Enhanced Multiple Anchoring and Catalytic Conversion of Polysulfides by Amorphous MoS3 Nanoboxes for High‐Performance Li‐S Batteries
The practical implementation of lithium–sulfur batteries is obstructed by poor conductivity, sluggish redox kinetics, the shuttle effect, large volume variation, and low areal loading of sulfur electrodes. Now, amorphous N‐doped carbon/MoS3 (NC/MoS3) nanoboxes with hollow porous architectures have b...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2020-07, Vol.59 (31), p.13071-13078 |
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| creator | Yu, Jian Xiao, Jiewen Li, Anran Yang, Zhao Zeng, Liang Zhang, Qianfan Zhu, Yujie Guo, Lin |
| description | The practical implementation of lithium–sulfur batteries is obstructed by poor conductivity, sluggish redox kinetics, the shuttle effect, large volume variation, and low areal loading of sulfur electrodes. Now, amorphous N‐doped carbon/MoS3 (NC/MoS3) nanoboxes with hollow porous architectures have been meticulously designed as an advanced sulfur host. Benefiting from the enhanced conductivity by the N‐doped carbon, reduced shuttle effect by the strong chemical interaction between unsaturated Mo and lithium polysulfides, improved redox reaction kinetics by the catalytic effect of MoS3, great tolerance of volume variation and high sulfur loading arising from flexible amorphous materials with hollow‐porous structures, the amorphous NC/MoS3 nanoboxes enabled sulfur electrodes to deliver a high areal capacity with superior rate capacity and decent cycling stability. The synthetic strategy can be generalized to fabricate other amorphous metal sulfide nanoboxes.
Ticking the right nanoboxes: A general strategy for the synthesis of amorphous metal sulfide nanoboxes has been developed. By using the multifunctional amorphous MoS3 nanoboxes as sulfur hosts, a high‐capacity and long‐life Li‐S battery can be realized. |
| doi_str_mv | 10.1002/anie.202004914 |
| format | Article |
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Ticking the right nanoboxes: A general strategy for the synthesis of amorphous metal sulfide nanoboxes has been developed. By using the multifunctional amorphous MoS3 nanoboxes as sulfur hosts, a high‐capacity and long‐life Li‐S battery can be realized.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202004914</identifier><identifier>PMID: 32347627</identifier><language>eng</language><publisher>WEINHEIM: Wiley</publisher><subject>Amorphous materials ; amorphous nanomaterials ; Anchoring ; Carbon ; Catalytic converters ; Chemistry ; Chemistry, Multidisciplinary ; Conductivity ; Electrodes ; heterogeneous catalysis ; hollow nanoboxes ; Kinetics ; Li-S batteries ; Lithium ; Lithium sulfur batteries ; molybdenum polysulfide ; Physical Sciences ; Polysulfides ; Porous materials ; Reaction kinetics ; Science & Technology ; Sulfide ; Sulfur</subject><ispartof>Angewandte Chemie International Edition, 2020-07, Vol.59 (31), p.13071-13078</ispartof><rights>2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>198</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000535739200001</woscitedreferencesoriginalsourcerecordid><cites>FETCH-LOGICAL-g3034-e4535854a42866d0199782ac8ab267058c4d9aafb3ab161731985125fa13723e3</cites><orcidid>0000-0002-6070-2384 ; 0000-0002-8852-5666 ; 0000-0001-8121-7727 ; 0000-0002-6686-3867</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202004914$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202004914$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,781,785,1418,27929,27930,28253,45579,45580</link.rule.ids></links><search><creatorcontrib>Yu, Jian</creatorcontrib><creatorcontrib>Xiao, Jiewen</creatorcontrib><creatorcontrib>Li, Anran</creatorcontrib><creatorcontrib>Yang, Zhao</creatorcontrib><creatorcontrib>Zeng, Liang</creatorcontrib><creatorcontrib>Zhang, Qianfan</creatorcontrib><creatorcontrib>Zhu, Yujie</creatorcontrib><creatorcontrib>Guo, Lin</creatorcontrib><title>Enhanced Multiple Anchoring and Catalytic Conversion of Polysulfides by Amorphous MoS3 Nanoboxes for High‐Performance Li‐S Batteries</title><title>Angewandte Chemie International Edition</title><addtitle>ANGEW CHEM INT EDIT</addtitle><description>The practical implementation of lithium–sulfur batteries is obstructed by poor conductivity, sluggish redox kinetics, the shuttle effect, large volume variation, and low areal loading of sulfur electrodes. Now, amorphous N‐doped carbon/MoS3 (NC/MoS3) nanoboxes with hollow porous architectures have been meticulously designed as an advanced sulfur host. Benefiting from the enhanced conductivity by the N‐doped carbon, reduced shuttle effect by the strong chemical interaction between unsaturated Mo and lithium polysulfides, improved redox reaction kinetics by the catalytic effect of MoS3, great tolerance of volume variation and high sulfur loading arising from flexible amorphous materials with hollow‐porous structures, the amorphous NC/MoS3 nanoboxes enabled sulfur electrodes to deliver a high areal capacity with superior rate capacity and decent cycling stability. The synthetic strategy can be generalized to fabricate other amorphous metal sulfide nanoboxes.
