The late Paleozoic Ice Age along the southwestern margin of Gondwana: Facies models, age constraints, correlation and sequence stratigraphic framework

The southwestern margin of South America offers a complete record of the Late Paleozoic Ice Age (LPIA) that affected the Gondwana supercontinent. The tripartite division of LPIA glacial episodes has been refined with the help of new radiometric dates and biostratigraphic (flora and fauna) zonations in recent years to five shorter-lived discrete events: 1. Latest Devonian-earliest Tournaisian, 2. Tournaisian, 3. Visean, 4. Serpukhovian-Early Bashkirian, 5. late Pennsylvanian-earliest Permian. These glacial events are capped by postglacial transgressive deposits with marine fauna. The unbalanced preservation potential of the glacial deposits, skewed toward the glaciomarine sediments, provides an uneven stratigraphic record with few cases of continental glacial sedimentation, confined to the Serpukhovian-Early Bashkirian event, and numerous examples of glacial sedimentation in marine environments. Glacial sedimentation in marine settings has been grouped in two main facies associations: a valley-glacier-retreat (fjord) facies association and a submarine-retreat (glaciomarine apron) facies association in open-marine areas. Transitional facies, correspondent to those formed by the flooding of valleys during postglacial transgressions, are widely distributed along the Protoprecordillera in western Argentina, where paleofjord successions are well exposed particularly in western Paganzo Basin, and mapped in subsurface in the Tarija basin. A general paleofjord model includes (from base to top) the following stages: (i) Incision of paleovalley and deposition of subglacial diamictites in ice contact deltas, (ii) Early Transgressive stage characterized by resedimentation of subglacial material by subaqueous sediment gravity flows and slumps in proglacial settings, (iii) Maximum flooding (late transgressive stage) dominated by black shales or laminated mudstones related to a marine incursion that flooded valleys; normal marine or brackish conditions may dominate this stage and (iv) Highstand: progradation of a fluvial-deltaic system including in some cases Gilbert-type deltas. In glaciomarine apron environments, the basal facies includes massive clast-supported conglomerates, with few striated and polished clasts, followed by fining-upward successions including thinly bedded diamictites with ice-rafted debris (IRD) and locally contorted sandstone masses in diamictite beds, indicative of mass-emplacement mechanisms. The presence of inter- and intratill pavements suggest