Pulsed electrodeposition of compact, corrosion resistant, and bioactive HAp coatings by application of optimized magnetic field

NiTi shape memory alloy possess spectacular properties, so it has a great potential to use as bio-implants. However, releasing toxic Ni ions from its surface have restricted its successful use in human's body. The present research attempts to modify the surface conditions of NiTi through deposi...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Materials chemistry and physics 2020-11, Vol.254, p.123511, Article 123511
Hauptverfasser: Mohammad Salahi Tohidi, Parinaz, Safavi, Mir Saman, Etminanfar, Mohamadreza, Khalil-Allafi, Jafar
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page
container_issue
container_start_page 123511
container_title Materials chemistry and physics
container_volume 254
creator Mohammad Salahi Tohidi, Parinaz
Safavi, Mir Saman
Etminanfar, Mohamadreza
Khalil-Allafi, Jafar
description NiTi shape memory alloy possess spectacular properties, so it has a great potential to use as bio-implants. However, releasing toxic Ni ions from its surface have restricted its successful use in human's body. The present research attempts to modify the surface conditions of NiTi through deposition of calcium phosphate (CaP) coatings to overcome the abovementioned challenge, besides improving the other critical characteristics required for successful use of NiTi in bio-related applications. CaP deposits were deposited on NiTi by means of pulsed electrodeposition under magnetic field. Since the hydroxyapatite (HAp) has the closest Ca/P ratio to that of human's bone among the other CaP types, and considering its superior bioactivity, the processing variables including pulse current density, deposition time, as well as magnetic field direction and magnitude were adjusted in such a way that the Ca/P ratio of HAp obtains. The aim behind application of magnetic field was to attain favorable morphological and structural properties. Then, the characteristics of coatings electrodeposited under optimized conditions were investigated via Fourier transform Infrared (FTIR) and X-ray diffraction (XRD). Electrochemical potentiodynamic polarization studies test in Ringer's solution was performed to assess the corrosion behavior of the coatings. A noticeable increment in polarization resistance of NiTi, about 10 times, is obtained with deposition of the optimized coatings. Ni ion release was found to decrease by 89% after deposition of HAp coatings on NiTi. In vitro bioactivity of the coatings were studied through immersion of HAp coatings in simulated body fluid (SBF). Nucleation of apatite particles all over the coating microstructure demonstrate the desirable bioactivity of the deposits. In general, compact, corrosion resistive, and bioactive HAp coating with minimal Ni ion release were deposited on NiTi by controlling the operating conditions. [Display omitted] •HAp coatings were electrodeposited under optimized magnetic field on NiTi.•Morphological and structural properties of the coatings are addressed.•Ni ion release, corrosion behavior, and bioactivity of HAp coating are stressed.
doi_str_mv 10.1016/j.matchemphys.2020.123511
format Article
fullrecord <record><control><sourceid>proquest_webof</sourceid><recordid>TN_cdi_webofscience_primary_000570089000005CitationCount</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0254058420308762</els_id><sourcerecordid>2462188176</sourcerecordid><originalsourceid>FETCH-LOGICAL-c349t-8f0d32fc4d5e0e20ba5067a70cf8c3e38c1c9e1e828b1584de2f880a33d1dfde3</originalsourceid><addsrcrecordid>eNqNkc1u1DAUhSMEEkPhHYJYQoZrO5k4yyqiFKkSLGBtOfZ169EkNranaNjw6twhBbGsN7aOznd_jqvqNYMtA7Z7v9_Oupg7nOPdKW85cNK56Bh7Um2Y7IdGCMafVhvgXdtAJ9vn1Yuc9wCsZ0xsql9fjoeMtsYDmpKCxRiyLz4sdXC1CXPUpryjR0qkk5ow-1z0QqJebD35QAZ_j_X1ZSSbLn65zfV0qnWMB2_031IhFj_7n9Rp1rcLFm9q5_FgX1bPnKYJXj3cF9W3qw9fx-vm5vPHT-PlTWNEO5RGOrCCO9PaDgE5TLqDXa97ME4agUIaZgZkKLmcGG1pkTspQQthmXUWxUX1Zq0bU_h-xFzUPhzTQi0Vb3ecScn6HbmG1WVo3ZzQqZj8rNNJMVDnvNVe_Ze3Ouet1ryJlSv7A6fgsvG4GPzHA0DXA8gBzqcbffkTzRiOSyH07eNRco-rGymve49JPRDWJ_pEZYN_xLi_ASXTsyI</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2462188176</pqid></control><display><type>article</type><title>Pulsed