Recent advances in soluble ruthenium(0) nanocatalysts and their reactivity
[Display omitted] •Simple and convenient methods of generating soluble ruthenium nano-catalysts.•High activity and unique selectivity in a variety of transformations.•Applications in (de)hydrogenation, transfer hydrogenation, and oxidation.•Challenges in nanocatalysis: identification, separation, an...
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| Veröffentlicht in: | Applied catalysis. A, General General, 2020-05, Vol.598, p.117561, Article 117561 |
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| container_title | Applied catalysis. A, General |
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| creator | Reshi, Noor U. Din Samuelson, Ashoka G. |
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•Simple and convenient methods of generating soluble ruthenium nano-catalysts.•High activity and unique selectivity in a variety of transformations.•Applications in (de)hydrogenation, transfer hydrogenation, and oxidation.•Challenges in nanocatalysis: identification, separation, and asymmetric induction.
Metal nanoparticles exhibit unusual properties different from metal complexes and heterogeneous metals and hence draw considerable attention for applications in catalysis, magnetism, medicine, optoelectronics, and sensors. Herein we present an overview of the recent progress in catalysis using soluble ruthenium nanocatalysts (colloids). These nanocatalysts have been widely used for catalyzing the hydrogenation of various substrates particularly arenes due to the milder conditions and the unique selectivities achieved compared to those exhibited by classical heterogeneous catalysts. Ru(0) colloids have been also examined for catalyzing many different reactions including transfer hydrogenation, dehydrogenation, coupling reactions and CH activation, etc. Although in many of these transformations Ru(0) nanocatalysts exhibit high activities, there remain several challenges such as recovery of the soluble catalyst, catalysis by leached molecular clusters, and asymmetric catalysis with high enantioselectivity. |
| doi_str_mv | 10.1016/j.apcata.2020.117561 |
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•Simple and convenient methods of generating soluble ruthenium nano-catalysts.•High activity and unique selectivity in a variety of transformations.•Applications in (de)hydrogenation, transfer hydrogenation, and oxidation.•Challenges in nanocatalysis: identification, separation, and asymmetric induction.
Metal nanoparticles exhibit unusual properties different from metal complexes and heterogeneous metals and hence draw considerable attention for applications in catalysis, magnetism, medicine, optoelectronics, and sensors. Herein we present an overview of the recent progress in catalysis using soluble ruthenium nanocatalysts (colloids). These nanocatalysts have been widely used for catalyzing the hydrogenation of various substrates particularly arenes due to the milder conditions and the unique selectivities achieved compared to those exhibited by classical heterogeneous catalysts. Ru(0) colloids have been also examined for catalyzing many different reactions including transfer hydrogenation, dehydrogenation, coupling reactions and CH activation, etc. Although in many of these transformations Ru(0) nanocatalysts exhibit high activities, there remain several challenges such as recovery of the soluble catalyst, catalysis by leached molecular clusters, and asymmetric catalysis with high enantioselectivity.</description><identifier>ISSN: 0926-860X</identifier><identifier>EISSN: 1873-3875</identifier><identifier>DOI: 10.1016/j.apcata.2020.117561</identifier><language>eng</language><publisher>AMSTERDAM: Elsevier B.V</publisher><subject>Aromatic compounds ; Catalysis ; Catalysts ; Chemical reactions ; Chemistry ; Chemistry, Physical ; Chirality induction ; Colloids ; Coordination compounds ; Coupling (molecular) ; Dehydrogenation ; Enantiomers ; Environmental Sciences ; Environmental Sciences & Ecology ; Hydrogenation ; Life Sciences & Biomedicine ; Ligands ; Magnetism ; Molecular clusters ; Nanocatalysis ; Nanoparticles ; Optoelectronics ; Physical Sciences ; Ru nanoparticles ; Ruthenium ; Science & Technology ; Stabilizers ; Substrates</subject><ispartof>Applied catalysis. A, General, 2020-05, Vol.598, p.117561, Article 117561</ispartof><rights>2020 Elsevier B.V.