Autarkic desorption electrospray ionization source for on-site analysis of consumer goods
A general-purpose desorption electrospray ionization (DESI) source is presented which is not bound to the laboratory site. It allows autarkic operation for a few hours and can be connected to different types of (autarkic or non-autarkic) mass spectrometers via an atmospheric-pressure interface. Tech...
Gespeichert in:
| Veröffentlicht in: | Analyst (London) 2020-08, Vol.145 (16), p.5584-5593 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5593 |
|---|---|
| container_issue | 16 |
| container_start_page | 5584 |
| container_title | Analyst (London) |
| container_volume | 145 |
| creator | Lotz, Florian Gerbig, Stefanie Lotze, Christian Spengler, Bernhard Schulz, Sabine |
| description | A general-purpose desorption electrospray ionization (DESI) source is presented which is not bound to the laboratory site. It allows autarkic operation for a few hours and can be connected to different types of (autarkic or non-autarkic) mass spectrometers
via
an atmospheric-pressure interface. Technical characteristics are described as well as results from direct surface analysis of consumer goods such as plastics, fruit peels or pills, or from living objects such as human skin, demonstrating the detection of various target compounds such as plasticizers, pesticides, drugs or sun blockers. Quantitative analysis is demonstrated for phthalates in plastics. The geometry of the sample, the sample table and the sprayer were modified and characterized for optimization of the method. The autarkic ion source has a total size of 48.4 × 27.0 × 18.0 cm (
l
×
w
×
h
) and a total mass of 7 kg. The source delivers 5.5 bar pressurized air and an adjustable solvent flow rate down to 1.5 μl min
−1
for the DESI sprayer. A rechargeable 25.6 V battery allows autarkic runtimes of more than 3.5 hours. Source optimization and characterization was done on an orbital trapping mass spectrometer. Connected to a portable mass spectrometer, the developed device makes DESI suitable for on-site analyses in
e.g.
consumer protection, border control or homeland security.
A battery-powered DESI source with integrated solvent/gas supply and novel sampling geometry is presented for daily-goods analysis. |
| doi_str_mv | 10.1039/d0an00713g |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_webof</sourceid><recordid>TN_cdi_webofscience_primary_000558067300023CitationCount</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2431811563</sourcerecordid><originalsourceid>FETCH-LOGICAL-c340t-c629bdc44e209d20fbf9eb9e85f6f33f213a2ead7fe4c8099e2d18463d2b88893</originalsourceid><addsrcrecordid>eNqNkcGL1DAUh4Mo7jh68S5EvIhSfclrM-lxGHUVFr3owVNJk5cla6epSYuMf72ZGVnBg3hK8vh-gd_3GHss4JUAbF87MCPARuD1HbYSqOqqaaS-y1YAgJVUTX3BHuR8U54CGrjPLlAqqSXiin3dLrNJ34LljnJM0xziyGkgO6eYp2QOvAzCT3Oa57gkS9zHxONY5TATN6MZDjlkHj23cczLnhK_jtHlh-yeN0OmR7_PNfvy7u3n3fvq6tPlh932qrJYw1xZJdve2bomCa2T4HvfUt-SbrzyiF4KNJKM23iqrYa2JemErhU62WutW1yz5-d_pxS_L5Tnbh-ypWEwI8Uld7KWoFDIUnfNnv2F3pRGpcGRQqGFaNSRenGmbFGQE_luSmFv0qET0B2Fd29g-_Ek_LLA-gz_oD76bAONlm4DxXjTaFAbLDeJuzCfRO7iMs4l-vL_o4V-eqZTtrfQn813k_OFefIvBn8Butqn1g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2431811563</pqid></control><display><type>article</type><title>Autarkic desorption electrospray ionization source for on-site analysis of consumer goods</title><source>Royal Society of Chemistry Journals Archive (1841-2007)</source><source>Royal Society Of Chemistry Journals 2008-</source><source>Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /></source><source>Alma/SFX Local Collection</source><creator>Lotz, Florian ; Gerbig, Stefanie ; Lotze, Christian ; Spengler, Bernhard ; Schulz, Sabine</creator><creatorcontrib>Lotz, Florian ; Gerbig, Stefanie ; Lotze, Christian ; Spengler, Bernhard ; Schulz, Sabine</creatorcontrib><description>A general-purpose desorption electrospray ionization (DESI) source is presented which is not bound to the laboratory site. It allows autarkic operation for a few hours and can be connected to different types of (autarkic or non-autarkic) mass spectrometers
via
an atmospheric-pressure interface. Technical characteristics are described as well as results from direct surface analysis of consumer goods such as plastics, fruit peels or pills, or from living objects such as human skin, demonstrating the detection of various target compounds such as plasticizers, pesticides, drugs or sun blockers. Quantitative analysis is demonstrated for phthalates in plastics. The geometry of the sample, the sample table and the sprayer were modified and characterized for optimization of the method. The autarkic ion source has a total size of 48.4 × 27.0 × 18.0 cm (
l
×
w
×
h
) and a total mass of 7 kg. The source delivers 5.5 bar pressurized air and an adjustable solvent flow rate down to 1.5 μl min
−1
for the DESI sprayer. A rechargeable 25.6 V battery allows autarkic runtimes of more than 3.5 hours. Source optimization and characterization was done on an orbital trapping mass spectrometer. Connected to a portable mass spectrometer, the developed device makes DESI suitable for on-site analyses in
e.g.
