([n-C4H9)4 N]3PMo2W9(Sn4+.xH2O)O39/TiO2): a new visible photocatalyst for photodegradation of DR16 characterization and optimization process by RSM
Optimization of the photodegradation of direct red 16 (DR16) under visible light irradiation in the presence of new photocatalyst [n-C 4 H 9 ) 4 N] 3 PMo 2 W 9 (Sn 4+ .xH 2 O)O 39 /TiO 2 (PMoWSn/TiO 2 ) was investigated. PMoWSn/TiO 2 with different ratios of PMoWSn to TiO 2 (2, 11, and 20%) were sy...
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creator | Rafiee, Ezzat Noori, Elham Zinatizadeh, Aliakbar Zanganeh, Hadis |
description | Optimization of the photodegradation of direct red 16 (DR16) under visible light irradiation in the presence of new photocatalyst [n-C
4
H
9
)
4
N]
3
PMo
2
W
9
(Sn
4+
.xH
2
O)O
39
/TiO
2
(PMoWSn/TiO
2
) was investigated. PMoWSn/TiO
2
with different ratios of PMoWSn to TiO
2
(2, 11, and 20%) were synthesized by modified sol–gel hydrothermal method. Characterization of the prepared nanocatalysts was carried out by photoluminescence spectroscopy, X-ray diffraction, Fourier transform infrared, field emission scanning electron microscopy, Brunauer Emmett–Teller, and diffuse reflectance spectra. Factorial experimental design was applied to study the interaction effects of five operational variables including DR16 concentration, polyoxometalate content, catalyst loading, reaction time, and pH on the photodegradation process performance. By increasing the amount of PMoWSn, the recombination rate of electrons and holes was decreased and redshift to visible range was observed. Bandgap of the photocatalysts was evaluated from Tauc and Mott–Schottky plots. The efficient and suitable photocatalytic performance of photocatalyst can be attributed to the efficient separation of photo-generated electron–hole pairs and polarization resistance of the catalyst evaluated by Nyquist and Bode plots extracted from electrochemical impedance spectroscopy. The results showed that the photocatalytic activity of 20-PMoWSn/TiO
2
was better than the other nanocatalysts. A central composite design based on response surface methodology was successfully used in optimization of the photodegradation of DR16. The optimum conditions were achieved at acidic pH (3), DR16 concentration of 20 mg/L, and polyoxometalate loading of 20 wt.%. Also this catalyst showed excellent reusability at least after four runs. |
doi_str_mv | 10.1007/s13738-020-02149-w |
format | Article |
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4
H
9
)
4
N]
3
PMo
2
W
9
(Sn
4+
.xH
2
O)O
39
/TiO
2
(PMoWSn/TiO
2
) was investigated. PMoWSn/TiO
2
with different ratios of PMoWSn to TiO
2
(2, 11, and 20%) were synthesized by modified sol–gel hydrothermal method. Characterization of the prepared nanocatalysts was carried out by photoluminescence spectroscopy, X-ray diffraction, Fourier transform infrared, field emission scanning electron microscopy, Brunauer Emmett–Teller, and diffuse reflectance spectra. Factorial experimental design was applied to study the interaction effects of five operational variables including DR16 concentration, polyoxometalate content, catalyst loading, reaction time, and pH on the photodegradation process performance. By increasing the amount of PMoWSn, the recombination rate of electrons and holes was decreased and redshift to visible range was observed. Bandgap of the photocatalysts was evaluated from Tauc and Mott–Schottky plots. The efficient and suitable photocatalytic performance of photocatalyst can be attributed to the efficient separation of photo-generated electron–hole pairs and polarization resistance of the catalyst evaluated by Nyquist and Bode plots extracted from electrochemical impedance spectroscopy. The results showed that the photocatalytic activity of 20-PMoWSn/TiO
2
was better than the other nanocatalysts. A central composite design based on response surface methodology was successfully used in optimization of the photodegradation of DR16. The optimum conditions were achieved at acidic pH (3), DR16 concentration of 20 mg/L, and polyoxometalate loading of 20 wt.%. Also this catalyst showed excellent reusability at least after four runs.</description><identifier>ISSN: 1735-207X</identifier><identifier>EISSN: 1735-2428</identifier><identifier>DOI: 10.1007/s13738-020-02149-w</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Biochemistry ; Catalysts ; Catalytic activity ; Chemistry ; Chemistry and Materials Science ; Chemistry, Multidisciplinary ; Design of experiments ; Electrochemical impedance spectroscopy ; Electron recombination ; Field emission microscopy ; Fourier transforms ; Inorganic Chemistry ; Light irradiation ; Optimization ; Organic Chemistry ; Original Paper ; Photocatalysis ; Photocatalysts ; Photodegradation ; Photoluminescence ; Physical Chemistry ; Physical Sciences ; Polyoxometallates ; Reaction time ; Red shift ; Response surface methodology ; Science & Technology ; Sol-gel processes ; Spectrum analysis ; Titanium dioxide</subject><ispartof>Journal