electrodeposition of compact, corrosion resistant, and bioactive HAp coatings by application of optimized magnetic field</title><source>Web of Science - Science Citation Index Expanded - 2020&lt;img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /&gt;</source><source>Access via ScienceDirect (Elsevier)</source><creator>Mohammad Salahi Tohidi, Parinaz ; Safavi, Mir Saman ; Etminanfar, Mohamadreza ; Khalil-Allafi, Jafar</creator><creatorcontrib>Mohammad Salahi Tohidi, Parinaz ; Safavi, Mir Saman ; Etminanfar, Mohamadreza ; Khalil-Allafi, Jafar</creatorcontrib><description>NiTi shape memory alloy possess spectacular properties, so it has a great potential to use as bio-implants. However, releasing toxic Ni ions from its surface have restricted its successful use in human's body. The present research attempts to modify the surface conditions of NiTi through deposition of calcium phosphate (CaP) coatings to overcome the abovementioned challenge, besides improving the other critical characteristics required for successful use of NiTi in bio-related applications. CaP deposits were deposited on NiTi by means of pulsed electrodeposition under magnetic field. Since the hydroxyapatite (HAp) has the closest Ca/P ratio to that of human's bone among the other CaP types, and considering its superior bioactivity, the processing variables including pulse current density, deposition time, as well as magnetic field direction and magnitude were adjusted in such a way that the Ca/P ratio of HAp obtains. The aim behind application of magnetic field was to attain favorable morphological and structural properties. Then, the characteristics of coatings electrodeposited under optimized conditions were investigated via Fourier transform Infrared (FTIR) and X-ray diffraction (XRD). Electrochemical potentiodynamic polarization studies test in Ringer's solution was performed to assess the corrosion behavior of the coatings. A noticeable increment in polarization resistance of NiTi, about 10 times, is obtained with deposition of the optimized coatings. Ni ion release was found to decrease by 89% after deposition of HAp coatings on NiTi. In vitro bioactivity of the coatings were studied through immersion of HAp coatings in simulated body fluid (SBF). Nucleation of apatite particles all over the coating microstructure demonstrate the desirable bioactivity of the deposits. In general, compact, corrosion resistive, and bioactive HAp coating with minimal Ni ion release were deposited on NiTi by controlling the operating conditions. [Display omitted] •HAp coatings were electrodeposited under optimized magnetic field on NiTi.•Morphological and structural properties of the coatings are addressed.•Ni ion release, corrosion behavior, and bioactivity of HAp coating are stressed.</description><identifier>ISSN: 0254-0584</identifier><identifier>EISSN: 1879-3312</identifier><identifier>DOI: 10.1016/j.matchemphys.2020.123511</identifier><language>eng</language><publisher>LAUSANNE: Elsevier B.V</publisher><subject>Apatite ; Bioactivity ; Biocompatibility ; Biological activity ; Biomedical materials ; Body fluids ; Calcium phosphates ; Coated electrodes ; Coating ; Coatings ; Corrosion ; Corrosion resistance ; Electrodeposition ; Fourier transforms ; Hydroxyapatite ; In vitro methods and tests ; Intermetallic compounds ; Magnetic field ; Magnetic fields ; Magnetic properties ; Materials Science ; Materials Science, Multidisciplinary ; Nickel base alloys ; Nickel compounds ; Nickel titanides ; Nucleation ; Polarization ; Science &amp; Technology ; Shape memory alloys ; Submerging ; Surgical implants ; Technology</subject><ispartof>Materials chemistry and physics, 2020-11, Vol.254, p.123511, Article 123511</ispartof><rights>2020 Elsevier B.V.