Helpful correlations to estimate the pKa of coordinated HNO: a potential-pH exploration in a pendant-arm cyclam-based ruthenium nitroxyl

The acid-base speciation of coordinated azanone (HNO) remains a highly relevant topic in bioinorganic chemistry. Ruthenium nitroxyl complexes with sufficient robustness towards ligand loss have gained significance as operating platforms to delve into such studies. In this work, we revisit an octahed...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2021-02, Vol.50 (5), p.1641-1650
Hauptverfasser:	Perdomenico, Julian, Ruiz, Mariano M., Osa Codesido, Nicolas, De Candia, Ariel G., Marcolongo, Juan P., Slep, Leonardo D.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aqueous solutions Chemistry Chemistry, Inorganic & Nuclear Electrochemical analysis Ligands Physical Sciences Ruthenium Science & Technology Speciation
Online-Zugang:	Volltext
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