Diethylene triamine penta methylene phosphonic acid encountered silver ions: a convenient method for preparation of flame retardant and antibacterial lyocell fabric
Ammonium salt of diethylene triamine penta methylene phosphonic acid (ADTPMPA), a novel flame retardant, was synthesized and grafted on the lyocell fabric to obtain a kind of flame retardant lyocell fabric (FR-lyocell). Then FR-lyocell was coated by Ag nanoparticles (Ag NPs) to fabricate flame retar...
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| Veröffentlicht in: | Cellulose (London) 2021-07, Vol.28 (11), p.7465-7481 |
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| creator | Xiao, Mengyuan Guo, Yingbin Zhang, Jiayue Liu, Yansong Ren, Yuanlin Liu, Xiaohui |
| description | Ammonium salt of diethylene triamine penta methylene phosphonic acid (ADTPMPA), a novel flame retardant, was synthesized and grafted on the lyocell fabric to obtain a kind of flame retardant lyocell fabric (FR-lyocell). Then FR-lyocell was coated by Ag nanoparticles (Ag NPs) to fabricate flame retardant and antibacterial lyocell fabric (FR-Ag-lyocell). The elemental composition, surface morphology, combustion behavior and antibacterial activity of the lyocell fabric before and after modification were investigated. The flame retardant and antibacterial mechanism of FR-Ag-lyocell fabric was also analyzed. The limiting oxygen index (LOI) values of FR-Ag-lyocell fabric before and after 20 laundering cycles (LCs) reached 44.8% and 31.3%, respectively. The treated lyocell fabric possessed lower peak of heat release rate (pHRR) and total heat release (THR) values compared with control lyocell fabric. The FR-Ag-lyocell fabric exhibited excellent antimicrobial ability against Staphylococcus aureus (
S. aureus
) and Escherichia coli (
E. coli
), even after 10 LCs. These results indicated that FR-Ag-lyocell fabric had durable flame retardant and antibacterial properties.
Graphic abstract |
| doi_str_mv | 10.1007/s10570-021-04000-8 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_webof</sourceid><recordid>TN_cdi_webofscience_primary_000662150200004</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2551804193</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-53abc2083d35c462088577c3c10ec63b4ebc1c60f79572af438296d5232e6d943</originalsourceid><addsrcrecordid>eNqNkc2KFTEQhYMoeB19AVcBl9Kan0534k6u4w8MuFFwF9LpipOhb9ImuSP3fXxQa27LuBMXRQrqO5XkHEKec_aKMza-rpypkXVM8I71jLFOPyA7rkbRaS2-PSQ7ZgaDY2kekye13iBiRsF35Ne7CO36tEAC2kp0h4jNCqk5ergfrNe5YqXoqfNxppB8PqYGBWZa43ILhcac6hvqqM_pFlLEBWd9nmnIha4FVldcQ4rmQMPiDkALNFdmh6RLM1aLk_O4NLqFLqfsYVlocFOJ_il5FNxS4dmf84J8fX_5Zf-xu_r84dP-7VXnJTetU9JNXjAtZ6l8P2Cn1Th66TkDP8iph8lzP7AwGnTGhV5qYYZZCSlgmE0vL8iLbe9a8o8j1GZv8rEkvNIKpbhmPTcSKbFRvuRaCwS7lnhw5WQ5s3dp2C0Ni2nYcxpWo0hvop8w5VA9OuThXojMMAiumMCO9fvYzl7t71xG6cv_lyItN7oikb5D-fuHfzzvN6pvsT0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2551804193</pqid></control><display><type>article</type><title>Diethylene triamine penta methylene phosphonic acid encountered silver ions: a convenient method for preparation of flame retardant and antibacterial lyocell fabric</title><source>SpringerNature Journals</source><source>Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /></source><creator>Xiao, Mengyuan ; Guo, Yingbin ; Zhang, Jiayue ; Liu, Yansong ; Ren, Yuanlin ; Liu, Xiaohui</creator><creatorcontrib>Xiao, Mengyuan ; Guo, Yingbin ; Zhang, Jiayue ; Liu, Yansong ; Ren, Yuanlin ; Liu, Xiaohui</creatorcontrib><description>Ammonium salt of diethylene triamine penta methylene phosphonic acid (ADTPMPA), a novel flame retardant, was synthesized and grafted on the lyocell fabric to obtain a kind of flame retardant lyocell fabric (FR-lyocell). Then FR-lyocell was coated by Ag nanoparticles (Ag NPs) to fabricate flame retardant and antibacterial lyocell fabric (FR-Ag-lyocell). The elemental composition, surface morphology, combustion behavior and antibacterial activity of the lyocell fabric before and after modification were investigated. The flame retardant and antibacterial mechanism of FR-Ag-lyocell fabric was also analyzed. The limiting oxygen index (LOI) values of FR-Ag-lyocell fabric before and after 20 laundering cycles (LCs) reached 44.8% and 31.3%, respectively. The treated lyocell fabric possessed lower peak of heat release rate (pHRR) and total heat release (THR) values compared with control lyocell fabric. The FR-Ag-lyocell fabric exhibited excellent antimicrobial ability against Staphylococcus aureus (