</rights><rights>Copyright Elsevier BV Nov 1, 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>40</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000570089000005</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c349t-8f0d32fc4d5e0e20ba5067a70cf8c3e38c1c9e1e828b1584de2f880a33d1dfde3</citedby><cites>FETCH-LOGICAL-c349t-8f0d32fc4d5e0e20ba5067a70cf8c3e38c1c9e1e828b1584de2f880a33d1dfde3</cites><orcidid>0000-0002-3291-753X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.matchemphys.2020.123511$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,782,786,3552,27931,27932,28255,46002</link.rule.ids></links><search><creatorcontrib>Mohammad Salahi Tohidi, Parinaz</creatorcontrib><creatorcontrib>Safavi, Mir Saman</creatorcontrib><creatorcontrib>Etminanfar, Mohamadreza</creatorcontrib><creatorcontrib>Khalil-Allafi, Jafar</creatorcontrib><title>Pulsed electrodeposition of compact, corrosion resistant, and bioactive HAp coatings by application of optimized magnetic field</title><title>Materials chemistry and physics</title><addtitle>MATER CHEM PHYS</addtitle><description>NiTi shape memory alloy possess spectacular properties, so it has a great potential to use as bio-implants. However, releasing toxic Ni ions from its surface have restricted its successful use in human's body. The present research attempts to modify the surface conditions of NiTi through deposition of calcium phosphate (CaP) coatings to overcome the abovementioned challenge, besides improving the other critical characteristics required for successful use of NiTi in bio-related applications. CaP deposits were deposited on NiTi by means of pulsed electrodeposition under magnetic field. Since the hydroxyapatite (HAp) has the closest Ca/P ratio to that of human's bone among the other CaP types, and considering its superior bioactivity, the processing variables including pulse current density, deposition time, as well as magnetic field direction and magnitude were adjusted in such a way that the Ca/P ratio of HAp obtains. The aim behind application of magnetic field was to attain favorable morphological and structural properties. Then, the characteristics of coatings electrodeposited under optimized conditions were investigated via Fourier transform Infrared (FTIR) and X-ray diffraction (XRD). Electrochemical potentiodynamic polarization studies test in Ringer's solution was performed to assess the corrosion behavior of the coatings. A noticeable increment in polarization resistance of NiTi, about 10 times, is obtained with deposition of the optimized coatings. Ni ion release was found to decrease by 89% after deposition of HAp coatings on NiTi. In vitro bioactivity of the coatings were studied through immersion of HAp coatings in simulated body fluid (SBF). Nucleation of apatite particles all over the coating microstructure demonstrate the desirable bioactivity of the deposits. In general, compact, corrosion resistive, and bioactive HAp coating with minimal Ni ion release were deposited on NiTi by controlling the operating conditions. [Display omitted] •HAp coatings were electrodeposited under optimized magnetic field on NiTi.•Morphological and structural properties of the coatings are addressed.•Ni ion release, corrosion behavior, and bioactivity of HAp coating are stressed.</description><subject>Apatite</subject><subject>Bioactivity</subject><subject>Biocompatibility</subject><subject>Biological activity</subject><subject>Biomedical materials</subject><subject>Body fluids</subject><subject>Calcium phosphates</subject><subject>Coated electrodes</subject><subject>Coating</subject><subject>Coatings</subject><subject>Corrosion</subject><subject>Corrosion resistance</subject><subject>Electrodeposition</subject><subject>Fourier transforms</subject><subject>Hydroxyapatite</subject><subject>In vitro methods and tests</subject><subject>Intermetallic compounds</subject><subject>Magnetic field</subject><subject>Magnetic fields</subject><subject>Magnetic properties</subject><subject>Materials