of the Iranian Chemical Society, 2021-07, Vol.18 (7), p.1761-1772</ispartof><rights>Iranian Chemical Society 2021</rights><rights>Iranian Chemical Society 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>3</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000608385800002</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c356t-b0bb0a329bcfcd59eb12537f24e400055ced2de597086f19ee51da541ced66e03</citedby><cites>FETCH-LOGICAL-c356t-b0bb0a329bcfcd59eb12537f24e400055ced2de597086f19ee51da541ced66e03</cites><orcidid>0000-0002-6848-9602</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13738-020-02149-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13738-020-02149-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27931,27932,39265,41495,42564,51326</link.rule.ids></links><search><creatorcontrib>Rafiee, Ezzat</creatorcontrib><creatorcontrib>Noori, Elham</creatorcontrib><creatorcontrib>Zinatizadeh, Aliakbar</creatorcontrib><creatorcontrib>Zanganeh, Hadis</creatorcontrib><title>([n-C4H9)4 N]3PMo2W9(Sn4+.xH2O)O39/TiO2): a new visible photocatalyst for photodegradation of DR16 characterization and optimization process by RSM</title><title>Journal of the Iranian Chemical Society</title><addtitle>J IRAN CHEM SOC</addtitle><description>Optimization of the photodegradation of direct red 16 (DR16) under visible light irradiation in the presence of new photocatalyst [n-C
4
H
9
)
4
N]
3
PMo
2
W
9
(Sn
4+
.xH
2
O)O
39
/TiO
2
(PMoWSn/TiO
2
) was investigated. PMoWSn/TiO
2
with different ratios of PMoWSn to TiO
2
(2, 11, and 20%) were synthesized by modified sol–gel hydrothermal method. Characterization of the prepared nanocatalysts was carried out by photoluminescence spectroscopy, X-ray diffraction, Fourier transform infrared, field emission scanning electron microscopy, Brunauer Emmett–Teller, and diffuse reflectance spectra. Factorial experimental design was applied to study the interaction effects of five operational variables including DR16 concentration, polyoxometalate content, catalyst loading, reaction time, and pH on the photodegradation process performance. By increasing the amount of PMoWSn, the recombination rate of electrons and holes was decreased and redshift to visible range was observed. Bandgap of the photocatalysts was evaluated from Tauc and Mott–Schottky plots. The efficient and suitable photocatalytic performance of photocatalyst can be attributed to the efficient separation of photo-generated electron–hole pairs and polarization resistance of the catalyst evaluated by Nyquist and Bode plots extracted from electrochemical impedance spectroscopy. The results showed that the photocatalytic activity of 20-PMoWSn/TiO
2
was better than the other nanocatalysts. A central composite design based on response surface methodology was successfully used in optimization of the photodegradation of DR16. The optimum conditions were achieved at acidic pH (3), DR16 concentration of 20 mg/L, and polyoxometalate loading of 20 wt.%. Also this catalyst showed excellent reusability at least after four runs.</description><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry, Multidisciplinary</subject><subject>Design of experiments</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electron recombination</subject><subject>Field emission microscopy</subject><subject>Fourier transforms</subject><subject>Inorganic Chemistry</subject><subject>Light irradiation</subject><subject>Optimization</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Photodegradation</subject><subject>Photoluminescence</subject><subject>Physical Chemistry</subject><subject>Physical Sciences</subject><subject>Polyoxometallates</subject><subject>Reaction time</subject><subject>Red shift</subject><subject>Response surface methodology</subject><subject>Science & Technology</subject><subject>Sol-gel processes</subject><subject>Spectrum analysis</subject><subject>Titanium dioxide</subject><issn>1735-207X</issn><issn>1735-2428</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><recordid>eNqNUNtOFEEQnRBNQPQHfOrEFzZkoK8z076Z8bIkwBrAQGJMp6enBpos3Wt3r-v6HXyA3-KX0TCib8aHSlVOnVOXUxQvCd4jGNf7kbCaNSWmOAfhslxtFFukZqKknDZPHmtcX2wWz2K8xljUWPCt4nbnsytbPpUT_uvn8Rf28cjTc7lz6vju3vcpnU1mTO6f2RmdvEYaOVihbzbabg5oceWTNzrp-TomNPgwIj1cBt3rZL1DfkBvT0iFzJUO2iQI9sfY0K5HfpHszSOwCN5AjKhbo5PTo-fF00HPI7z4nbeLT-_fnbXT8nD24aB9c1gaJqpUdrjrsGZUdmYwvZDQESpYPVAOHOcPhYGe9iBkjZtqIBJAkF4LTjJeVYDZdvFqnJvXf11CTOraL4PLK1UeJAXnorpn0ZFlgo8xwKAWwd7osFYEq3v31ei-yu6rB_fVKot2R9EKOj9EY8EZ-CPM11W4YY1ocoVpZjf_z25tejCt9UuXspSN0pjp7hLC3x_-cd4d2Piopg</recordid><startdate>20210701</startdate><enddate>20210701</enddate><creator>Rafiee, Ezzat</creator><creator>Noori, Elham</creator><creator>Zinatizadeh, Aliakbar</creator><creator>Zanganeh, Hadis</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature</general><general>Springer Nature B.V</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-6848-9602</orcidid></search><sort><creationdate>20210701</creationdate><title>([n-C4H9)4 