</rights><rights>Copyright Elsevier Science SA May 25, 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>5</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000536133800011</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c334t-7d5aa753f7a597872d13fa641d9deb2258aaa9ad11b4748837ce4da1d41885ec3</citedby><cites>FETCH-LOGICAL-c334t-7d5aa753f7a597872d13fa641d9deb2258aaa9ad11b4748837ce4da1d41885ec3</cites><orcidid>0000-0001-9416-162X ; 0000-0001-9452-2608</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.apcata.2020.117561$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>315,781,785,3551,27929,27930,28253,46000</link.rule.ids></links><search><creatorcontrib>Reshi, Noor U. Din</creatorcontrib><creatorcontrib>Samuelson, Ashoka G.</creatorcontrib><title>Recent advances in soluble ruthenium(0) nanocatalysts and their reactivity</title><title>Applied catalysis. A, General</title><addtitle>APPL CATAL A-GEN</addtitle><description>[Display omitted]
•Simple and convenient methods of generating soluble ruthenium nano-catalysts.•High activity and unique selectivity in a variety of transformations.•Applications in (de)hydrogenation, transfer hydrogenation, and oxidation.•Challenges in nanocatalysis: identification, separation, and asymmetric induction.
Metal nanoparticles exhibit unusual properties different from metal complexes and heterogeneous metals and hence draw considerable attention for applications in catalysis, magnetism, medicine, optoelectronics, and sensors. Herein we present an overview of the recent progress in catalysis using soluble ruthenium nanocatalysts (colloids). These nanocatalysts have been widely used for catalyzing the hydrogenation of various substrates particularly arenes due to the milder conditions and the unique selectivities achieved compared to those exhibited by classical heterogeneous catalysts. Ru(0) colloids have been also examined for catalyzing many different reactions including transfer hydrogenation, dehydrogenation, coupling reactions and CH activation, etc. Although in many of these transformations Ru(0) nanocatalysts exhibit high activities, there remain several challenges such as recovery of the soluble catalyst, catalysis by leached molecular clusters, and asymmetric catalysis with high enantioselectivity.</description><subject>Aromatic compounds</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Chemistry, Physical</subject><subject>Chirality induction</subject><subject>Colloids</subject><subject>Coordination compounds</subject><subject>Coupling (molecular)</subject><subject>Dehydrogenation</subject><subject>Enantiomers</subject><subject>Environmental Sciences</subject><subject>Environmental Sciences & Ecology</subject><subject>Hydrogenation</subject><subject>Life Sciences & Biomedicine</subject><subject>Ligands</subject><subject>Magnetism</subject><subject>Molecular clusters</subject><subject>Nanocatalysis</subject><subject>Nanoparticles</subject><subject>Optoelectronics</subject><subject>Physical Sciences</subject><subject>Ru nanoparticles</subject><subject>Ruthenium</subject><subject>Science & Technology</subject><subject>Stabilizers</subject><subject>Substrates</subject><issn>0926-860X</issn><issn>1873-3875</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNkF1rFDEUQINYcG39Bz4M-KLIbPM5ybwIslSrFAqi4Fu4m9zBLNtkTTIr--_NMsVH6VNCck5uOIS8ZnTNKBuud2s4OKiw5pS3I6bVwJ6RFTNa9MJo9Zys6MiH3gz05wvyspQdpZTLUa3I12_oMNYO_BGiw9KF2JW0n7d77PJcf2EM88Nb-q6LENN5xv5Uaukg-q5dhtxlBFfDMdTTFbmYYF_w1eN6SX58uvm-ue3v7j9_2Xy8650QsvbaKwCtxKRBjdpo7pmYYJDMjx63nCsDACN4xrZSS2OEdig9MC-ZMQqduCRvlncPOf2esVS7S3OObaTlUhjOmdamUXKhXE6lZJzsIYcHyCfLqD1Xszu7VLPnanap1rT3i_YHt2kqLmCr8k9t2ZRolDBtx860eTq9CRVqSHGT5lib-mFRsaU6Bsz2Ufcho6vWp_D_n_4FeWWX_Q</recordid><startdate>20200525</startdate><enddate>20200525</enddate><creator>Reshi, Noor U. 