Ethylene Glycol: A Green Solvent for Visible Light‐Promoted Aerobic Transition Metal‐Free Cascade Sulfonation/Cyclization Reaction
With ethylene glycol as a green solvent, a general transition metal‐free photocatalytic system using 9‐mesityl‐10‐methylacridinium perchlorate (Acr+−Mes ⋅ ClO4−) as catalyst was developed for the synthesis of sulfone‐containing heterocycles including thioflavones, oxindoles, and quinoline‐2,4(1H,3H)...
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| Veröffentlicht in: | Advanced synthesis & catalysis 2020-07, Vol.362 (13), p.2609-2614 |
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| container_title | Advanced synthesis & catalysis |
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| creator | Jiang, Yu‐Qin Li, Jing Feng, Zhi‐Wen Xu, Gui‐Qing Shi, Xin Ding, Qing‐Jie Li, Wei Ma, Chun‐Hua Yu, Bing |
| description | With ethylene glycol as a green solvent, a general transition metal‐free photocatalytic system using 9‐mesityl‐10‐methylacridinium perchlorate (Acr+−Mes ⋅ ClO4−) as catalyst was developed for the synthesis of sulfone‐containing heterocycles including thioflavones, oxindoles, and quinoline‐2,4(1H,3H)‐diones through the cascade sulfonation/cyclization reactions under the irradiation of blue light at room temperature. |
| doi_str_mv | 10.1002/adsc.202000233 |
| format | Article |
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| subjects | Cascade chemical reactions Chemical reactions Chemical synthesis Chemistry Chemistry, Applied Chemistry, Organic Cyclization Ethylene glycol Green solvent Heterocycles Photocatalysis Physical Sciences Quinoline Room temperature Science & Technology Solvents Sulfonation Transition metals |
| title | Ethylene Glycol: A Green Solvent for Visible Light‐Promoted Aerobic Transition Metal‐Free Cascade Sulfonation/Cyclization Reaction |
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