Science</subject><subject>Materials Science, Multidisciplinary</subject><subject>Nickel base alloys</subject><subject>Nickel compounds</subject><subject>Nickel titanides</subject><subject>Nucleation</subject><subject>Polarization</subject><subject>Science &amp; Technology</subject><subject>Shape memory alloys</subject><subject>Submerging</subject><subject>Surgical implants</subject><subject>Technology</subject><issn>0254-0584</issn><issn>1879-3312</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNkc1u1DAUhSMEEkPhHYJYQoZrO5k4yyqiFKkSLGBtOfZ169EkNranaNjw6twhBbGsN7aOznd_jqvqNYMtA7Z7v9_Oupg7nOPdKW85cNK56Bh7Um2Y7IdGCMafVhvgXdtAJ9vn1Yuc9wCsZ0xsql9fjoeMtsYDmpKCxRiyLz4sdXC1CXPUpryjR0qkk5ow-1z0QqJebD35QAZ_j_X1ZSSbLn65zfV0qnWMB2_031IhFj_7n9Rp1rcLFm9q5_FgX1bPnKYJXj3cF9W3qw9fx-vm5vPHT-PlTWNEO5RGOrCCO9PaDgE5TLqDXa97ME4agUIaZgZkKLmcGG1pkTspQQthmXUWxUX1Zq0bU_h-xFzUPhzTQi0Vb3ecScn6HbmG1WVo3ZzQqZj8rNNJMVDnvNVe_Ze3Ouet1ryJlSv7A6fgsvG4GPzHA0DXA8gBzqcbffkTzRiOSyH07eNRco-rGymve49JPRDWJ_pEZYN_xLi_ASXTsyI</recordid><startdate>20201101</startdate><enddate>20201101</enddate><creator>Mohammad Salahi Tohidi, Parinaz</creator><creator>Safavi, Mir Saman</creator><creator>Etminanfar, Mohamadreza</creator><creator>Khalil-Allafi, Jafar</creator><general>Elsevier B.V</general><general>Elsevier</general><general>Elsevier BV</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-3291-753X</orcidid></search><sort><creationdate>20201101</creationdate><title>Pulsed electrodeposition of compact, corrosion resistant, and bioactive HAp coatings by application of optimized magnetic field</title><author>Mohammad Salahi Tohidi, Parinaz ; Safavi, Mir Saman ; Etminanfar, Mohamadreza ; Khalil-Allafi, Jafar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c349t-8f0d32fc4d5e0e20ba5067a70cf8c3e38c1c9e1e828b1584de2f880a33d1dfde3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Apatite</topic><topic>Bioactivity</topic><topic>Biocompatibility</topic><topic>Biological activity</topic><topic>Biomedical materials</topic><topic>Body fluids</topic><topic>Calcium phosphates</topic><topic>Coated electrodes</topic><topic>Coating</topic><topic>Coatings</topic><topic>Corrosion</topic><topic>Corrosion resistance</topic><topic>Electrodeposition</topic><topic>Fourier transforms</topic><topic>Hydroxyapatite</topic><topic>In vitro methods and tests</topic><topic>Intermetallic compounds</topic><topic>Magnetic field</topic><topic>Magnetic fields</topic><topic>Magnetic properties</topic><topic>Materials Science</topic><topic>Materials Science, Multidisciplinary</topic><topic>Nickel base alloys</topic><topic>Nickel compounds</topic><topic>Nickel titanides</topic><topic>Nucleation</topic><topic>Polarization</topic><topic>Science &amp; Technology</topic><topic>Shape memory alloys</topic><topic>Submerging</topic><topic>Surgical implants</topic><topic>Technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mohammad Salahi Tohidi, Parinaz</creatorcontrib><creatorcontrib>Safavi, Mir Saman</creatorcontrib><creatorcontrib>Etminanfar, Mohamadreza</creatorcontrib><creatorcontrib>Khalil-Allafi, Jafar</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Materials chemistry and physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mohammad Salahi Tohidi, Parinaz</au><au>Safavi, Mir Saman</au><au>Etminanfar, Mohamadreza</au><au>Khalil-Allafi, Jafar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pulsed electrodeposition of compact, corrosion resistant, and bioactive HAp coatings by application of optimized magnetic field</atitle><jtitle>Materials chemistry and physics</jtitle><stitle>MATER CHEM PHYS</stitle><date>2020-11-01</date><risdate>2020</risdate><volume>254</volume><spage>123511</spage><pages>123511-</pages><artnum>123511</artnum><issn>0254-0584</issn><eissn>1879-3312</eissn><abstract>NiTi shape memory alloy possess spectacular properties, so it has a great potential to use as bio-implants. However, releasing toxic Ni ions from its surface have restricted its successful use