N]3PMo2W9(Sn4+.xH2O)O39/TiO2): a new visible photocatalyst for photodegradation of DR16 characterization and optimization process by RSM</title><author>Rafiee, Ezzat ; Noori, Elham ; Zinatizadeh, Aliakbar ; Zanganeh, Hadis</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-b0bb0a329bcfcd59eb12537f24e400055ced2de597086f19ee51da541ced66e03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry, Multidisciplinary</topic><topic>Design of experiments</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electron recombination</topic><topic>Field emission microscopy</topic><topic>Fourier transforms</topic><topic>Inorganic Chemistry</topic><topic>Light irradiation</topic><topic>Optimization</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><topic>Photodegradation</topic><topic>Photoluminescence</topic><topic>Physical Chemistry</topic><topic>Physical Sciences</topic><topic>Polyoxometallates</topic><topic>Reaction time</topic><topic>Red shift</topic><topic>Response surface methodology</topic><topic>Science & Technology</topic><topic>Sol-gel processes</topic><topic>Spectrum analysis</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rafiee, Ezzat</creatorcontrib><creatorcontrib>Noori, Elham</creatorcontrib><creatorcontrib>Zinatizadeh, Aliakbar</creatorcontrib><creatorcontrib>Zanganeh, Hadis</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 2021</collection><collection>CrossRef</collection><jtitle>Journal of the Iranian Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rafiee, Ezzat</au><au>Noori, Elham</au><au>Zinatizadeh, Aliakbar</au><au>Zanganeh, Hadis</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>([n-C4H9)4 N]3PMo2W9(Sn4+.xH2O)O39/TiO2): a new visible photocatalyst for photodegradation of DR16 characterization and optimization process by RSM</atitle><jtitle>Journal of the Iranian Chemical Society</jtitle><stitle>J IRAN CHEM SOC</stitle><date>2021-07-01</date><risdate>2021</risdate><volume>18</volume><issue>7</issue><spage>1761</spage><epage>1772</epage><pages>1761-1772</pages><issn>1735-207X</issn><eissn>1735-2428</eissn><abstract>Optimization of the photodegradation of direct red 16 (DR16) under visible light irradiation in the presence of new photocatalyst [n-C
4
H
9
)
4
N]
3
PMo
2
W
9
(Sn
4+
.xH
2
O)O
39
/TiO
2
(PMoWSn/TiO
2
) was investigated. PMoWSn/TiO
2
with different ratios of PMoWSn to TiO
2
(2, 11, and 20%) were synthesized by modified sol–gel hydrothermal method. Characterization of the prepared nanocatalysts was carried out by photoluminescence spectroscopy, X-ray diffraction, Fourier transform infrared, field emission scanning electron microscopy, Brunauer Emmett–Teller, and diffuse reflectance spectra. Factorial experimental design was applied to study the interaction effects of five operational variables including DR16 concentration, polyoxometalate content, catalyst loading, reaction time, and pH on the photodegradation process performance. By increasing the amount of PMoWSn, the recombination rate of electrons and holes was decreased and redshift to visible range was observed. Bandgap of the photocatalysts was evaluated from Tauc and Mott–Schottky plots. The efficient and suitable photocatalytic performance of photocatalyst can be attributed to the efficient separation of photo-generated electron–hole pairs and polarization resistance of the catalyst evaluated by Nyquist and Bode plots extracted from electrochemical impedance spectroscopy. The results showed that the photocatalytic activity of 20-PMoWSn/TiO
2
was better than the other nanocatalysts. A central composite design based on response surface methodology was successfully used in optimization of the photodegradation of DR16. The optimum conditions were achieved at acidic pH (3), DR16 concentration of 20 mg/L, and polyoxometalate loading of 20 wt.%. Also this catalyst showed excellent reusability at least after four runs.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13738-020-02149-w</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0002-6848-9602</orcidid></addata></record> |
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source | SpringerNature Journals; Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /> |
subjects | Analytical Chemistry Biochemistry Catalysts Catalytic activity Chemistry Chemistry and Materials Science Chemistry, Multidisciplinary Design of experiments Electrochemical impedance spectroscopy Electron recombination Field emission microscopy Fourier transforms Inorganic Chemistry Light irradiation Optimization Organic Chemistry Original Paper Photocatalysis Photocatalysts Photodegradation Photoluminescence Physical Chemistry Physical Sciences Polyoxometallates Reaction time Red shift Response surface methodology Science & Technology Sol-gel processes Spectrum analysis Titanium dioxide |
title | ([n-C4H9)4 N]3PMo2W9(Sn4+.xH2O)O39/TiO2): a new visible photocatalyst for photodegradation of DR16 characterization and optimization process by RSM |
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