consumer protection, border control or homeland security.
A battery-powered DESI source with integrated solvent/gas supply and novel sampling geometry is presented for daily-goods analysis.</description><identifier>ISSN: 0003-2654</identifier><identifier>EISSN: 1364-5528</identifier><identifier>DOI: 10.1039/d0an00713g</identifier><identifier>PMID: 32628233</identifier><language>eng</language><publisher>CAMBRIDGE: Royal Soc Chemistry</publisher><subject>Chemistry ; Chemistry, Analytical ; Consumer goods ; Consumer protection ; Desorption ; Electrospraying ; Flow velocity ; Geometry ; Ion sources ; Ionization ; Ions ; Mass spectrometers ; National security ; Object recognition ; Optimization ; Pesticides ; Phthalates ; Physical Sciences ; Polymers ; Portable equipment ; Quantitative analysis ; Rechargeable batteries ; Sampling ; Science & Technology ; Spectrometers ; Surface analysis (chemical) ; Target detection</subject><ispartof>Analyst (London), 2020-08, Vol.145 (16), p.5584-5593</ispartof><rights>Copyright Royal Society of Chemistry 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>2</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000558067300023</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c340t-c629bdc44e209d20fbf9eb9e85f6f33f213a2ead7fe4c8099e2d18463d2b88893</citedby><cites>FETCH-LOGICAL-c340t-c629bdc44e209d20fbf9eb9e85f6f33f213a2ead7fe4c8099e2d18463d2b88893</cites><orcidid>0000-0003-1355-4048 ; 0000-0002-6561-5562 ; 0000-0003-0179-5653</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,2832,2833,27929,27930,28253</link.rule.ids></links><search><creatorcontrib>Lotz, Florian</creatorcontrib><creatorcontrib>Gerbig, Stefanie</creatorcontrib><creatorcontrib>Lotze, Christian</creatorcontrib><creatorcontrib>Spengler, Bernhard</creatorcontrib><creatorcontrib>Schulz, Sabine</creatorcontrib><title>Autarkic desorption electrospray ionization source for on-site analysis of consumer goods</title><title>Analyst (London)</title><addtitle>ANALYST</addtitle><description>A general-purpose desorption electrospray ionization (DESI) source is presented which is not bound to the laboratory site. It allows autarkic operation for a few hours and can be connected to different types of (autarkic or non-autarkic) mass spectrometers
via
an atmospheric-pressure interface. Technical characteristics are described as well as results from direct surface analysis of consumer goods such as plastics, fruit peels or pills, or from living objects such as human skin, demonstrating the detection of various target compounds such as plasticizers, pesticides, drugs or sun blockers. Quantitative analysis is demonstrated for phthalates in plastics. The geometry of the sample, the sample table and the sprayer were modified and characterized for optimization of the method. The autarkic ion source has a total size of 48.4 × 27.0 × 18.0 cm (
l
×
w
×
h
) and a total mass of 7 kg. The source delivers 5.5 bar pressurized air and an adjustable solvent flow rate down to 1.5 μl min
−1
for the DESI sprayer. A rechargeable 25.6 V battery allows autarkic runtimes of more than 3.5 hours. Source optimization and characterization was done on an orbital trapping mass spectrometer. Connected to a portable mass spectrometer, the developed device makes DESI suitable for on-site analyses in
e.g.
consumer protection, border control or homeland security.
