Surprisingly big linker-dependence of activity and selectivity in CO reduction by an iridium() pincer complex

Here, we report the quantitative electroreduction of CO 2 to CO by a PNP-pincer iridium( i ) complex bearing amino linkers in DMF/water. The electrocatalytic properties greatly depend on the choice of linker within the ligand. The complex 3-N is far superior to the analogues with methylene and oxyge...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2020-08, Vol.56 (64), p.9126-9129
Hauptverfasser:	Hu, Gongfang, Jiang, Jianbing "Jimmy", Kelly, H. Ray, Matula, Adam J, Wu, Yueshen, Romano, Neyen, Mercado, Brandon Q, Wang, Hailiang, Batista, Victor S, Crabtree, Robert H, Brudvig, Gary W
Format:	Artikel
Sprache:	eng
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