Synthesis and Properties of Nanostructured Tungsten Oxide on Au(111)
WO3 nanostructures have been synthesized on Au(111) through the solution-processing method. Three types of structures have been obtained: reticulated polymeric structures, two dimensional WO3 (111), and three-dimensional islands. Their electronic properties have been probed by scanning tunneling spe...
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Veröffentlicht in: | Journal of physical chemistry. C 2021-01, Vol.125 (1), p.660-666 |
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container_title | Journal of physical chemistry. C |
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creator | Harsh, Rishav Ben Youssef, Mariem Chacon, Cyril Repain, Vincent Bellec, Amandine Girard, Yann Rousset, Sylvie Piquemal, Jean-Yves Seydou, Mahamadou Decorse, Philippe Lang, Philippe Lagoute, Jerome |
description | WO3 nanostructures have been synthesized on Au(111) through the solution-processing method. Three types of structures have been obtained: reticulated polymeric structures, two dimensional WO3 (111), and three-dimensional islands. Their electronic properties have been probed by scanning tunneling spectroscopy. The reticulated structure has a featureless spectrum. WO3 (111) shows n-type semiconducting properties with resonances corresponding to surface states arising from W 5d states. These oxide nanostructures efficiently decouple the electronic states of molecular adsorbates from the metal substrate. |
doi_str_mv | 10.1021/acs.jpcc.0c10258 |
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title | Synthesis and Properties of Nanostructured Tungsten Oxide on Au(111) |
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