A battery-powered DESI source with integrated solvent/gas supply and novel sampling geometry is presented for daily-goods analysis.</description><subject>Chemistry</subject><subject>Chemistry, Analytical</subject><subject>Consumer goods</subject><subject>Consumer protection</subject><subject>Desorption</subject><subject>Electrospraying</subject><subject>Flow velocity</subject><subject>Geometry</subject><subject>Ion sources</subject><subject>Ionization</subject><subject>Ions</subject><subject>Mass spectrometers</subject><subject>National security</subject><subject>Object recognition</subject><subject>Optimization</subject><subject>Pesticides</subject><subject>Phthalates</subject><subject>Physical Sciences</subject><subject>Polymers</subject><subject>Portable equipment</subject><subject>Quantitative analysis</subject><subject>Rechargeable batteries</subject><subject>Sampling</subject><subject>Science & Technology</subject><subject>Spectrometers</subject><subject>Surface analysis (chemical)</subject><subject>Target detection</subject><issn>0003-2654</issn><issn>1364-5528</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNkcGL1DAUh4Mo7jh68S5EvIhSfclrM-lxGHUVFr3owVNJk5cla6epSYuMf72ZGVnBg3hK8vh-gd_3GHss4JUAbF87MCPARuD1HbYSqOqqaaS-y1YAgJVUTX3BHuR8U54CGrjPLlAqqSXiin3dLrNJ34LljnJM0xziyGkgO6eYp2QOvAzCT3Oa57gkS9zHxONY5TATN6MZDjlkHj23cczLnhK_jtHlh-yeN0OmR7_PNfvy7u3n3fvq6tPlh932qrJYw1xZJdve2bomCa2T4HvfUt-SbrzyiF4KNJKM23iqrYa2JemErhU62WutW1yz5-d_pxS_L5Tnbh-ypWEwI8Uld7KWoFDIUnfNnv2F3pRGpcGRQqGFaNSRenGmbFGQE_luSmFv0qET0B2Fd29g-_Ek_LLA-gz_oD76bAONlm4DxXjTaFAbLDeJuzCfRO7iMs4l-vL_o4V-eqZTtrfQn813k_OFefIvBn8Butqn1g</recordid><startdate>20200821</startdate><enddate>20200821</enddate><creator>Lotz, Florian</creator><creator>Gerbig, Stefanie</creator><creator>Lotze, Christian</creator><creator>Spengler, Bernhard</creator><creator>Schulz, Sabine</creator><general>Royal Soc Chemistry</general><general>Royal Society of Chemistry</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-1355-4048</orcidid><orcidid>https://orcid.org/0000-0002-6561-5562</orcidid><orcidid>https://orcid.org/0000-0003-0179-5653</orcidid></search><sort><creationdate>20200821</creationdate><title>Autarkic desorption electrospray ionization source for on-site analysis of consumer goods</title><author>Lotz, Florian ; Gerbig, Stefanie ; Lotze, Christian ; Spengler, Bernhard ; Schulz, Sabine</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c340t-c629bdc44e209d20fbf9eb9e85f6f33f213a2ead7fe4c8099e2d18463d2b88893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Chemistry</topic><topic>Chemistry, Analytical</topic><topic>Consumer goods</topic><topic>Consumer protection</topic><topic>Desorption</topic><topic>Electrospraying</topic><topic>Flow velocity</topic><topic>Geometry</topic><topic>Ion sources</topic><topic>Ionization</topic><topic>Ions</topic><topic>Mass spectrometers</topic><topic>National security</topic><topic>Object recognition</topic><topic>Optimization</topic><topic>Pesticides</topic><topic>Phthalates</topic><topic>Physical Sciences</topic><topic>Polymers</topic><topic>Portable equipment</topic><topic>Quantitative analysis</topic><topic>Rechargeable batteries</topic><topic>Sampling</topic><topic>Science & Technology</topic><topic>Spectrometers</topic><topic>Surface analysis (chemical)</topic><topic>Target detection</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lotz, Florian</creatorcontrib><creatorcontrib>Gerbig, Stefanie</creatorcontrib><creatorcontrib>Lotze, Christian</creatorcontrib><creatorcontrib>Spengler, Bernhard</creatorcontrib><creatorcontrib>Schulz, Sabine</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Analyst (London)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lotz, Florian</au><au>Gerbig, Stefanie</au><au>Lotze, Christian</au><au>Spengler, Bernhard</au><au>Schulz, Sabine</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Autarkic