Ticking the right nanoboxes: A general strategy for the synthesis of amorphous metal sulfide nanoboxes has been developed. By using the multifunctional amorphous MoS3 nanoboxes as sulfur hosts, a high‐capacity and long‐life Li‐S battery can be realized.</description><subject>Amorphous materials</subject><subject>amorphous nanomaterials</subject><subject>Anchoring</subject><subject>Carbon</subject><subject>Catalytic converters</subject><subject>Chemistry</subject><subject>Chemistry, Multidisciplinary</subject><subject>Conductivity</subject><subject>Electrodes</subject><subject>heterogeneous catalysis</subject><subject>hollow nanoboxes</subject><subject>Kinetics</subject><subject>Li-S batteries</subject><subject>Lithium</subject><subject>Lithium sulfur batteries</subject><subject>molybdenum polysulfide</subject><subject>Physical Sciences</subject><subject>Polysulfides</subject><subject>Porous materials</subject><subject>Reaction kinetics</subject><subject>Science & Technology</subject><subject>Sulfide</subject><subject>Sulfur</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNksFu1DAQhi0EoqVw5WyJCxJKa3vs2Dku0UIrbUulwtlyEmfXVdZe7KSQG0eOfcY-Sb1qtQdOnDxjfzPzj_Uj9J6SU0oIOzPe2VNGGCG8ovwFOqaC0QKkhJc55gCFVIIeoTcp3WZeKVK-RkfAgMuSyWP0d-k3xre2w5fTMLrdYPHCt5sQnV9j4ztcm9EM8-haXAd_Z2NywePQ4-swzGkaetfZhJsZL7Yh7jZhSvgy3AC-Mj404Xd-60PE5269efhzf21jzrb7eXjl8sUN_mzG0UZn01v0qjdDsu-ezxP048vye31erL59vagXq2INBHhhuQChBDecqbLsCK0qqZhplWlYKYlQLe8qY_oGTENLKoFWeX8mekNBMrBwgj4-9d3F8HOyadRbl1o7DMbbrF4zqMo8SYLI6Id_0NswRZ_VacaZEAIqpjL16Yn6ZZvQp9bZvJ7eRbc1cdaEkCxYZjJHhGZa_T9du9GM-b_rMPkxl1bPpW6w86GGEr13gt47QR-coBdXF8tDBo-6SKcR</recordid><startdate>20200727</startdate><enddate>20200727</enddate><creator>Yu, Jian</creator><creator>Xiao, Jiewen</creator><creator>Li, Anran</creator><creator>Yang, Zhao</creator><creator>Zeng, Liang</creator><creator>Zhang, Qianfan</creator><creator>Zhu, Yujie</creator><creator>Guo, Lin</creator><general>Wiley</general><general>Wiley Subscription Services, Inc</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0002-6070-2384</orcidid><orcidid>https://orcid.org/0000-0002-8852-5666</orcidid><orcidid>https://orcid.org/0000-0001-8121-7727</orcidid><orcidid>https://orcid.org/0000-0002-6686-3867</orcidid></search><sort><creationdate>20200727</creationdate><title>Enhanced Multiple Anchoring and Catalytic Conversion of Polysulfides by Amorphous MoS3 Nanoboxes for High‐Performance Li‐S Batteries</title><author>Yu, Jian ; Xiao, Jiewen ; Li, Anran ; Yang, Zhao ; Zeng, Liang ; Zhang, Qianfan ; Zhu, Yujie ; Guo, Lin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g3034-e4535854a42866d0199782ac8ab267058c4d9aafb3ab161731985125fa13723e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Amorphous materials</topic><topic>amorphous nanomaterials</topic><topic>Anchoring</topic><topic>Carbon</topic><topic>Catalytic converters</topic><topic>Chemistry</topic><topic>Chemistry, Multidisciplinary</topic><topic>Conductivity</topic><topic>Electrodes</topic><topic>heterogeneous catalysis</topic><topic>hollow nanoboxes</topic><topic>Kinetics</topic><topic>Li-S batteries</topic><topic>Lithium</topic><topic>Lithium sulfur batteries</topic><topic>molybdenum polysulfide</topic><topic>Physical Sciences</topic><topic>Polysulfides</topic><topic>Porous materials</topic><topic>Reaction kinetics</topic><topic>Science & Technology</topic><topic>Sulfide</topic><topic>Sulfur</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yu, Jian</creatorcontrib><creatorcontrib>Xiao, Jiewen</creatorcontrib><creatorcontrib>Li, Anran</creatorcontrib><creatorcontrib>Yang, Zhao</creatorcontrib><creatorcontrib>Zeng, Liang</creatorcontrib><creatorcontrib>Zhang, Qianfan</creatorcontrib><creatorcontrib>Zhu, Yujie</creatorcontrib><creatorcontrib>Guo, Lin</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yu, Jian</au><au>Xiao, Jiewen</au><au>Li, Anran</au><au>Yang, Zhao</au><au>Zeng, Liang</au><au>Zhang, Qianfan</au><au>Zhu, Yujie</au><au>Guo, Lin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced Multiple Anchoring and Catalytic Conversion of Polysulfides by Amorphous MoS3 Nanoboxes for High‐Performance Li‐S Batteries</atitle><jtitle>Angewandte Chemie International Edition</jtitle><stitle>ANGEW CHEM INT EDIT</stitle><date>2020-07-27</date><risdate>2020</risdate><volume>59</volume><issue>31</issue><spage>13071</spage><epage>13078</epage><pages>13071-13078</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>The practical implementation of lithium–sulfur batteries is obstructed by poor conductivity, sluggish redox kinetics, the shuttle effect, large volume variation, and low areal loading of sulfur electrodes. Now, amorphous N‐doped carbon/MoS3 (NC/MoS3) nanoboxes with hollow porous architectures have been meticulously designed as an advanced sulfur host. Benefiting from the enhanced conductivity by the N‐doped carbon, reduced shuttle effect by the strong chemical interaction between unsaturated Mo and lithium polysulfides, improved redox reaction kinetics by the catalytic effect of MoS3, great tolerance of volume variation and high sulfur loading arising from flexible amorphous materials with hollow‐porous structures, the amorphous NC/MoS3 nanoboxes enabled sulfur electrodes to deliver a high areal capacity with superior rate capacity and decent cycling stability. The synthetic strategy can be generalized to fabricate other amorphous metal sulfide nanoboxes.
Ticking the right nanoboxes: A general strategy for the synthesis of amorphous metal sulfide nanoboxes has been developed. By using the multifunctional amorphous MoS3 nanoboxes as sulfur hosts, a high‐capacity and long‐life Li‐S battery can be realized.</abstract><cop>WEINHEIM</cop><pub>Wiley</pub><pmid>32347627</pmid><doi>10.1002/anie.202004914</doi><tpages>8</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-6070-2384</orcidid><orcidid>https://orcid.org/0000-0002-8852-5666</orcidid><orcidid>https://orcid.org/0000-0001-8121-7727</orcidid><orcidid>https://orcid.org/0000-0002-6686-3867</orcidid></addata></record> |
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| subjects | Amorphous materials amorphous nanomaterials Anchoring Carbon Catalytic converters Chemistry Chemistry, Multidisciplinary Conductivity Electrodes heterogeneous catalysis hollow nanoboxes Kinetics Li-S batteries Lithium Lithium sulfur batteries molybdenum polysulfide Physical Sciences Polysulfides Porous materials Reaction kinetics Science & Technology Sulfide Sulfur |
| title | Enhanced Multiple Anchoring and Catalytic Conversion of Polysulfides by Amorphous MoS3 Nanoboxes for High‐Performance Li‐S Batteries |
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