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Din ; Samuelson, Ashoka G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c334t-7d5aa753f7a597872d13fa641d9deb2258aaa9ad11b4748837ce4da1d41885ec3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aromatic compounds</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>Chemistry, Physical</topic><topic>Chirality induction</topic><topic>Colloids</topic><topic>Coordination compounds</topic><topic>Coupling (molecular)</topic><topic>Dehydrogenation</topic><topic>Enantiomers</topic><topic>Environmental Sciences</topic><topic>Environmental Sciences & Ecology</topic><topic>Hydrogenation</topic><topic>Life Sciences & Biomedicine</topic><topic>Ligands</topic><topic>Magnetism</topic><topic>Molecular clusters</topic><topic>Nanocatalysis</topic><topic>Nanoparticles</topic><topic>Optoelectronics</topic><topic>Physical Sciences</topic><topic>Ru nanoparticles</topic><topic>Ruthenium</topic><topic>Science & Technology</topic><topic>Stabilizers</topic><topic>Substrates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Reshi, Noor U. Din</creatorcontrib><creatorcontrib>Samuelson, Ashoka G.</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied catalysis. A, General</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Reshi, Noor U. Din</au><au>Samuelson, Ashoka G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recent advances in soluble ruthenium(0) nanocatalysts and their reactivity</atitle><jtitle>Applied catalysis. A, General</jtitle><stitle>APPL CATAL A-GEN</stitle><date>2020-05-25</date><risdate>2020</risdate><volume>598</volume><spage>117561</spage><pages>117561-</pages><artnum>117561</artnum><issn>0926-860X</issn><eissn>1873-3875</eissn><abstract>[Display omitted]
•Simple and convenient methods of generating soluble ruthenium nano-catalysts.•High activity and unique selectivity in a variety of transformations.•Applications in (de)hydrogenation, transfer hydrogenation, and oxidation.•Challenges in nanocatalysis: identification, separation, and asymmetric induction.
Metal nanoparticles exhibit unusual properties different from metal complexes and heterogeneous metals and hence draw considerable attention for applications in catalysis, magnetism, medicine, optoelectronics, and sensors. Herein we present an overview of the recent progress in catalysis using soluble ruthenium nanocatalysts (colloids). These nanocatalysts have been widely used for catalyzing the hydrogenation of various substrates particularly arenes due to the milder conditions and the unique selectivities achieved compared to those exhibited by classical heterogeneous catalysts. Ru(0) colloids have been also examined for catalyzing many different reactions including transfer hydrogenation, dehydrogenation, coupling reactions and CH activation, etc. Although in many of these transformations Ru(0) nanocatalysts exhibit high activities, there remain several challenges such as recovery of the soluble catalyst, catalysis by leached molecular clusters, and asymmetric catalysis with high enantioselectivity.</abstract><cop>AMSTERDAM</cop><pub>Elsevier B.V</pub><doi>10.1016/j.apcata.2020.117561</doi><tpages>17</tpages><orcidid>https://orcid.org/0000-0001-9416-162X</orcidid><orcidid>https://orcid.org/0000-0001-9452-2608</orcidid></addata></record> |
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| subjects | Aromatic compounds Catalysis Catalysts Chemical reactions Chemistry Chemistry, Physical Chirality induction Colloids Coordination compounds Coupling (molecular) Dehydrogenation Enantiomers Environmental Sciences Environmental Sciences & Ecology Hydrogenation Life Sciences & Biomedicine Ligands Magnetism Molecular clusters Nanocatalysis Nanoparticles Optoelectronics Physical Sciences Ru nanoparticles Ruthenium Science & Technology Stabilizers Substrates |
| title | Recent advances in soluble ruthenium(0) nanocatalysts and their reactivity |
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