Optimizing supramolecular interactions in metal-organic frameworks for C-2 separation
C-2 separation is of great importance in the petrochemical industry. Traditionally, it is performed by distillation at cryogenic temperatures, which necessitates the consumption of a huge amount of energy to operate the refrigeration system in the production process. In this regard, it is imperative...
Gespeichert in:
Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2020-11, Vol.49 (44), p.15548-15559 |
---|---|
Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 15559 |
---|---|
container_issue | 44 |
container_start_page | 15548 |
container_title | Dalton transactions : an international journal of inorganic chemistry |
container_volume | 49 |
creator | Hua, Gui-Fang Xie, Xiao-Jing Lu, Weigang Li, Dan |
description | C-2 separation is of great importance in the petrochemical industry. Traditionally, it is performed by distillation at cryogenic temperatures, which necessitates the consumption of a huge amount of energy to operate the refrigeration system in the production process. In this regard, it is imperative to seek alternative separation methods with high efficiency and low energy cost. Although of recent origin, metal-organic frameworks (MOFs) have already been extensively studied as advanced adsorbents in many applications, and significant progress has been made particularly in gas separation owing to their unprecedented porosity and tunable structures. In this review, we extrapolated three most frequently invoked design strategies for efficient C-2 separation hinged upon supramolecular interactions, including molecular sieving, gate opening, and surface engineering. Recent progress of MOF materials in C-2 separation was highlighted within each of these strategies, and their advantages and limitations are compared and discussed. Accordingly, we provide perspectives on current challenges and future emphases in designing MOF materials for hydrocarbon separation. With our continued efforts in this area, we expect that integrating supramolecular interactions in a single MOF system is a viable approach to achieve a balance between adsorption capacity and selectivity for different hydrocarbon separation scenarios. |
doi_str_mv | 10.1039/d0dt03013a |
format | Article |
fullrecord | <record><control><sourceid>webofscience_cross</sourceid><recordid>TN_cdi_webofscience_primary_000590136500002CitationCount</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>000590136500002</sourcerecordid><originalsourceid>FETCH-LOGICAL-c161t-74db8372b726d1e0682f3b9d74b5c5bd3c0a9bd62aa5a484e060588f9f2b239a3</originalsourceid><addsrcrecordid>eNqN0E1PwzAMBuAIgdgYXPgFPYMKTtLP49TxJU3aZTtXTppMgbapkkwT_Hq6De3Mybb02JJfQu4pPFHg5XMDTQAOlOMFmdIkz-OS8eTy3LNsQm68_wRgDFJ2TSacU8o4zaZksxqC6cyP6beR3w0OO9squWvRRaYPyqEMxvZ-HKJOBWxj67bYGxnpkaq9dV8-0tZFVcwirwZ0ePC35Epj69XdX52RzevLunqPl6u3j2q-jCXNaIjzpBEFz5nIWdZQBVnBNBdlkycilalouAQsRZMxxBSTIhkFpEWhS80E4yXyGXk43ZXOeu-UrgdnOnTfNYX6kE29gMX6mM18xI8nvFfCai-N6qU6LwBAWo4uS8cO2KiL_-vKhOPfld31gf8C3fB29Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Optimizing supramolecular interactions in metal-organic frameworks for C-2 separation</title><source>Royal Society Of Chemistry Journals</source><source>Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /></source><source>Alma/SFX Local Collection</source><creator>Hua, Gui-Fang ; Xie, Xiao-Jing ; Lu, Weigang ; Li, Dan</creator><creatorcontrib>Hua, Gui-Fang ; Xie, Xiao-Jing ; Lu, Weigang ; Li, Dan</creatorcontrib><description>C-2 separation is of great importance in the petrochemical industry. Traditionally, it is performed by distillation at cryogenic temperatures, which necessitates the consumption of a huge amount of energy to operate the refrigeration system in the production process. In this regard, it is imperative to seek alternative separation methods with high efficiency and low energy cost. Although of recent origin, metal-organic frameworks (MOFs) have already been extensively studied as advanced adsorbents in many applications, and significant progress has been made particularly in gas separation owing to their unprecedented porosity and tunable structures. In this review, we extrapolated three most frequently invoked design strategies for efficient C-2 separation hinged