molar ratio EDTA-2Na. 2H
O/CuSO
. 5H
O, molar ratio CuCl
/Al powder,
and temperature of the deposition bath should be 2.0, 0.05, 8.8 and 55 °C, respectively.</description><identifier>ISSN: 1862-5282</identifier><identifier>ISSN: 2195-8556</identifier><identifier>EISSN: 2195-8556</identifier><identifier>DOI: 10.1515/ijmr-2020-8167</identifier><language>eng</language><publisher>BERLIN: De Gruyter</publisher><subject>Al/Cu core-shell ; Aluminum ; ANOVA ; Complexing agents ; Copper ; Copper chloride ; Copper sulfate ; Core-shell particles ; Deposition ; Ethylenediaminetetraacetic acids ; Galvanic replacement reaction ; Metallurgy & Metallurgical Engineering ; Optimization ; Science & Technology ; Taguchi method ; Taguchi methods ; Technology</subject><ispartof>International journal of materials research, 2021-05, Vol.112 (6), p.439-447</ispartof><rights>Copyright Carl Hanser Verlag Jun 2021</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>3</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000672580000002</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c320t-2237d9f39d7061f7ddb2ca5e162e3693557b64ab3a5e095dd566aa35e275da413</citedby><cites>FETCH-LOGICAL-c320t-2237d9f39d7061f7ddb2ca5e162e3693557b64ab3a5e095dd566aa35e275da413</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.degruyter.com/document/doi/10.1515/ijmr-2020-8167/pdf$$EPDF$$P50$$Gwalterdegruyter$$H</linktopdf><linktohtml>$$Uhttps://www.degruyter.com/document/doi/10.1515/ijmr-2020-8167/html$$EHTML$$P50$$Gwalterdegruyter$$H</linktohtml><link.rule.ids>315,782,786,27931,27932,39265,66761,68545</link.rule.ids></links><search><creatorcontrib>Ali, Rashid</creatorcontrib><creatorcontrib>Ali, Fahad</creatorcontrib><creatorcontrib>Zahoor, Aqib</creatorcontrib><creatorcontrib>Nawaz Shahid, Rub</creatorcontrib><creatorcontrib>ul HaqTariq, Naeem</creatorcontrib><creatorcontrib>Ullah, Saad</creatorcontrib><creatorcontrib>Mahmood, Arshad</creatorcontrib><creatorcontrib>Shah, Attaullah</creatorcontrib><creatorcontrib>Bin Awais, Hasan</creatorcontrib><title>Synthesis of Al/Cu core–shell particles through optimization of galvanic replacement method in alkaline solution</title><title>International journal of materials research</title><addtitle>INT J MATER RES</addtitle><description>In this work, Al/Cu core–shell particles were successfully synthesized through an optimized galvanic replacement method. For this purpose, a uniform and dense copper layer was deposited on aluminum particles in an alkaline solution. The effects of four deposition factors, i. e. (i) molar ratio EDTA-2Na/CuSO
· 5H
O, (ii) molar ratio CuCl
/Al powder, (iii)
and (iv) temperature were systematically studied and optimized using the Taguchi orthogonal (L9) method. It was observed that molar ratio EDTA-2Na/CuSO
· 5H
O and temperature are the most affecting factors in the deposition process. By increasing their levels, copper deposition increases within a specified time. The X-ray diffraction and scanning electron microscopy/ energy-dispersive X-ray spectroscopy results revealed the formation of homogeneous nanostructured Cu shells around Al particles. The results revealed that to achieve maximum copper deposition on Al powder; molar ratio EDTA-2Na. 2H
O/CuSO
. 5H
O, molar ratio CuCl
/Al powder,
and temperature of the deposition bath should be 2.0, 0.05, 8.8 and 55 °C, respectively.</description><subject>Al/Cu core-shell</subject><subject>Aluminum</subject><subject>ANOVA</subject><subject>Complexing agents</subject><subject>Copper</subject><subject>Copper chloride</subject><subject>Copper sulfate</subject><subject>Core-shell particles</subject><subject>Deposition</subject><subject>Ethylenediaminetetraacetic acids</subject><subject>Galvanic replacement reaction</subject><subject>Metallurgy & Metallurgical Engineering</subject><subject>Optimization</subject><subject>Science & Technology</subject><subject>Taguchi method</subject><subject>Taguchi methods</subject><subject>Technology</subject><issn>1862-5282</issn><issn>2195-8556</issn><issn>2195-8556</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><recordid>eNqNkMtu1DAUQC1EJYa2W9YWW5TWj7GTLFhUEY9KlVhA15bHuZl4cOxgO6BhxT_wh3xJnU7FDglvbF2dY10dhF5RckUFFdf2MMWKEUaqhsr6Gdow2oqqEUI-RxvaSFYJ1rAX6GVKB0JEYdgGxc9Hn0dINuEw4Bt33S3YhAh_fv1OIziHZx2zNQ4SzmMMy37EYc52sj91tsGv0l6779pbgyPMThuYwGc8QR5Dj63H2n3VznrAKbhldS7Q2aBdgsun-xzdv3_3pftY3X36cNvd3FWGM5IrxnjdtwNv-5pIOtR9v2NGC6CSAZctF6Leya3e8TIjreh7IaXWXACrRa-3lJ-j16d_5xi-LZCyKguGmJNiQvBCMyILdHWCTAwpRRjUHO2k41FRotasas2q1qxqzVqENyfhB-zCkIwFb-CvRAgpWUVDHg8rdPP_dGfzY9QuLD4X9e2Tql2G2MM-LsfyUIewRF_C_WNDSpnc8pY_AIyjovk</recordid><startdate>20210531</startdate><enddate>20210531</enddate><creator>Ali, Rashid</creator><creator>Ali, Fahad</creator><creator>Zahoor, Aqib</creator><creator>Nawaz