Direct synthesis of the organic and Ge free Al containing BOG zeolite (ITQ-47) and its application for transformation of biomass derived molecules
Aluminosilicate boggsite (Si/Al-BOG) has been hydrothermally synthesized without adding organic structure-directing agents (OSDAs) in the synthesis gel using the borosilicogermanium ITQ-47 (Si/B-ITQ-47) zeolite as seeds. The introduction of the costly and environmentally less benign phosphazene orga...
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| Veröffentlicht in: | Chemical science (Cambridge) 2020-11, Vol.11 (44), p.1213-1218 |
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| creator | Huang, Qintong Chen, Ningyue Liu, Lichen Arias, Karen S Iborra, Sara Yi, Xianfeng Ma, Chao Liang, Weichi Zheng, Anmin Zhang, Chuanqi Hu, Jibo Cai, Zilin Liu, Yi Jiang, Jiuxing Corma, Avelino |
| description | Aluminosilicate boggsite (Si/Al-BOG) has been hydrothermally synthesized without adding organic structure-directing agents (OSDAs) in the synthesis gel using the borosilicogermanium ITQ-47 (Si/B-ITQ-47) zeolite as seeds. The introduction of the costly and environmentally less benign phosphazene organic structure-directing agent is not required to grow the zeolite. Physicochemical characterization experiments show that Si/Al-BOG has good crystallinity, high surface area, tetrahedral Al
3+
species, and acid sites. In order to test the catalytic performance of the zeolite, the synthesis of
l
,
l
-lactide from
l
-lactic acid was performed. Si/Al-BOG exhibits 88.2% conversion of
l
-lactic acid and 83.8%
l
,
l
-lactide selectivity, which are better than those of other zeolites studied up to now.
Aluminosilicate boggsite (Si/Al-BOG) has been hydrothermally synthesized without adding organic structure-directing agents (OSDAs) in the synthesis gel using the borosilicogermanium ITQ-47 (Si/B-ITQ-47) zeolite as seeds. |
| doi_str_mv | 10.1039/d0sc04044d |
| format | Article |
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3+
species, and acid sites. In order to test the catalytic performance of the zeolite, the synthesis of
l
,
l
-lactide from
l
-lactic acid was performed. Si/Al-BOG exhibits 88.2% conversion of
l
-lactic acid and 83.8%
l
,
l
-lactide selectivity, which are better than those of other zeolites studied up to now.
Aluminosilicate boggsite (Si/Al-BOG) has been hydrothermally synthesized without adding organic structure-directing agents (OSDAs) in the synthesis gel using the borosilicogermanium ITQ-47 (Si/B-ITQ-47) zeolite as seeds.</description><identifier>ISSN: 2041-6520</identifier><identifier>EISSN: 2041-6539</identifier><identifier>DOI: 10.1039/d0sc04044d</identifier><identifier>PMID: 34123221</identifier><language>eng</language><publisher>CAMBRIDGE: Royal Soc Chemistry</publisher><subject>Aluminosilicates ; Aluminum ; Aluminum silicates ; Chemistry ; Chemistry, Multidisciplinary ; Lactic acid ; Phosphazene ; Physical Sciences ; Science & Technology ; Selectivity ; Silicon ; Zeolites</subject><ispartof>Chemical science (Cambridge), 2020-11, Vol.11 (44), p.1213-1218</ispartof><rights>Copyright Royal Society of Chemistry 2020</rights><rights>This journal is © The Royal Society of Chemistry 2020 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>16</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000590392400010</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c335t-e75e753f2e7f49ea934e247324386249f66cdddbb72b892eefebd29611dca7743</citedby><cites>FETCH-LOGICAL-c335t-e75e753f2e7f49ea934e247324386249f66cdddbb72b892eefebd29611dca7743</cites><orcidid>0000-0002-2232-3527 ; 0000-0001-7115-6510 ; 0000-0003-1758-5095 ; 0000-0001-9664-3235 ; 0000-0001-5067-0481</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162478/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC8162478/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,315,729,782,786,866,887,2118,27933,27934,28257,53800,53802</link.rule.ids></links><search><creatorcontrib>Huang, Qintong</creatorcontrib><creatorcontrib>Chen, Ningyue</creatorcontrib><creatorcontrib>Liu, Lichen</creatorcontrib><creatorcontrib>Arias, Karen