upon supramolecular interactions, including molecular sieving, gate opening, and surface engineering. Recent progress of MOF materials in C-2 separation was highlighted within each of these strategies, and their advantages and limitations are compared and discussed. Accordingly, we provide perspectives on current challenges and future emphases in designing MOF materials for hydrocarbon separation. With our continued efforts in this area, we expect that integrating supramolecular interactions in a single MOF system is a viable approach to achieve a balance between adsorption capacity and selectivity for different hydrocarbon separation scenarios.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/d0dt03013a</identifier><identifier>PMID: 33112316</identifier><language>eng</language><publisher>CAMBRIDGE: Royal Soc Chemistry</publisher><subject>Chemistry ; Chemistry, Inorganic & Nuclear ; Physical Sciences ; Science & Technology</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2020-11, Vol.49 (44), p.15548-15559</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>17</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000590136500002</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c161t-74db8372b726d1e0682f3b9d74b5c5bd3c0a9bd62aa5a484e060588f9f2b239a3</citedby><cites>FETCH-LOGICAL-c161t-74db8372b726d1e0682f3b9d74b5c5bd3c0a9bd62aa5a484e060588f9f2b239a3</cites><orcidid>0000-0001-9751-8241 ; 0000-0002-4936-4599</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,782,786,27931,27932,28255</link.rule.ids></links><search><creatorcontrib>Hua, Gui-Fang</creatorcontrib><creatorcontrib>Xie, Xiao-Jing</creatorcontrib><creatorcontrib>Lu, Weigang</creatorcontrib><creatorcontrib>Li, Dan</creatorcontrib><title>Optimizing supramolecular interactions in metal-organic frameworks for C-2 separation</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>DALTON T</addtitle><description>C-2 separation is of great importance in the petrochemical industry. Traditionally, it is performed by distillation at cryogenic temperatures, which necessitates the consumption of a huge amount of energy to operate the refrigeration system in the production process. In this regard, it is imperative to seek alternative separation methods with high efficiency and low energy cost. Although of recent origin, metal-organic frameworks (MOFs) have already been extensively studied as advanced adsorbents in many applications, and significant progress has been made particularly in gas separation owing to their unprecedented porosity and tunable structures. In this review, we extrapolated three most frequently invoked design strategies for efficient C-2 separation hinged upon supramolecular interactions, including molecular sieving, gate opening, and surface engineering. Recent progress of MOF materials in C-2 separation was highlighted within each of these strategies, and their advantages and limitations are compared and discussed. Accordingly, we provide perspectives on current challenges and future emphases in designing MOF materials for hydrocarbon separation. With our continued efforts in this area, we expect that integrating supramolecular interactions in a single MOF system is a viable approach to achieve a balance between adsorption capacity and selectivity for different hydrocarbon separation scenarios.</description><subject>Chemistry</subject><subject>Chemistry, Inorganic & Nuclear</subject><subject>Physical Sciences</subject><subject>Science & Technology</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqN0E1PwzAMBuAIgdgYXPgFPYMKTtLP49TxJU3aZTtXTppMgbapkkwT_Hq6De3Mybb02JJfQu4pPFHg5XMDTQAOlOMFmdIkz-OS8eTy3LNsQm68_wRgDFJ2TSacU8o4zaZksxqC6cyP6beR3w0OO9squWvRRaYPyqEMxvZ-HKJOBWxj67bYGxnpkaq9dV8-0tZFVcwirwZ0ePC35Epj69XdX52RzevLunqPl6u3j2q-jCXNaIjzpBEFz5nIWdZQBVnBNBdlkycilalouAQsRZMxxBSTIhkFpEWhS80E4yXyGXk43ZXOeu-UrgdnOnTfNYX6kE29gMX6mM18xI8nvFfCai-N6qU6LwBAWo4uS8cO2KiL_-vKhOPfld31gf8C3fB29Q</recordid><startdate>20201128</startdate><enddate>20201128</enddate><creator>Hua, Gui-Fang</creator><creator>Xie, Xiao-Jing</creator><creator>Lu, Weigang</creator><creator>Li, Dan</creator><general>Royal Soc Chemistry</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-9751-8241</orcidid><orcidid>https://orcid.org/0000-0002-4936-4599</orcidid></search><sort><creationdate>20201128</creationdate><title>Optimizing