desorption electrospray ionization source for on-site analysis of consumer goods</atitle><jtitle>Analyst (London)</jtitle><stitle>ANALYST</stitle><date>2020-08-21</date><risdate>2020</risdate><volume>145</volume><issue>16</issue><spage>5584</spage><epage>5593</epage><pages>5584-5593</pages><issn>0003-2654</issn><eissn>1364-5528</eissn><abstract>A general-purpose desorption electrospray ionization (DESI) source is presented which is not bound to the laboratory site. It allows autarkic operation for a few hours and can be connected to different types of (autarkic or non-autarkic) mass spectrometers
via
an atmospheric-pressure interface. Technical characteristics are described as well as results from direct surface analysis of consumer goods such as plastics, fruit peels or pills, or from living objects such as human skin, demonstrating the detection of various target compounds such as plasticizers, pesticides, drugs or sun blockers. Quantitative analysis is demonstrated for phthalates in plastics. The geometry of the sample, the sample table and the sprayer were modified and characterized for optimization of the method. The autarkic ion source has a total size of 48.4 × 27.0 × 18.0 cm (
l
×
w
×
h
) and a total mass of 7 kg. The source delivers 5.5 bar pressurized air and an adjustable solvent flow rate down to 1.5 μl min
−1
for the DESI sprayer. A rechargeable 25.6 V battery allows autarkic runtimes of more than 3.5 hours. Source optimization and characterization was done on an orbital trapping mass spectrometer. Connected to a portable mass spectrometer, the developed device makes DESI suitable for on-site analyses in
e.g.
consumer protection, border control or homeland security.
A battery-powered DESI source with integrated solvent/gas supply and novel sampling geometry is presented for daily-goods analysis.</abstract><cop>CAMBRIDGE</cop><pub>Royal Soc Chemistry</pub><pmid>32628233</pmid><doi>10.1039/d0an00713g</doi><orcidid>https://orcid.org/0000-0003-1355-4048</orcidid><orcidid>https://orcid.org/0000-0002-6561-5562</orcidid><orcidid>https://orcid.org/0000-0003-0179-5653</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0003-2654 |
| ispartof | Analyst (London), 2020-08, Vol.145 (16), p.5584-5593 |
| issn | 0003-2654 1364-5528 |
| language | eng |
| recordid | cdi_webofscience_primary_000558067300023CitationCount |
| source | Royal Society of Chemistry Journals Archive (1841-2007); Royal Society Of Chemistry Journals 2008-; Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" />; Alma/SFX Local Collection |
| subjects | Chemistry Chemistry, Analytical Consumer goods Consumer protection Desorption Electrospraying Flow velocity Geometry Ion sources Ionization Ions Mass spectrometers National security Object recognition Optimization Pesticides Phthalates Physical Sciences Polymers Portable equipment Quantitative analysis Rechargeable batteries Sampling Science & Technology Spectrometers Surface analysis (chemical) Target detection |
| title | Autarkic desorption electrospray ionization source for on-site analysis of consumer goods |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-15T14%3A15%3A37IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_webof&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Autarkic%20desorption%20electrospray%20ionization%20source%20for%20on-site%20analysis%20of%20consumer%20goods&rft.jtitle=Analyst%20(London)&rft.au=Lotz,%20Florian&rft.date=2020-08-21&rft.volume=145&rft.issue=16&rft.spage=5584&rft.epage=5593&rft.pages=5584-5593&rft.issn=0003-2654&rft.eissn=1364-5528&rft_id=info:doi/10.1039/d0an00713g&rft_dat=%3Cproquest_webof%3E2431811563%3C/proquest_webof%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2431811563&rft_id=info:pmid/32628233&rfr_iscdi=true |