Achiral and chiral NNN-pincer nickel complexes with oxazolinyl backbones: application in transfer hydrogenation of ketones

We describe the synthesis of new NNN-oxazolinyl-pincer nickel complexes and their application in the transfer hydrogenation of ketones. Achiral NNN-ligands, R′ 2 -oxazolinyl-2-C 6 H 4 -NH-C(O)CH 2 NEt 2 [( R′2-Ox NNN Et2 )-H; R' = H ( 3a ), R′ = Me ( 3b )], and chiral ligands, ( R )-R′-oxazolin...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	New journal of chemistry 2021-07, Vol.45 (27), p.11927-11936
Hauptverfasser:	Jagtap, Rahul A, Ankade, Shidheshwar B, Gonnade, Rajesh G, Punji, Benudhar
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Chemistry Chemistry, Multidisciplinary Coordination compounds Crystallography Enantiomers Hydrogenation Ketones Ligands Molecular structure Nickel NMR Nuclear magnetic resonance Physical Sciences Science & Technology
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!