S. aureus
) and Escherichia coli (
E. coli
), even after 10 LCs. These results indicated that FR-Ag-lyocell fabric had durable flame retardant and antibacterial properties.
Graphic abstract</description><identifier>ISSN: 0969-0239</identifier><identifier>EISSN: 1572-882X</identifier><identifier>DOI: 10.1007/s10570-021-04000-8</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Bioorganic Chemistry ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Diethylene triamine ; E coli ; Enthalpy ; Flame retardants ; Glass ; Heat release rate ; Materials Science ; Materials Science, Paper & Wood ; Materials Science, Textiles ; Methylene ; Morphology ; Nanoparticles ; Natural Materials ; Organic Chemistry ; Original Research ; Phosphonic acids ; Physical Chemistry ; Physical Sciences ; Polymer Science ; Polymer Sciences ; Science & Technology ; Silver ; Sustainable Development ; Technology</subject><ispartof>Cellulose (London), 2021-07, Vol.28 (11), p.7465-7481</ispartof><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021</rights><rights>The Author(s), under exclusive licence to Springer Nature B.V. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>31</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000662150200004</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c319t-53abc2083d35c462088577c3c10ec63b4ebc1c60f79572af438296d5232e6d943</citedby><cites>FETCH-LOGICAL-c319t-53abc2083d35c462088577c3c10ec63b4ebc1c60f79572af438296d5232e6d943</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10570-021-04000-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10570-021-04000-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27931,27932,39265,41495,42564,51326</link.rule.ids></links><search><creatorcontrib>Xiao, Mengyuan</creatorcontrib><creatorcontrib>Guo, Yingbin</creatorcontrib><creatorcontrib>Zhang, Jiayue</creatorcontrib><creatorcontrib>Liu, Yansong</creatorcontrib><creatorcontrib>Ren, Yuanlin</creatorcontrib><creatorcontrib>Liu, Xiaohui</creatorcontrib><title>Diethylene triamine penta methylene phosphonic acid encountered silver ions: a convenient method for preparation of flame retardant and antibacterial lyocell fabric</title><title>Cellulose (London)</title><addtitle>Cellulose</addtitle><addtitle>CELLULOSE</addtitle><description>Ammonium salt of diethylene triamine penta methylene phosphonic acid (ADTPMPA), a novel flame retardant, was synthesized and grafted on the lyocell fabric to obtain a kind of flame retardant lyocell fabric (FR-lyocell). Then FR-lyocell was coated by Ag nanoparticles (Ag NPs) to fabricate flame retardant and antibacterial lyocell fabric (FR-Ag-lyocell). The elemental composition, surface morphology, combustion behavior and antibacterial activity of the lyocell fabric before and after modification were investigated. The flame retardant and antibacterial mechanism of FR-Ag-lyocell fabric was also analyzed. The limiting oxygen index (LOI) values of FR-Ag-lyocell fabric before and after 20 laundering cycles (LCs) reached 44.8% and 31.3%, respectively. The treated lyocell fabric possessed lower peak of heat release rate (pHRR) and total heat release (THR) values compared with control lyocell fabric. The FR-Ag-lyocell fabric exhibited excellent antimicrobial ability against Staphylococcus aureus (
S. aureus
) and Escherichia coli (
E. coli
), even after 10 LCs. These results indicated that FR-Ag-lyocell fabric had durable flame retardant and antibacterial properties.
Graphic abstract</description><subject>Bioorganic Chemistry</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Diethylene triamine</subject><subject>E coli</subject><subject>Enthalpy</subject><subject>Flame retardants</subject><subject>Glass</subject><subject>Heat release rate</subject><subject>Materials Science</subject><subject>Materials Science, Paper & Wood</subject><subject>Materials Science, Textiles</subject><subject>Methylene</subject><subject>Morphology</subject><subject>Nanoparticles</subject><subject>Natural Materials</subject><subject>Organic Chemistry</subject><subject>Original Research</subject><subject>Phosphonic acids</subject><subject>Physical Chemistry</subject><subject>Physical Sciences</subject><subject>Polymer Science</subject><subject>Polymer Sciences</subject><subject>Science & Technology</subject><subject>Silver</subject><subject>Sustainable Development</subject><subject>Technology</subject><issn>0969-0239</issn><issn>1572-882X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqNkc2KFTEQhYMoeB19AVcBl9Kan0534k6u4w8MuFFwF9LpipOhb9ImuSP3fXxQa27LuBMXRQrqO5XkHEKec_aKMza-rpypkXVM8I71jLFOPyA7rkbRaS2-PSQ7ZgaDY2kekye13iBiRsF35Ne7CO36tEAC2kp0h4jNCqk5ergfrNe5YqXoqfNxppB8PqYGBWZa43ILhcac6hvqqM_pFlLEBWd9nmnIha4FVldcQ4rmQMPiDkALNFdmh6RLM1aLk_O4NLqFLqfsYVlocFOJ_il5FNxS4dmf84J8fX_5Zf-xu_r84dP-7VXnJTetU9JNXjAtZ6l8P2Cn1Th66TkDP8iph8lzP7AwGnTGhV5qYYZZCSlgmE0vL8iLbe9a8o8j1GZv8rEkvNIKpbhmPTcSKbFRvuRaCwS7lnhw5WQ5s3dp2C0Ni2nYcxpWo0hvop8w5VA9OuThXojMMAiumMCO9fvYzl7t71xG6cv_lyItN7oikb5D-fuHfzzvN6pvsT0</recordid><startdate>20210701</startdate><enddate>20210701</enddate><creator>Xiao, Mengyuan</creator><creator>Guo, Yingbin</creator><creator>Zhang, Jiayue</creator><creator>Liu, Yansong</creator><creator>Ren, Yuanlin</creator><creator>Liu, Xiaohui</creator><general>Springer Netherlands</general><general>Springer Nature</general><general>Springer Nature B.V</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20210701</creationdate><title>Diethylene triamine penta methylene phosphonic acid encountered silver ions: a convenient method for preparation of flame retardant and antibacterial lyocell fabric</title><author>Xiao, Mengyuan ; Guo, Yingbin ; Zhang, Jiayue ; Liu, Yansong ; Ren, Yuanlin ; Liu, Xiaohui</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-53abc2083d35c462088577c3c10ec63b4ebc1c60f79572af438296d5232e6d943</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Bioorganic Chemistry</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Diethylene triamine</topic><topic>E coli</topic><topic>Enthalpy</topic><topic>Flame retardants</topic><topic>Glass</topic><topic>Heat release rate</topic><topic>Materials Science</topic><topic>Materials Science, Paper & Wood</topic><topic>Materials Science, Textiles</topic><topic>Methylene</topic><topic>Morphology</topic><topic>Nanoparticles</topic><topic>Natural Materials</topic><topic>Organic Chemistry</topic><topic>Original Research</topic><topic>Phosphonic acids</topic><topic>Physical Chemistry</topic><topic>Physical Sciences</topic><topic>Polymer Science</topic><topic>Polymer Sciences</topic><topic>Science & Technology</topic><topic>Silver</topic><topic>Sustainable