First radical cation salts based on dibenzotetrathiafulvalene (DBTTF) with metallacarborane an ions: Synt hesis, structure, properties
The new radical cation salts based on transition metal bis(dicarbollides) with dibenzotetrathiafulvalene (DBTTF) donors (DBTTF)[3,3'-Fe(1,2-C2B9H11)(2)] ( 1 ) and (DBTTF)(2)[3,3'-Cr(1,2-C2B9H11)(2)] ( 2 ) were synthe-sized and their crystal structures were determined by single crystal X-ra...
Gespeichert in:
| Veröffentlicht in: | Journal of organometallic chemistry 2020-12, Vol.930, Article 121592 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | |
| container_start_page | |
| container_title | Journal of organometallic chemistry |
| container_volume | 930 |
| creator | Kazheva, Olga N. Chudak, Denis M. Shilov, Gennady V. Kravchenko, Andrey V. Kosenko, Irina D. Sivaev, Igor B. Abashev, Georgy G. Shklyaeva, Elena V. Starodub, Vladimir A. Buravov, Lev I. Bregadze, Vladimir I. Dyachenko, Oleg A. |
| description | The new radical cation salts based on transition metal bis(dicarbollides) with dibenzotetrathiafulvalene (DBTTF) donors (DBTTF)[3,3'-Fe(1,2-C2B9H11)(2)] ( 1 ) and (DBTTF)(2)[3,3'-Cr(1,2-C2B9H11)(2)] ( 2 ) were synthe-sized and their crystal structures were determined by single crystal X-ray diffractions. The electric conductivity measurements revealed that these compounds are semiconductors at room temperature and the conductivity of (DBTTF)(2)[3,3'-Cr(1,2-C2B9H11)(2)] is similar to 500 times higher than that of its BEDT-TTF analogue. (c) 2020 Elsevier B.V. All rights reserved. |
| doi_str_mv | 10.1016/j.jorganchem.2020.121592 |
| format | Article |
| fullrecord | <record><control><sourceid>webofscience</sourceid><recordid>TN_cdi_webofscience_primary_000592625700005CitationCount</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>000592625700005</sourcerecordid><originalsourceid>FETCH-webofscience_primary_0005926257000053</originalsourceid><addsrcrecordid>eNqVT0FOAzEMjBBIlMIffATRliSrtgtHllbc6YFb5c26bKo0qWIvVXkA72ZBPABO4xmPPB6lwOiJ0WZ2t51sU37D6FraTay2vWzN9N6eqIEp53ZcTmfmVA20tnZc2PL1XF0wb7XWptDlQH0ufWaBjI13GMCh-BSBMQhDjUwN9LTxNcWPJCQZpfW46cI7BooE10-Pq9XyBg5eWtiRYAjoMNcpY7_FCP01foCXYxRoiT2PgCV3TrpMI9jntKcsnvhSnW0wMF394lDdLher6nl8oDpt2HmKjtb77HeYj-v--77hzE7n-nsshqr8u7vy8lOySl2U4n9BXxZcdC0</addsrcrecordid><sourcetype>Index Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>First radical cation salts based on dibenzotetrathiafulvalene (DBTTF) with metallacarborane an ions: Synt hesis, structure, properties</title><source>Elsevier ScienceDirect Journals Complete</source><source>Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /></source><creator>Kazheva, Olga N. ; Chudak, Denis M. ; Shilov, Gennady V. ; Kravchenko, Andrey V. ; Kosenko, Irina D. ; Sivaev, Igor B. ; Abashev, Georgy G. ; Shklyaeva, Elena V. ; Starodub, Vladimir A. ; Buravov, Lev I. ; Bregadze, Vladimir I. ; Dyachenko, Oleg A.</creator><creatorcontrib>Kazheva, Olga N. ; Chudak, Denis M. ; Shilov, Gennady V. ; Kravchenko, Andrey V. ; Kosenko, Irina D. ; Sivaev, Igor B. ; Abashev, Georgy G. ; Shklyaeva, Elena V. ; Starodub, Vladimir A. ; Buravov, Lev I. ; Bregadze, Vladimir I. ; Dyachenko, Oleg A.</creatorcontrib><description>The new radical cation salts based on transition metal bis(dicarbollides) with dibenzotetrathiafulvalene (DBTTF) donors (DBTTF)[3,3'-Fe(1,2-C2B9H11)(2)] ( 1 ) and (DBTTF)(2)[3,3'-Cr(1,2-C2B9H11)(2)] ( 2 ) were synthe-sized and their crystal structures were determined by single crystal X-ray diffractions. The electric conductivity measurements revealed that these compounds are semiconductors at room temperature and the conductivity of (DBTTF)(2)[3,3'-Cr(1,2-C2B9H11)(2)] is similar to 500 times higher than that of its BEDT-TTF analogue. (c) 2020 Elsevier B.V. All rights reserved.