supramolecular interactions in metal-organic frameworks for C-2 separation</title><author>Hua, Gui-Fang ; Xie, Xiao-Jing ; Lu, Weigang ; Li, Dan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c161t-74db8372b726d1e0682f3b9d74b5c5bd3c0a9bd62aa5a484e060588f9f2b239a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Chemistry</topic><topic>Chemistry, Inorganic & Nuclear</topic><topic>Physical Sciences</topic><topic>Science & Technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hua, Gui-Fang</creatorcontrib><creatorcontrib>Xie, Xiao-Jing</creatorcontrib><creatorcontrib>Lu, Weigang</creatorcontrib><creatorcontrib>Li, Dan</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>CrossRef</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hua, Gui-Fang</au><au>Xie, Xiao-Jing</au><au>Lu, Weigang</au><au>Li, Dan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Optimizing supramolecular interactions in metal-organic frameworks for C-2 separation</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><stitle>DALTON T</stitle><date>2020-11-28</date><risdate>2020</risdate><volume>49</volume><issue>44</issue><spage>15548</spage><epage>15559</epage><pages>15548-15559</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>C-2 separation is of great importance in the petrochemical industry. Traditionally, it is performed by distillation at cryogenic temperatures, which necessitates the consumption of a huge amount of energy to operate the refrigeration system in the production process. In this regard, it is imperative to seek alternative separation methods with high efficiency and low energy cost. Although of recent origin, metal-organic frameworks (MOFs) have already been extensively studied as advanced adsorbents in many applications, and significant progress has been made particularly in gas separation owing to their unprecedented porosity and tunable structures. In this review, we extrapolated three most frequently invoked design strategies for efficient C-2 separation hinged upon supramolecular interactions, including molecular sieving, gate opening, and surface engineering. Recent progress of MOF materials in C-2 separation was highlighted within each of these strategies, and their advantages and limitations are compared and discussed. Accordingly, we provide perspectives on current challenges and future emphases in designing MOF materials for hydrocarbon separation. With our continued efforts in this area, we expect that integrating supramolecular interactions in a single MOF system is a viable approach to achieve a balance between adsorption capacity and selectivity for different hydrocarbon separation scenarios.</abstract><cop>CAMBRIDGE</cop><pub>Royal Soc Chemistry</pub><pmid>33112316</pmid><doi>10.1039/d0dt03013a</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-9751-8241</orcidid><orcidid>https://orcid.org/0000-0002-4936-4599</orcidid></addata></record> |
fulltext | fulltext |
identifier | ISSN: 1477-9226 |
ispartof | Dalton transactions : an international journal of inorganic chemistry, 2020-11, Vol.49 (44), p.15548-15559 |
issn | 1477-9226 1477-9234 |
language | eng |
recordid | cdi_webofscience_primary_000590136500002CitationCount |
source | Royal Society Of Chemistry Journals; Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" />; Alma/SFX Local Collection |
subjects | Chemistry Chemistry, Inorganic & Nuclear Physical Sciences Science & Technology |
title | Optimizing supramolecular interactions in metal-organic frameworks for C-2 separation |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-06T00%3A17%3A39IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-webofscience_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Optimizing%20supramolecular%20interactions%20in%20metal-organic%20frameworks%20for%20C-2%20separation&rft.jtitle=Dalton%20transactions%20:%20an%20international%20journal%20of%20inorganic%20chemistry&rft.au=Hua,%20Gui-Fang&rft.date=2020-11-28&rft.volume=49&rft.issue=44&rft.spage=15548&rft.epage=15559&rft.pages=15548-15559&rft.issn=1477-9226&rft.eissn=1477-9234&rft_id=info:doi/10.1039/d0dt03013a&rft_dat=%3Cwebofscience_cross%3E000590136500002%3C/webofscience_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/33112316&rfr_iscdi=true |