S</creatorcontrib><creatorcontrib>Iborra, Sara</creatorcontrib><creatorcontrib>Yi, Xianfeng</creatorcontrib><creatorcontrib>Ma, Chao</creatorcontrib><creatorcontrib>Liang, Weichi</creatorcontrib><creatorcontrib>Zheng, Anmin</creatorcontrib><creatorcontrib>Zhang, Chuanqi</creatorcontrib><creatorcontrib>Hu, Jibo</creatorcontrib><creatorcontrib>Cai, Zilin</creatorcontrib><creatorcontrib>Liu, Yi</creatorcontrib><creatorcontrib>Jiang, Jiuxing</creatorcontrib><creatorcontrib>Corma, Avelino</creatorcontrib><title>Direct synthesis of the organic and Ge free Al containing BOG zeolite (ITQ-47) and its application for transformation of biomass derived molecules</title><title>Chemical science (Cambridge)</title><addtitle>CHEM SCI</addtitle><description>Aluminosilicate boggsite (Si/Al-BOG) has been hydrothermally synthesized without adding organic structure-directing agents (OSDAs) in the synthesis gel using the borosilicogermanium ITQ-47 (Si/B-ITQ-47) zeolite as seeds. The introduction of the costly and environmentally less benign phosphazene organic structure-directing agent is not required to grow the zeolite. Physicochemical characterization experiments show that Si/Al-BOG has good crystallinity, high surface area, tetrahedral Al
3+
species, and acid sites. In order to test the catalytic performance of the zeolite, the synthesis of
l
,
l
-lactide from
l
-lactic acid was performed. Si/Al-BOG exhibits 88.2% conversion of
l
-lactic acid and 83.8%
l
,
l
-lactide selectivity, which are better than those of other zeolites studied up to now.
Aluminosilicate boggsite (Si/Al-BOG) has been hydrothermally synthesized without adding organic structure-directing agents (OSDAs) in the synthesis gel using the borosilicogermanium ITQ-47 (Si/B-ITQ-47) zeolite as seeds.</description><subject>Aluminosilicates</subject><subject>Aluminum</subject><subject>Aluminum silicates</subject><subject>Chemistry</subject><subject>Chemistry, Multidisciplinary</subject><subject>Lactic acid</subject><subject>Phosphazene</subject><subject>Physical Sciences</subject><subject>Science & Technology</subject><subject>Selectivity</subject><subject>Silicon</subject><subject>Zeolites</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNUl9rFDEcXESxpfbFdyHgS1VW8283uy9C3dOzUChifQ7Z5LfXlN3kTLKV-jH8xOZuy4k-GQIZkpnJhElRPCf4LcGsfWdw1Jhjzs2j4phiTsq6Yu3jA6b4qDiN8RbnwRipqHhaHDFOKKOUHBe_VjaATijeu3QD0UbkB5QR8mGjnNVIOYPWgIYAgM5HpL1LyjrrNujD1Rr9BD_aBOjs4vpLycWrPd2miNR2O1qtkvUODT6gFJSLGUzLVr6kt35SMSIDwd6BQZMfQc8jxGfFk0GNEU4f1pPi26eP193n8vJqfdGdX5aasSqVIKo82UBBDLwF1TIOlAtGOWtqytuhrrUxpu8F7ZuWAgzQG9rWhBithODspHi_-G7nfgKjweWQo9wGO6lwL72y8u8TZ2_kxt_JhmR_0WSDsweD4L_PEJOcbNQwjsqBn6OkFceCYlHjTH35D_XWz8Hl50nKa1I1Fal3iV4vLB18jAGGQxiC5a5tucJfu33bq0x-s5B_QO-HqC04DQdBbrtqs4LyjMguQPP_7M6mfU2dn13K0heLNER9UPz5duw31enGtw</recordid><startdate>20201118</startdate><enddate>20201118</enddate><creator>Huang, Qintong</creator><creator>Chen, Ningyue</creator><creator>Liu, Lichen</creator><creator>Arias, Karen S</creator><creator>Iborra, Sara</creator><creator>Yi, Xianfeng</creator><creator>Ma, Chao</creator><creator>Liang, Weichi</creator><creator>Zheng, Anmin</creator><creator>Zhang, Chuanqi</creator><creator>Hu, Jibo</creator><creator>Cai, Zilin</creator><creator>Liu, Yi</creator><creator>Jiang, Jiuxing</creator><creator>Corma, Avelino</creator><general>Royal Soc Chemistry</general><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-2232-3527</orcidid><orcidid>https://orcid.org/0000-0001-7115-6510</orcidid><orcidid>https://orcid.org/0000-0003-1758-5095</orcidid><orcidid>https://orcid.org/0000-0001-9664-3235</orcidid><orcidid>https://orcid.org/0000-0001-5067-0481</orcidid></search><sort><creationdate>20201118</creationdate><title>Direct synthesis of the organic and Ge free Al containing BOG zeolite (ITQ-47) and its application for transformation of biomass derived molecules</title><author>Huang, Qintong ; Chen, Ningyue ; Liu, Lichen ; Arias, Karen S ; Iborra, Sara ; Yi, Xianfeng ; Ma, Chao ; Liang, Weichi ; Zheng, Anmin ; Zhang, Chuanqi ; Hu, Jibo ; Cai, Zilin ; Liu, Yi ; Jiang, Jiuxing ; Corma, Avelino</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c335t-e75e753f2e7f49ea934e247324386249f66cdddbb72b892eefebd29611dca7743</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aluminosilicates</topic><topic>Aluminum</topic><topic>Aluminum silicates</topic><topic>Chemistry</topic><topic>Chemistry, Multidisciplinary</topic><topic>Lactic acid</topic><topic>Phosphazene</topic><topic>Physical Sciences</topic><topic>Science & Technology</topic><topic>Selectivity</topic><topic>Silicon</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Huang, Qintong</creatorcontrib><creatorcontrib>Chen, Ningyue</creatorcontrib><creatorcontrib>Liu, Lichen</creatorcontrib><creatorcontrib>Arias, Karen S</creatorcontrib><creatorcontrib>Iborra, Sara</creatorcontrib><creatorcontrib>Yi, Xianfeng</creatorcontrib><creatorcontrib>Ma, Chao</creatorcontrib><creatorcontrib>Liang, Weichi</creatorcontrib><creatorcontrib>Zheng, Anmin</creatorcontrib><creatorcontrib>Zhang, Chuanqi</creatorcontrib><creatorcontrib>Hu, Jibo</creatorcontrib><creatorcontrib>Cai, Zilin</creatorcontrib><creatorcontrib>Liu, Yi</creatorcontrib><creatorcontrib>Jiang, Jiuxing</creatorcontrib><creatorcontrib>Corma, Avelino</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Huang, Qintong</au><au>Chen, Ningyue</au><au>Liu, Lichen</au><au>Arias, Karen S</au><au>Iborra, Sara</au><au>Yi, Xianfeng</au><au>Ma, Chao</au><au>Liang, Weichi</au><au>Zheng, Anmin</au><au>Zhang, Chuanqi</au><au>Hu, Jibo</au><au>Cai, Zilin</au><au>Liu, Yi</au><au>Jiang, Jiuxing</au><au>Corma, Avelino</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Direct synthesis of the organic and Ge free Al containing BOG zeolite (ITQ-47) and its application for transformation of biomass derived molecules</atitle><jtitle>Chemical science (Cambridge)</jtitle><stitle>CHEM SCI</stitle><date>2020-11-18</date><risdate>2020</risdate><volume>11</volume><issue>44</issue><spage>1213</spage><epage>1218</epage><pages>1213-1218</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Aluminosilicate boggsite (Si/Al-BOG) has been hydrothermally synthesized without adding organic structure-directing agents (OSDAs) in the synthesis gel using the borosilicogermanium ITQ-47 (Si/B-ITQ-47) zeolite as seeds. The introduction of the costly and environmentally less benign phosphazene organic structure-directing agent is not required to grow the zeolite. Physicochemical characterization experiments show that Si/Al-BOG has good crystallinity, high surface area, tetrahedral Al
3+
species, and acid sites. In order to test the catalytic performance of the zeolite, the synthesis of
l
,
l
-lactide from
l
-lactic acid was performed. Si/Al-BOG exhibits 88.2% conversion of
l
-lactic acid and 83.8%
l
,
l
-lactide selectivity, which are better than those of other zeolites studied up to now.
Aluminosilicate boggsite (Si/Al-BOG) has been hydrothermally synthesized without adding organic structure-directing agents (OSDAs) in the synthesis gel using the borosilicogermanium ITQ-47 (Si/B-ITQ-47) zeolite as seeds.</abstract><cop>CAMBRIDGE</cop><pub>Royal Soc Chemistry</pub><pmid>34123221</pmid><doi>10.1039/d0sc04044d</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-2232-3527</orcidid><orcidid>https://orcid.org/0000-0001-7115-6510</orcidid><orcidid>https://orcid.org/0000-0003-1758-5095</orcidid><orcidid>https://orcid.org/0000-0001-9664-3235</orcidid><orcidid>https://orcid.org/0000-0001-5067-0481</orcidid><oa>free_for_read</oa></addata></record> |
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| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" />; PubMed Central |
| subjects | Aluminosilicates Aluminum Aluminum silicates Chemistry Chemistry, Multidisciplinary Lactic acid Phosphazene Physical Sciences Science & Technology Selectivity Silicon Zeolites |
| title | Direct synthesis of the organic and Ge free Al containing BOG zeolite (ITQ-47) and its application for transformation of biomass derived molecules |
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