Unexpected effect of hydroxyl radical on tellurium corrosion of the Ni–Mo–Cr–Nb based alloy

[Display omitted] The unexpected effect of hydroxyl radical on tellurium corrosion of the Ni–Mo–Cr–Nb based alloy was first observed in this study. In the corrosion experiments with the quartz tubes as vessels, hydroxyl radicals are released from the quartz at the high temperature (700 °C) and then...

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Veröffentlicht in:Corrosion science 2020-08, Vol.173, p.108748, Article 108748
Hauptverfasser: Jiang, Li, Wang, Wei, Ye, Xiang-Xi, Li, Chao-Wen, Liang, Jian-Ping, Wang, De-Jun, Li, Zhi-Jun
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container_title Corrosion science
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Wang, Wei
Ye, Xiang-Xi
Li, Chao-Wen
Liang, Jian-Ping
Wang, De-Jun
Li, Zhi-Jun
description [Display omitted] The unexpected effect of hydroxyl radical on tellurium corrosion of the Ni–Mo–Cr–Nb based alloy was first observed in this study. In the corrosion experiments with the quartz tubes as vessels, hydroxyl radicals are released from the quartz at the high temperature (700 °C) and then react with Cr atoms to form Cr2O3 layers at the surface of the alloy, which significantly suppress the simultaneous corrosion process by tellurium vapor. This work reveals the origin of the well-known uncertainty and helps to develop the more reliable experiments in future.
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source ScienceDirect Journals (5 years ago - present)
subjects Chromium
Corrosion
Corrosion effects
Corrosion tests
High temperature
Hydroxyl radicals
Molten salt reactor
Molybdenum
Nickel
Niobium base alloys
Quartz
Tellurium
Tellurium corrosion
Tubes
title Unexpected effect of hydroxyl radical on tellurium corrosion of the Ni–Mo–Cr–Nb based alloy
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