</description><identifier>ISSN: 0022-328X</identifier><identifier>EISSN: 1872-8561</identifier><identifier>DOI: 10.1016/j.jorganchem.2020.121592</identifier><language>eng</language><publisher>LAUSANNE: Elsevier</publisher><subject>Chemistry ; Chemistry, Inorganic & Nuclear ; Chemistry, Organic ; Physical Sciences ; Science & Technology</subject><ispartof>Journal of organometallic chemistry, 2020-12, Vol.930, Article 121592</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>4</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000592625700005</woscitedreferencesoriginalsourcerecordid><cites>FETCH-webofscience_primary_0005926257000053</cites><orcidid>0000-0002-5442-367X ; 0000-0001-5279-7283 ; 0000-0003-0829-363X ; 0000-0002-2910-8547</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930,28253</link.rule.ids></links><search><creatorcontrib>Kazheva, Olga N.</creatorcontrib><creatorcontrib>Chudak, Denis M.</creatorcontrib><creatorcontrib>Shilov, Gennady V.</creatorcontrib><creatorcontrib>Kravchenko, Andrey V.</creatorcontrib><creatorcontrib>Kosenko, Irina D.</creatorcontrib><creatorcontrib>Sivaev, Igor B.</creatorcontrib><creatorcontrib>Abashev, Georgy G.</creatorcontrib><creatorcontrib>Shklyaeva, Elena V.</creatorcontrib><creatorcontrib>Starodub, Vladimir A.</creatorcontrib><creatorcontrib>Buravov, Lev I.</creatorcontrib><creatorcontrib>Bregadze, Vladimir I.</creatorcontrib><creatorcontrib>Dyachenko, Oleg A.</creatorcontrib><title>First radical cation salts based on dibenzotetrathiafulvalene (DBTTF) with metallacarborane an ions: Synt hesis, structure, properties</title><title>Journal of organometallic chemistry</title><addtitle>J ORGANOMET CHEM</addtitle><description>The new radical cation salts based on transition metal bis(dicarbollides) with dibenzotetrathiafulvalene (DBTTF) donors (DBTTF)[3,3'-Fe(1,2-C2B9H11)(2)] ( 1 ) and (DBTTF)(2)[3,3'-Cr(1,2-C2B9H11)(2)] ( 2 ) were synthe-sized and their crystal structures were determined by single crystal X-ray diffractions. The electric conductivity measurements revealed that these compounds are semiconductors at room temperature and the conductivity of (DBTTF)(2)[3,3'-Cr(1,2-C2B9H11)(2)] is similar to 500 times higher than that of its BEDT-TTF analogue. (c) 2020 Elsevier B.V. All rights reserved.</description><subject>Chemistry</subject><subject>Chemistry, Inorganic & Nuclear</subject><subject>Chemistry, Organic</subject><subject>Physical Sciences</subject><subject>Science & Technology</subject><issn>0022-328X</issn><issn>1872-8561</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqVT0FOAzEMjBBIlMIffATRliSrtgtHllbc6YFb5c26bKo0qWIvVXkA72ZBPABO4xmPPB6lwOiJ0WZ2t51sU37D6FraTay2vWzN9N6eqIEp53ZcTmfmVA20tnZc2PL1XF0wb7XWptDlQH0ufWaBjI13GMCh-BSBMQhDjUwN9LTxNcWPJCQZpfW46cI7BooE10-Pq9XyBg5eWtiRYAjoMNcpY7_FCP01foCXYxRoiT2PgCV3TrpMI9jntKcsnvhSnW0wMF394lDdLher6nl8oDpt2HmKjtb77HeYj-v--77hzE7n-nsshqr8u7vy8lOySl2U4n9BXxZcdC0</recordid><startdate>20201221</startdate><enddate>20201221</enddate><creator>Kazheva, Olga N.</creator><creator>Chudak, Denis M.</creator><creator>Shilov, Gennady V.</creator><creator>Kravchenko, Andrey V.</creator><creator>Kosenko, Irina D.</creator><creator>Sivaev, Igor B.</creator><creator>Abashev, Georgy G.</creator><creator>Shklyaeva, Elena V.</creator><creator>Starodub, Vladimir A.</creator><creator>Buravov, Lev I.</creator><creator>Bregadze, Vladimir I.</creator><creator>Dyachenko, Oleg A.</creator><general>Elsevier</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><orcidid>https://orcid.org/0000-0002-5442-367X</orcidid><orcidid>https://orcid.org/0000-0001-5279-7283</orcidid><orcidid>https://orcid.org/0000-0003-0829-363X</orcidid><orcidid>https://orcid.org/0000-0002-2910-8547</orcidid></search><sort><creationdate>20201221</creationdate><title>First radical cation salts based on dibenzotetrathiafulvalene (DBTTF) with metallacarborane an ions: Synt hesis, structure, properties</title><author>Kazheva, Olga N. ; Chudak, Denis M. ; Shilov, Gennady V. ; Kravchenko, Andrey V. ; Kosenko, Irina D. ; Sivaev, Igor B. ; Abashev, Georgy G. ; Shklyaeva, Elena V. ; Starodub, Vladimir A. ; Buravov, Lev I. ; Bregadze, Vladimir I. ; Dyachenko, Oleg A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-webofscience_primary_0005926257000053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Chemistry</topic><topic>Chemistry, Inorganic & Nuclear</topic><topic>Chemistry, Organic</topic><topic>Physical Sciences</topic><topic>Science & Technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kazheva, Olga N.