Development</topic><topic>Technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xiao, Mengyuan</creatorcontrib><creatorcontrib>Guo, Yingbin</creatorcontrib><creatorcontrib>Zhang, Jiayue</creatorcontrib><creatorcontrib>Liu, Yansong</creatorcontrib><creatorcontrib>Ren, Yuanlin</creatorcontrib><creatorcontrib>Liu, Xiaohui</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 2021</collection><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Cellulose (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiao, Mengyuan</au><au>Guo, Yingbin</au><au>Zhang, Jiayue</au><au>Liu, Yansong</au><au>Ren, Yuanlin</au><au>Liu, Xiaohui</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Diethylene triamine penta methylene phosphonic acid encountered silver ions: a convenient method for preparation of flame retardant and antibacterial lyocell fabric</atitle><jtitle>Cellulose (London)</jtitle><stitle>Cellulose</stitle><stitle>CELLULOSE</stitle><date>2021-07-01</date><risdate>2021</risdate><volume>28</volume><issue>11</issue><spage>7465</spage><epage>7481</epage><pages>7465-7481</pages><issn>0969-0239</issn><eissn>1572-882X</eissn><abstract>Ammonium salt of diethylene triamine penta methylene phosphonic acid (ADTPMPA), a novel flame retardant, was synthesized and grafted on the lyocell fabric to obtain a kind of flame retardant lyocell fabric (FR-lyocell). Then FR-lyocell was coated by Ag nanoparticles (Ag NPs) to fabricate flame retardant and antibacterial lyocell fabric (FR-Ag-lyocell). The elemental composition, surface morphology, combustion behavior and antibacterial activity of the lyocell fabric before and after modification were investigated. The flame retardant and antibacterial mechanism of FR-Ag-lyocell fabric was also analyzed. The limiting oxygen index (LOI) values of FR-Ag-lyocell fabric before and after 20 laundering cycles (LCs) reached 44.8% and 31.3%, respectively. The treated lyocell fabric possessed lower peak of heat release rate (pHRR) and total heat release (THR) values compared with control lyocell fabric. The FR-Ag-lyocell fabric exhibited excellent antimicrobial ability against Staphylococcus aureus (
S. aureus
) and Escherichia coli (
E. coli
), even after 10 LCs. These results indicated that FR-Ag-lyocell fabric had durable flame retardant and antibacterial properties.
Graphic abstract</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10570-021-04000-8</doi><tpages>17</tpages></addata></record> |
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| ispartof | Cellulose (London), 2021-07, Vol.28 (11), p.7465-7481 |
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| source | SpringerNature Journals; Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /> |
| subjects | Bioorganic Chemistry Ceramics Chemistry Chemistry and Materials Science Composites Diethylene triamine E coli Enthalpy Flame retardants Glass Heat release rate Materials Science Materials Science, Paper & Wood Materials Science, Textiles Methylene Morphology Nanoparticles Natural Materials Organic Chemistry Original Research Phosphonic acids Physical Chemistry Physical Sciences Polymer Science Polymer Sciences Science & Technology Silver Sustainable Development Technology |
| title | Diethylene triamine penta methylene phosphonic acid encountered silver ions: a convenient method for preparation of flame retardant and antibacterial lyocell fabric |
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