Mechanism of Synthesis and Structure Formation of Hybrid Oligomers Based on Complex Oligophenylene Compounds with Metals

The reaction mechanism of the formation of hybrid oligomers based on complexes compounds of metal and oligophenylene is considered. The structure of compounds formed in such a reaction is determined. The effect of the addition of dimethyl sulfoxide on the increase in the yield of the main reaction p...

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Veröffentlicht in:Journal of superhard materials 2020-11, Vol.42 (6), p.443-445
Hauptverfasser: Savchenko, D. O., Pashchenko, E. O., Kaidash, O. M., Kukharenko, S. A., Buriachek, O. V., Rumiantseva, Yu. Yu, Skorokhod, S. V., Romanenko, Y. M.
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container_end_page 445
container_issue 6
container_start_page 443
container_title Journal of superhard materials
container_volume 42
creator Savchenko, D. O.
Pashchenko, E. O.
Kaidash, O. M.
Kukharenko, S. A.
Buriachek, O. V.
Rumiantseva, Yu. Yu
Skorokhod, S. V.
Romanenko, Y. M.
description The reaction mechanism of the formation of hybrid oligomers based on complexes compounds of metal and oligophenylene is considered. The structure of compounds formed in such a reaction is determined. The effect of the addition of dimethyl sulfoxide on the increase in the yield of the main reaction product was found, and a mechanism of this effect was proposed, based on the change in the conformational features of oligophenylene in the synthesis process. The produced oligomers are promising as binders for composites of superhard materials.
doi_str_mv 10.3103/S106345762006009X
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subjects Chemistry
Chemistry and Materials Science
Coordination compounds
Dimethyl sulfoxide
Letters to the Editor
Materials Science
Materials Science, Multidisciplinary
Oligomers
Physical Chemistry
Reaction mechanisms
Reaction products
Science & Technology
Synthesis
Technology
title Mechanism of Synthesis and Structure Formation of Hybrid Oligomers Based on Complex Oligophenylene Compounds with Metals
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