Synthesis and Properties of Nanostructured Tungsten Oxide on Au(111)

WO3 nanostructures have been synthesized on Au(111) through the solution-processing method. Three types of structures have been obtained: reticulated polymeric structures, two dimensional WO3 (111), and three-dimensional islands. Their electronic properties have been probed by scanning tunneling spe...

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Veröffentlicht in:Journal of physical chemistry. C 2021-01, Vol.125 (1), p.660-666
Hauptverfasser: Harsh, Rishav, Ben Youssef, Mariem, Chacon, Cyril, Repain, Vincent, Bellec, Amandine, Girard, Yann, Rousset, Sylvie, Piquemal, Jean-Yves, Seydou, Mahamadou, Decorse, Philippe, Lang, Philippe, Lagoute, Jerome
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container_end_page 666
container_issue 1
container_start_page 660
container_title Journal of physical chemistry. C
container_volume 125
creator Harsh, Rishav
Ben Youssef, Mariem
Chacon, Cyril
Repain, Vincent
Bellec, Amandine
Girard, Yann
Rousset, Sylvie
Piquemal, Jean-Yves
Seydou, Mahamadou
Decorse, Philippe
Lang, Philippe
Lagoute, Jerome
description WO3 nanostructures have been synthesized on Au(111) through the solution-processing method. Three types of structures have been obtained: reticulated polymeric structures, two dimensional WO3 (111), and three-dimensional islands. Their electronic properties have been probed by scanning tunneling spectroscopy. The reticulated structure has a featureless spectrum. WO3 (111) shows n-type semiconducting properties with resonances corresponding to surface states arising from W 5d states. These oxide nanostructures efficiently decouple the electronic states of molecular adsorbates from the metal substrate.
doi_str_mv 10.1021/acs.jpcc.0c10258
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source American Chemical Society Journals
subjects Chemistry
Chemistry, Physical
Condensed Matter
Materials Science
Materials Science, Multidisciplinary
Nanoscience & Nanotechnology
Physical Sciences
Physics
Science & Technology
Science & Technology - Other Topics
Technology
title Synthesis and Properties of Nanostructured Tungsten Oxide on Au(111)
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