in human's body. The present research attempts to modify the surface conditions of NiTi through deposition of calcium phosphate (CaP) coatings to overcome the abovementioned challenge, besides improving the other critical characteristics required for successful use of NiTi in bio-related applications. CaP deposits were deposited on NiTi by means of pulsed electrodeposition under magnetic field. Since the hydroxyapatite (HAp) has the closest Ca/P ratio to that of human's bone among the other CaP types, and considering its superior bioactivity, the processing variables including pulse current density, deposition time, as well as magnetic field direction and magnitude were adjusted in such a way that the Ca/P ratio of HAp obtains. The aim behind application of magnetic field was to attain favorable morphological and structural properties. Then, the characteristics of coatings electrodeposited under optimized conditions were investigated via Fourier transform Infrared (FTIR) and X-ray diffraction (XRD). Electrochemical potentiodynamic polarization studies test in Ringer's solution was performed to assess the corrosion behavior of the coatings. A noticeable increment in polarization resistance of NiTi, about 10 times, is obtained with deposition of the optimized coatings. Ni ion release was found to decrease by 89% after deposition of HAp coatings on NiTi. In vitro bioactivity of the coatings were studied through immersion of HAp coatings in simulated body fluid (SBF). Nucleation of apatite particles all over the coating microstructure demonstrate the desirable bioactivity of the deposits. In general, compact, corrosion resistive, and bioactive HAp coating with minimal Ni ion release were deposited on NiTi by controlling the operating conditions. [Display omitted] •HAp coatings were electrodeposited under optimized magnetic field on NiTi.•Morphological and structural properties of the coatings are addressed.•Ni ion release, corrosion behavior, and bioactivity of HAp coating are stressed.</abstract><cop>LAUSANNE</cop><pub>Elsevier B.V</pub><doi>10.1016/j.matchemphys.2020.123511</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-3291-753X</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 0254-0584
ispartof Materials chemistry and physics, 2020-11, Vol.254, p.123511, Article 123511
issn 0254-0584
1879-3312
language eng
recordid cdi_webofscience_primary_000570089000005CitationCount
source Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" />; Access via ScienceDirect (Elsevier)
subjects Apatite
Bioactivity
Biocompatibility
Biological activity
Biomedical materials
Body fluids
Calcium phosphates
Coated electrodes
Coating
Coatings
Corrosion
Corrosion resistance
Electrodeposition
Fourier transforms
Hydroxyapatite
In vitro methods and tests
Intermetallic compounds
Magnetic field
Magnetic fields
Magnetic properties
Materials Science
Materials Science, Multidisciplinary
Nickel base alloys
Nickel compounds
Nickel titanides
Nucleation
Polarization
Science & Technology
Shape memory alloys
Submerging
Surgical implants
Technology
title Pulsed electrodeposition of compact, corrosion resistant, and bioactive HAp coatings by application of optimized magnetic field
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-04T05%3A15%3A11IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_webof&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Pulsed%20electrodeposition%20of%20compact,%20corrosion%20resistant,%20and%20bioactive%20HAp%20coatings%20by%20application%20of%20optimized%20magnetic%20field&rft.jtitle=Materials%20chemistry%20and%20physics&rft.au=Mohammad%20Salahi%20Tohidi,%20Parinaz&rft.date=2020-11-01&rft.volume=254&rft.spage=123511&rft.pages=123511-&rft.artnum=123511&rft.issn=0254-0584&rft.eissn=1879-3312&rft_id=info:doi/10.1016/j.matchemphys.2020.123511&rft_dat=%3Cproquest_webof%3E2462188176%3C/proquest_webof%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2462188176&rft_id=info:pmid/&rft_els_id=S0254058420308762&rfr_iscdi=true