Study of Magnetic and Electrical Properties of Poly(o-phenylenediamine)/Manganese Substituted ZnFe2O4 Nanocomposites
Different concentrations of ZnFe 2 O 4 and manganese substituted ZnFe 2 O 4 nanoparticles (10%, 20% and 30%) dispersed poly( o -phenylenediamine) (PoPD)/ferrite nanocomposites have been prepared by in-situ oxidative polymerization method. The synthesized nanocomposites have been characterized by spe...
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| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2021-08, Vol.31 (8), p.3441-3459 |
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| container_title | Journal of inorganic and organometallic polymers and materials |
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| creator | Kannapiran, Nagarajan Muthusamy, Athianna Meena, Sher Singh |
| description | Different concentrations of ZnFe
2
O
4
and manganese substituted ZnFe
2
O
4
nanoparticles (10%, 20% and 30%) dispersed poly(
o
-phenylenediamine) (PoPD)/ferrite nanocomposites have been prepared by in-situ oxidative polymerization method. The synthesized nanocomposites have been characterized by spectroscopic, microscopic techniques, thermal and dielectric properties analyzed at different temperature and frequency. The XRD pattern revealed that there is a good interaction between PoPD and ferrite nanoparticles. The crystalline size of ferrite nanoparticles are changed when it is dispersed in PoPD. The morphology of PoPD is modified by ZnFe
2
O
4
nanoparticles into sheet like morphology. The Mössbauer spectra of ferrite nanoparticles are indicated that iron present in Fe
3+
high spin state. The magnetic studies of ferrite nanoparticles and PoPD/ferrite nanocomposites are exhibited ferromagnetic magnetic nature and saturation magnetization of PoPD/ferrite nanocomposites increases with increase concentration of nanoparticles. The PoPD/ZnFe
2
O
4
has higher dielectric constant than PoPD/MnZnFe
2
O
4
. The AC conductivity of PoPD/ferrite nanocomposites are increased with increasing in frequency and temperature. |
| doi_str_mv | 10.1007/s10904-021-02020-2 |
| format | Article |
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2
O
4
and manganese substituted ZnFe
2
O
4
nanoparticles (10%, 20% and 30%) dispersed poly(
o
-phenylenediamine) (PoPD)/ferrite nanocomposites have been prepared by in-situ oxidative polymerization method. The synthesized nanocomposites have been characterized by spectroscopic, microscopic techniques, thermal and dielectric properties analyzed at different temperature and frequency. The XRD pattern revealed that there is a good interaction between PoPD and ferrite nanoparticles. The crystalline size of ferrite nanoparticles are changed when it is dispersed in PoPD. The morphology of PoPD is modified by ZnFe
2
O
4
nanoparticles into sheet like morphology. The Mössbauer spectra of ferrite nanoparticles are indicated that iron present in Fe
3+
high spin state. The magnetic studies of ferrite nanoparticles and PoPD/ferrite nanocomposites are exhibited ferromagnetic magnetic nature and saturation magnetization of PoPD/ferrite nanocomposites increases with increase concentration of nanoparticles. The PoPD/ZnFe
2
O
4
has higher dielectric constant than PoPD/MnZnFe
2
O
4
. The AC conductivity of PoPD/ferrite nanocomposites are increased with increasing in frequency and temperature.</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-021-02020-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Dielectric properties ; Dispersion ; Electrical properties ; Ferromagnetism ; Inorganic Chemistry ; Magnetic properties ; Magnetic saturation ; Manganese ; Morphology ; Nanocomposites ; Nanoparticles ; Organic Chemistry ; Phenylenediamine ; Physical Sciences ; Polymer Science ; Polymer Sciences ; Science & Technology ; Substitutes ; Zinc ferrites</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2021-08, Vol.31 (8), p.3441-3459</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>3</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000650822300001</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c319t-be3e08c9ecf1485e48f632e98feb917095b990ccf5b1b7410b75645230a49b3f3</citedby><cites>FETCH-LOGICAL-c319t-be3e08c9ecf1485e48f632e98feb917095b990ccf5b1b7410b75645230a49b3f3</cites><orcidid>0000-0003-4978-2528</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-021-02020-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-021-02020-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,781,785,27929,27930,39263,41493,42562,51324</link.rule.ids></links><search><creatorcontrib>Kannapiran, Nagarajan</creatorcontrib><creatorcontrib>Muthusamy, Athianna</creatorcontrib><creatorcontrib>Meena, Sher Singh</creatorcontrib><title>Study of Magnetic and Electrical Properties of Poly(o-phenylenediamine)/Manganese Substituted ZnFe2O4 Nanocomposites</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><addtitle>J INORG ORGANOMET P</addtitle><description>Different concentrations of ZnFe
2
O
4
and manganese substituted ZnFe
2
O
4
nanoparticles (10%, 20% and 30%) dispersed poly(
o
-phenylenediamine) (PoPD)/ferrite nanocomposites have been prepared by in-situ oxidative polymerization method. The synthesized nanocomposites have been characterized by spectroscopic, microscopic techniques, thermal and dielectric properties analyzed at different temperature and frequency. The XRD pattern revealed that there is a good interaction between PoPD and ferrite nanoparticles. The crystalline size of ferrite nanoparticles are changed when it is dispersed in PoPD. The morphology of PoPD is modified by ZnFe
2
O
4
nanoparticles into sheet like morphology. The Mössbauer spectra of ferrite nanoparticles are indicated that iron present in Fe
3+
high spin state. The magnetic studies of ferrite nanoparticles and PoPD/ferrite nanocomposites are exhibited ferromagnetic magnetic nature and saturation magnetization of PoPD/ferrite nanocomposites increases with increase concentration of nanoparticles. The PoPD/ZnFe
2
O
4
has higher dielectric constant than PoPD/MnZnFe
2
O
4
. The AC conductivity of PoPD/ferrite nanocomposites are increased with increasing in frequency and temperature.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dielectric properties</subject><subject>Dispersion</subject><subject>Electrical properties</subject><subject>Ferromagnetism</subject><subject>Inorganic Chemistry</subject><subject>Magnetic properties</subject><subject>Magnetic saturation</subject><subject>Manganese</subject><subject>Morphology</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Organic Chemistry</subject><subject>Phenylenediamine</subject><subject>Physical Sciences</subject><subject>Polymer Science</subject><subject>Polymer Sciences</subject><subject>Science & Technology</subject><subject>Substitutes</subject><subject>Zinc ferrites</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><recordid>eNqNkE1rFTEUhoeiYG39A64G3Cgy9uTrzmQpl1aFfkF1001Ick9uU-YmY5JB7r837UjdlSaEk8XzJOe8TfOewBcC0J9kAhJ4B5TUU3dHD5pDInreES7Iq6c7Z2-atznfA7ABBDlsyk2ZN_s2uvZCbwMWb1sdNu3piLYkb_XYXqc4YSoe8wN1Hcf9x9hNdxj2IwbceL3zAT-dXOiw1QEztjezycWXueCmvQ1nSK94e6lDtHE3xewL5uPmtdNjxnf_6lHz6-z05_p7d3717cf663lnGZGlM8gQBivROsIHgXxwK0ZRDg6NJD1IYaQEa50wxPScgOnFigvKQHNpmGNHzYfl3SnF3zPmou7jnEL9UlEh2MAoW8lK0YWyKeac0Kkp-Z1Oe0VAPaSrlnRVTVc9pqtolYZF-oMmumw9BotPIgCsBAy0tlIXWfuii49hHedQqvr55Wql2ULnSoQtpv8zPNPeX1VDnkA</recordid><startdate>20210801</startdate><enddate>20210801</enddate><creator>Kannapiran, Nagarajan</creator><creator>Muthusamy, Athianna</creator><creator>Meena, Sher Singh</creator><general>Springer US</general><general>Springer Nature</general><general>Springer Nature B.V</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-4978-2528</orcidid></search><sort><creationdate>20210801</creationdate><title>Study of Magnetic and Electrical Properties of Poly(o-phenylenediamine)/Manganese Substituted ZnFe2O4 Nanocomposites</title><author>Kannapiran, Nagarajan ; Muthusamy, Athianna ; Meena, Sher Singh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-be3e08c9ecf1485e48f632e98feb917095b990ccf5b1b7410b75645230a49b3f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dielectric properties</topic><topic>Dispersion</topic><topic>Electrical properties</topic><topic>Ferromagnetism</topic><topic>Inorganic Chemistry</topic><topic>Magnetic properties</topic><topic>Magnetic saturation</topic><topic>Manganese</topic><topic>Morphology</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Organic Chemistry</topic><topic>Phenylenediamine</topic><topic>Physical Sciences</topic><topic>Polymer Science</topic><topic>Polymer Sciences</topic><topic>Science & Technology</topic><topic>Substitutes</topic><topic>Zinc ferrites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kannapiran, Nagarajan</creatorcontrib><creatorcontrib>Muthusamy, Athianna</creatorcontrib><creatorcontrib>Meena, Sher Singh</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 2021</collection><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kannapiran, Nagarajan</au><au>Muthusamy, Athianna</au><au>Meena, Sher Singh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study of Magnetic and Electrical Properties of Poly(o-phenylenediamine)/Manganese Substituted ZnFe2O4 Nanocomposites</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><stitle>J INORG ORGANOMET P</stitle><date>2021-08-01</date><risdate>2021</risdate><volume>31</volume><issue>8</issue><spage>3441</spage><epage>3459</epage><pages>3441-3459</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>Different concentrations of ZnFe
2
O
4
and manganese substituted ZnFe
2
O
4
nanoparticles (10%, 20% and 30%) dispersed poly(
o
-phenylenediamine) (PoPD)/ferrite nanocomposites have been prepared by in-situ oxidative polymerization method. The synthesized nanocomposites have been characterized by spectroscopic, microscopic techniques, thermal and dielectric properties analyzed at different temperature and frequency. The XRD pattern revealed that there is a good interaction between PoPD and ferrite nanoparticles. The crystalline size of ferrite nanoparticles are changed when it is dispersed in PoPD. The morphology of PoPD is modified by ZnFe
2
O
4
nanoparticles into sheet like morphology. The Mössbauer spectra of ferrite nanoparticles are indicated that iron present in Fe
3+
high spin state. The magnetic studies of ferrite nanoparticles and PoPD/ferrite nanocomposites are exhibited ferromagnetic magnetic nature and saturation magnetization of PoPD/ferrite nanocomposites increases with increase concentration of nanoparticles. The PoPD/ZnFe
2
O
4
has higher dielectric constant than PoPD/MnZnFe
2
O
4
. The AC conductivity of PoPD/ferrite nanocomposites are increased with increasing in frequency and temperature.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-021-02020-2</doi><tpages>19</tpages><orcidid>https://orcid.org/0000-0003-4978-2528</orcidid></addata></record> |
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| subjects | Chemistry Chemistry and Materials Science Dielectric properties Dispersion Electrical properties Ferromagnetism Inorganic Chemistry Magnetic properties Magnetic saturation Manganese Morphology Nanocomposites Nanoparticles Organic Chemistry Phenylenediamine Physical Sciences Polymer Science Polymer Sciences Science & Technology Substitutes Zinc ferrites |
| title | Study of Magnetic and Electrical Properties of Poly(o-phenylenediamine)/Manganese Substituted ZnFe2O4 Nanocomposites |
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