Eco-friendly ionic liquid imprinted polymer based on a green synthesis strategy for highly selective adsorption tylosin in animal muscle samples

A novel eco-friendly molecularly imprinted polymer (MIP) was proposed as solid-phase extraction (SPE) adsorbent to selective adsorption tylosin (TYL) in animal muscle samples. The MIP was synthesized in aqueous by using 1,4-butanediyl-3,3-bis-1-vinyl imidazolium chloride and 2-acrylamide-2-methylpro...

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Veröffentlicht in:Environmental science and pollution research international 2021-04, Vol.28 (13), p.16470-16479
Hauptverfasser: Wang, Lifang, Chen, Jingfan, Li, Xian, Chen, Letian, Zhang, Kaige, Wang, Xuefeng, Zhu, Guifen
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container_issue 13
container_start_page 16470
container_title Environmental science and pollution research international
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creator Wang, Lifang
Chen, Jingfan
Li, Xian
Chen, Letian
Zhang, Kaige
Wang, Xuefeng
Zhu, Guifen
description A novel eco-friendly molecularly imprinted polymer (MIP) was proposed as solid-phase extraction (SPE) adsorbent to selective adsorption tylosin (TYL) in animal muscle samples. The MIP was synthesized in aqueous by using 1,4-butanediyl-3,3-bis-1-vinyl imidazolium chloride and 2-acrylamide-2-methylpropanesulfonic acid as bifunctional monomer. The obtained MIP had excellent selectivity towards TYL in water, and the maximum binding capacity can reach 123.45 mg g −1 . Combined with high-performance liquid chromatography, the presented MIP can be used as SPE sorbent to recognize and detect TYL in the range of 0.008 to 0.6 mg L −1 ( R 2  = 0.9995). The limit of detection and limit of quantification were 0.003 mg L −1 and 0.008 mg L −1 , and the intraday and interday precision were 1.05% and 3.36%, respectively. Under the optimal condition, the established MIP-SPE-HPLC method was successfully applied to separate and determine trace TYL in chicken, pork, and beef samples with satisfactory recoveries ranged from 94.0 to 106.3%, and the MIP-SPE cartridge can be cycled at least 20 times. This study implies a promising green MIP-SPE-HPLC method for highly selective adsorption and analysis trace TYL in complex matrices.
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This study implies a promising green MIP-SPE-HPLC method for highly selective adsorption and analysis trace TYL in complex matrices.</description><subject>Acrylamide</subject><subject>Adsorption</subject><subject>Animals</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Cartridges</subject><subject>Chemical synthesis</subject><subject>Chromatography, High Pressure Liquid</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental science</subject><subject>Environmental Sciences</subject><subject>Environmental Sciences &amp; Ecology</subject><subject>High performance liquid chromatography</subject><subject>Imprinted polymers</subject><subject>Ionic Liquids</subject><subject>Ions</subject><subject>Life Sciences &amp; Biomedicine</subject><subject>Liquid chromatography</subject><subject>Molecular Imprinting</subject><subject>Muscles</subject><subject>Polymers</subject><subject>Pork</subject><subject>Research Article</subject><subject>Science &amp; Technology</subject><subject>Selective adsorption</subject><subject>Selectivity</subject><subject>Solid Phase Extraction</subject><subject>Solid phases</subject><subject>Sorbents</subject><subject>Tylosin</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNqNkc1u1DAUhS0EokPhBVggSyxRwH_5W6JRgUqV2MA6cpybGVeJPfV1QHkLHpk7pJRdRWQptvydY_scxl5L8V4KUX9AKXVZFUKJQsrGqKJ8wnaykqaoTds-ZTvRGlNIbcwFe4F4K4hsVf2cXWitm1pLsWO_rlwsxuQhDNPKfQze8cnfLX7gfj4lHzIM_BSndYbEe4u0ioFbfkgAgeMa8hHQI8ecbIbDyseY-NEfjuSGMIHL_gdwO2BMp0z2PK9TRB84DRv8bCc-L-gm4Gjn0wT4kj0b7YTw6v5_yb5_uvq2_1LcfP18vf94UzgjVS7A1YMdRA9Vo_q6MrKv9CiUanoojVJSq74VqtKtbJSjbdMMaux1qRXNWyv1JXu7-Z5SvFsAc3cblxToyE6VFJTRTVkTpTbKpYiYYOwok9mmtZOiO5fQbSV0pOj-lNCVJHpzb730MwwPkr-pE9BswE_o44iO0nfwgAkhKmEUudOn6r3P9pzcPi4hk_Td_0uJ1huN5yoPkP498pH7_wYfCrSb</recordid><startdate>20210401</startdate><enddate>20210401</enddate><creator>Wang, Lifang</creator><creator>Chen, Jingfan</creator><creator>Li, Xian</creator><creator>Chen, Letian</creator><creator>Zhang, Kaige</creator><creator>Wang, Xuefeng</creator><creator>Zhu, Guifen</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature</general><general>Springer Nature B.V</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>7WY</scope><scope>7WZ</scope><scope>7X7</scope><scope>7XB</scope><scope>87Z</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8FL</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FRNLG</scope><scope>FYUFA</scope><scope>F~G</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K60</scope><scope>K6~</scope><scope>K9.</scope><scope>L.-</scope><scope>M0C</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7N</scope><scope>P64</scope><scope>PATMY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope></search><sort><creationdate>20210401</creationdate><title>Eco-friendly ionic liquid imprinted polymer based on a green synthesis strategy for highly selective adsorption tylosin in animal muscle samples</title><author>Wang, Lifang ; 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The MIP was synthesized in aqueous by using 1,4-butanediyl-3,3-bis-1-vinyl imidazolium chloride and 2-acrylamide-2-methylpropanesulfonic acid as bifunctional monomer. The obtained MIP had excellent selectivity towards TYL in water, and the maximum binding capacity can reach 123.45 mg g −1 . Combined with high-performance liquid chromatography, the presented MIP can be used as SPE sorbent to recognize and detect TYL in the range of 0.008 to 0.6 mg L −1 ( R 2  = 0.9995). The limit of detection and limit of quantification were 0.003 mg L −1 and 0.008 mg L −1 , and the intraday and interday precision were 1.05% and 3.36%, respectively. Under the optimal condition, the established MIP-SPE-HPLC method was successfully applied to separate and determine trace TYL in chicken, pork, and beef samples with satisfactory recoveries ranged from 94.0 to 106.3%, and the MIP-SPE cartridge can be cycled at least 20 times. This study implies a promising green MIP-SPE-HPLC method for highly selective adsorption and analysis trace TYL in complex matrices.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>33387310</pmid><doi>10.1007/s11356-020-11842-5</doi><tpages>10</tpages></addata></record>
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subjects Acrylamide
Adsorption
Animals
Aquatic Pollution
Atmospheric Protection/Air Quality Control/Air Pollution
Cartridges
Chemical synthesis
Chromatography, High Pressure Liquid
Earth and Environmental Science
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Environmental science
Environmental Sciences
Environmental Sciences & Ecology
High performance liquid chromatography
Imprinted polymers
Ionic Liquids
Ions
Life Sciences & Biomedicine
Liquid chromatography
Molecular Imprinting
Muscles
Polymers
Pork
Research Article
Science & Technology
Selective adsorption
Selectivity
Solid Phase Extraction
Solid phases
Sorbents
Tylosin
Waste Water Technology
Water Management
Water Pollution Control
title Eco-friendly ionic liquid imprinted polymer based on a green synthesis strategy for highly selective adsorption tylosin in animal muscle samples
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