Shahid, Rub</creator><creator>ul HaqTariq, Naeem</creator><creator>Ullah, Saad</creator><creator>Mahmood, Arshad</creator><creator>Shah, Attaullah</creator><creator>Bin Awais, Hasan</creator><general>De Gruyter</general><general>Walter De Gruyter</general><general>Carl Hanser Verlag</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20210531</creationdate><title>Synthesis of Al/Cu core–shell particles through optimization of galvanic replacement method in alkaline solution</title><author>Ali, Rashid ; Ali, Fahad ; Zahoor, Aqib ; Nawaz Shahid, Rub ; ul HaqTariq, Naeem ; Ullah, Saad ; Mahmood, Arshad ; Shah, Attaullah ; Bin Awais, Hasan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c320t-2237d9f39d7061f7ddb2ca5e162e3693557b64ab3a5e095dd566aa35e275da413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Al/Cu core-shell</topic><topic>Aluminum</topic><topic>ANOVA</topic><topic>Complexing agents</topic><topic>Copper</topic><topic>Copper chloride</topic><topic>Copper sulfate</topic><topic>Core-shell particles</topic><topic>Deposition</topic><topic>Ethylenediaminetetraacetic acids</topic><topic>Galvanic replacement reaction</topic><topic>Metallurgy & Metallurgical Engineering</topic><topic>Optimization</topic><topic>Science & Technology</topic><topic>Taguchi method</topic><topic>Taguchi methods</topic><topic>Technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ali, Rashid</creatorcontrib><creatorcontrib>Ali, Fahad</creatorcontrib><creatorcontrib>Zahoor, Aqib</creatorcontrib><creatorcontrib>Nawaz Shahid, Rub</creatorcontrib><creatorcontrib>ul HaqTariq, Naeem</creatorcontrib><creatorcontrib>Ullah, Saad</creatorcontrib><creatorcontrib>Mahmood, Arshad</creatorcontrib><creatorcontrib>Shah, Attaullah</creatorcontrib><creatorcontrib>Bin Awais, Hasan</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 2021</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>International journal of materials research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ali, Rashid</au><au>Ali, Fahad</au><au>Zahoor, Aqib</au><au>Nawaz Shahid, Rub</au><au>ul HaqTariq, Naeem</au><au>Ullah, Saad</au><au>Mahmood, Arshad</au><au>Shah, Attaullah</au><au>Bin Awais, Hasan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of Al/Cu core–shell particles through optimization of galvanic replacement method in alkaline solution</atitle><jtitle>International journal of materials research</jtitle><stitle>INT J MATER RES</stitle><date>2021-05-31</date><risdate>2021</risdate><volume>112</volume><issue>6</issue><spage>439</spage><epage>447</epage><pages>439-447</pages><issn>1862-5282</issn><issn>2195-8556</issn><eissn>2195-8556</eissn><abstract>In this work, Al/Cu core–shell particles were successfully synthesized through an optimized galvanic replacement method. For this purpose, a uniform and dense copper layer was deposited on aluminum particles in an alkaline solution. The effects of four deposition factors, i. e. (i) molar ratio EDTA-2Na/CuSO
· 5H
O, (ii) molar ratio CuCl
/Al powder, (iii)
and (iv) temperature were systematically studied and optimized using the Taguchi orthogonal (L9) method. It was observed that molar ratio EDTA-2Na/CuSO
· 5H
O and temperature are the most affecting factors in the deposition process. By increasing their levels, copper deposition increases within a specified time. The X-ray diffraction and scanning electron microscopy/ energy-dispersive X-ray spectroscopy results revealed the formation of homogeneous nanostructured Cu shells around Al particles. The results revealed that to achieve maximum copper deposition on Al powder; molar ratio EDTA-2Na. 2H
O/CuSO
. 5H
O, molar ratio CuCl
/Al powder,
and temperature of the deposition bath should be 2.0, 0.05, 8.8 and 55 °C, respectively.</abstract><cop>BERLIN</cop><pub>De Gruyter</pub><doi>10.1515/ijmr-2020-8167</doi><tpages>9</tpages></addata></record> |
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| source | Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" />; De Gruyter journals |
| subjects | Al/Cu core-shell Aluminum ANOVA Complexing agents Copper Copper chloride Copper sulfate Core-shell particles Deposition Ethylenediaminetetraacetic acids Galvanic replacement reaction Metallurgy & Metallurgical Engineering Optimization Science & Technology Taguchi method Taguchi methods Technology |
| title | Synthesis of Al/Cu core–shell particles through optimization of galvanic replacement method in alkaline solution |
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