</creatorcontrib><creatorcontrib>Chudak, Denis M.</creatorcontrib><creatorcontrib>Shilov, Gennady V.</creatorcontrib><creatorcontrib>Kravchenko, Andrey V.</creatorcontrib><creatorcontrib>Kosenko, Irina D.</creatorcontrib><creatorcontrib>Sivaev, Igor B.</creatorcontrib><creatorcontrib>Abashev, Georgy G.</creatorcontrib><creatorcontrib>Shklyaeva, Elena V.</creatorcontrib><creatorcontrib>Starodub, Vladimir A.</creatorcontrib><creatorcontrib>Buravov, Lev I.</creatorcontrib><creatorcontrib>Bregadze, Vladimir I.</creatorcontrib><creatorcontrib>Dyachenko, Oleg A.</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><jtitle>Journal of organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kazheva, Olga N.</au><au>Chudak, Denis M.</au><au>Shilov, Gennady V.</au><au>Kravchenko, Andrey V.</au><au>Kosenko, Irina D.</au><au>Sivaev, Igor B.</au><au>Abashev, Georgy G.</au><au>Shklyaeva, Elena V.</au><au>Starodub, Vladimir A.</au><au>Buravov, Lev I.</au><au>Bregadze, Vladimir I.</au><au>Dyachenko, Oleg A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>First radical cation salts based on dibenzotetrathiafulvalene (DBTTF) with metallacarborane an ions: Synt hesis, structure, properties</atitle><jtitle>Journal of organometallic chemistry</jtitle><stitle>J ORGANOMET CHEM</stitle><date>2020-12-21</date><risdate>2020</risdate><volume>930</volume><artnum>121592</artnum><issn>0022-328X</issn><eissn>1872-8561</eissn><abstract>The new radical cation salts based on transition metal bis(dicarbollides) with dibenzotetrathiafulvalene (DBTTF) donors (DBTTF)[3,3'-Fe(1,2-C2B9H11)(2)] ( 1 ) and (DBTTF)(2)[3,3'-Cr(1,2-C2B9H11)(2)] ( 2 ) were synthe-sized and their crystal structures were determined by single crystal X-ray diffractions. The electric conductivity measurements revealed that these compounds are semiconductors at room temperature and the conductivity of (DBTTF)(2)[3,3'-Cr(1,2-C2B9H11)(2)] is similar to 500 times higher than that of its BEDT-TTF analogue. (c) 2020 Elsevier B.V. All rights reserved.</abstract><cop>LAUSANNE</cop><pub>Elsevier</pub><doi>10.1016/j.jorganchem.2020.121592</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-5442-367X</orcidid><orcidid>https://orcid.org/0000-0001-5279-7283</orcidid><orcidid>https://orcid.org/0000-0003-0829-363X</orcidid><orcidid>https://orcid.org/0000-0002-2910-8547</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-328X |
| ispartof | Journal of organometallic chemistry, 2020-12, Vol.930, Article 121592 |
| issn | 0022-328X 1872-8561 |
| language | eng |
| recordid | cdi_webofscience_primary_000592625700005CitationCount |
| source | Elsevier ScienceDirect Journals Complete; Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /> |
| subjects | Chemistry Chemistry, Inorganic & Nuclear Chemistry, Organic Physical Sciences Science & Technology |
| title | First radical cation salts based on dibenzotetrathiafulvalene (DBTTF) with metallacarborane an ions: Synt hesis, structure, properties |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-13T05%3A38%3A34IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-webofscience&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=First%20radical%20cation%20salts%20based%20on%20dibenzotetrathiafulvalene%20(DBTTF)%20with%20metallacarborane%20an%20ions:%20Synt%20hesis,%20structure,%20properties&rft.jtitle=Journal%20of%20organometallic%20chemistry&rft.au=Kazheva,%20Olga%20N.&rft.date=2020-12-21&rft.volume=930&rft.artnum=121592&rft.issn=0022-328X&rft.eissn=1872-8561&rft_id=info:doi/10.1016/j.jorganchem.2020.121592&rft_dat=%3Cwebofscience%3E000592625700005%3C/webofscience%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |