Exploring Metastable Oxynitrides by Thin Film Growth Approach
Metal oxynitrides are expected to show unique chemical and physical properties suitable for various applications. However, compared with oxides, the chemical space of oxynitrides has not been well explored mainly due to their thermal instability and high reaction temperature required in conventional...
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| Veröffentlicht in: | Bulletin of the Chemical Society of Japan 2021, Vol.94 (4), p.1355-1363 |
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| container_title | Bulletin of the Chemical Society of Japan |
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| creator | Hirose, Yasushi Hasegawa, Tetsuya |
| description | Metal oxynitrides are expected to show unique chemical and physical properties suitable for various applications. However, compared with oxides, the chemical space of oxynitrides has not been well explored mainly due to their thermal instability and high reaction temperature required in conventional bulk synthesis methods. Highly nonequilibrium thin film growth is a promising route for obtaining those unexplored oxynitrides. In this account, we will overview recent studies on thin film synthesis of oxynitrides, especially focusing on exploration of metastable phases, such as mid- and late-transition metal compounds, metastable polymorphs, geometrical isomers with respect to anion coordination, and amorphous phases. |
| doi_str_mv | 10.1246/bcsj.20210033 |
| format | Article |
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| source | Oxford University Press Journals All Titles (1996-Current); Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /> |
| subjects | Chemistry Chemistry, Multidisciplinary Film growth Frontiers of Molecular Science Isomers Metal compounds Metastable phases Oxynitrides Physical properties Physical Sciences Science & Technology Thermal instability Thin films Transition metal compounds |
| title | Exploring Metastable Oxynitrides by Thin Film Growth Approach |
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