Exfoliation in a low boiling point solvent and electrochemical applications of MoO3
MoO3 is a versatile two-dimensional transition metal oxide having applications in areas such as energy storage devices, electronic devices and catalysis. To efficiently utilize the properties of MoO3 arising from its two-dimensional nature exfoliation is necessary. In this work, the exfoliation of M...
Gespeichert in:
| Veröffentlicht in: | Beilstein journal of nanotechnology 2020, Vol.11 (1), p.662-670 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 670 |
|---|---|
| container_issue | 1 |
| container_start_page | 662 |
| container_title | Beilstein journal of nanotechnology |
| container_volume | 11 |
| creator | Sricharan, Matangi Gupta, Bikesh Moolayadukkam, Sreejesh Matte, H. S. S. Ramakrishna |
| description | MoO3 is a versatile two-dimensional transition metal oxide having applications in areas such as energy storage devices, electronic devices and catalysis. To efficiently utilize the properties of MoO3 arising from its two-dimensional nature exfoliation is necessary. In this work, the exfoliation of MoO3 is carried out in 2-butanone for the first time. The achieved concentration of the dispersion is about 0.57 mg.mL(-1) with a yield of 5.7%, which are the highest values reported to date. These high values of concentration and yield can be attributed to a favorable matching of energies involved in exfoliation and stabilization of MoO3 nanosheets in 2-butanone. Interestingly, the MoO3 dispersion in 2-butanone retains its intrinsic nature even after exposure to sunlight for 24 h. The composites of MoO3 nanosheets were used as an electrode material for supercapacitors and showed a high specific capacitance of 201 F.g(-1) in a three-electrode configuration at a scan rate of 50 mV.s(-1). |
| doi_str_mv | 10.3762/bjnano.11.52 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_webof</sourceid><recordid>TN_cdi_webofscience_primary_000526549000001</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><doaj_id>oai_doaj_org_article_8dc4631baa4841638315ecf2532a9b17</doaj_id><sourcerecordid>2407946932</sourcerecordid><originalsourceid>FETCH-LOGICAL-d375t-d5929007c30bebcd037ce47d7cda46478dbf663cd2f4be168020958a35c777263</originalsourceid><addsrcrecordid>eNqNkctqWzEQhkVoaYKTXR9A0E2h2NX9sikUkzaBlCzaroVux5GRpdNzSdK3rxyHkHSV2cww-udjRj8A7zFaUSnIZ7ctttQVxitOjsAJwRotGVHizbP6GJyN4xa1YIgord6BY0qooJiSE_Dz_L6rOdkp1QJTgRbmegddTTmVDexrKhMca76NLdsSYMzRT0P1N3GXvM3Q9n1uxX58hLWDP-o1PQVvO5vHePaYF-D3t_Nf64vl1fX3y_XXq2Wgkk_LwDXRCElPkYvOB0Slj0wG6YNlgkkVXCcE9YF0zEUsFCJIc2Up91JKIugCXB64odqt6Ye0s8NfU20yD406bIwdpuRzNCp41i521jLFsKCKYh59RzglVjssG-vLgdXPbheDb_cONr-Avnwp6cZs6q2RWApNUAN8fAQM9c8cx8ns0uhjzrbEOo-GUK2wQFzt9_7wn3Rb56G0rzKEIamZ0M2gBfh0UN1FV7vRp1h8fFqoucmJ4EzvfUW4qdXr1es0PTi2rnOZ6D__zLKJ</addsrcrecordid><sourcetype>Open Website</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2407946932</pqid></control><display><type>article</type><title>Exfoliation in a low boiling point solvent and electrochemical applications of MoO3</title><source>Directory of Open Access Journals</source><source>PubMed Central Open Access</source><source>PubMed (Medline)</source><source>Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /></source><source>Free E-Journal (出版社公開部分のみ）</source><source>Free Full-Text Journals in Chemistry</source><creator>Sricharan, Matangi ; Gupta, Bikesh ; Moolayadukkam, Sreejesh ; Matte, H. S. S. Ramakrishna</creator><creatorcontrib>Sricharan, Matangi ; Gupta, Bikesh ; Moolayadukkam, Sreejesh ; Matte, H. S. S. Ramakrishna</creatorcontrib><description>MoO3 is a versatile two-dimensional transition metal oxide having applications in areas such as energy storage devices, electronic devices and catalysis. To efficiently utilize the properties of MoO3 arising from its two-dimensional nature exfoliation is necessary. In this work, the exfoliation of MoO3 is carried out in 2-butanone for the first time. The achieved concentration of the dispersion is about 0.57 mg.mL(-1) with a yield of 5.7%, which are the highest values reported to date. These high values of concentration and yield can be attributed to a favorable matching of energies involved in exfoliation and stabilization of MoO3 nanosheets in 2-butanone. Interestingly, the MoO3 dispersion in 2-butanone retains its intrinsic nature even after exposure to sunlight for 24 h. The composites of MoO3 nanosheets were used as an electrode material for supercapacitors and showed a high specific capacitance of 201 F.g(-1) in a three-electrode configuration at a scan rate of 50 mV.s(-1).</description><identifier>ISSN: 2190-4286</identifier><identifier>EISSN: 2190-4286</identifier><identifier>DOI: 10.3762/bjnano.11.52</identifier><identifier>PMID: 32363132</identifier><language>eng</language><publisher>FRANKFURT AM MAIN: Beilstein-Institut</publisher><subject>2-butanone ; Boiling points ; Carbon black ; Dispersion ; Electrode materials ; Electrodes ; Electrolytes ; Electronic devices ; Energy storage ; Exfoliation ; Graphene ; Letter ; liquid-phase exfoliation ; low-boiling point solvent ; Materials Science ; Materials Science, Multidisciplinary ; Microscopy ; Molybdenum ; Molybdenum oxides ; Molybdenum trioxide ; molybdenum trioxide (moo3) ; Nanoscience ; Nanoscience & Nanotechnology ; Nanostructure ; Nanotechnology ; Physical Sciences ; Physics ; Physics, Applied ; Science & Technology ; Science & Technology - Other Topics ; supercapacitors ; Technology ; Transition metal oxides</subject><ispartof>Beilstein journal of nanotechnology, 2020, Vol.11 (1), p.662-670</ispartof><rights>Copyright © 2020, Sricharan et al.; licensee Beilstein-Institut. This work is published under http://creativecommons.org/licenses/by/4.0 (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>Copyright © 2020, Sricharan et al. 2020 Sricharan et al.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>9</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000526549000001</woscitedreferencesoriginalsourcerecordid><cites>FETCH-LOGICAL-d375t-d5929007c30bebcd037ce47d7cda46478dbf663cd2f4be168020958a35c777263</cites><orcidid>0000-0002-1046-447X ; 0000-0001-8279-8447</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7176920/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7176920/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,315,728,781,785,865,886,2103,2115,4025,27928,27929,27930,28253,53796,53798</link.rule.ids></links><search><creatorcontrib>Sricharan, Matangi</creatorcontrib><creatorcontrib>Gupta, Bikesh</creatorcontrib><creatorcontrib>Moolayadukkam, Sreejesh</creatorcontrib><creatorcontrib>Matte, H. S. S. Ramakrishna</creatorcontrib><title>Exfoliation in a low boiling point solvent and electrochemical applications of MoO3</title><title>Beilstein journal of nanotechnology</title><addtitle>BEILSTEIN J NANOTECH</addtitle><description>MoO3 is a versatile two-dimensional transition metal oxide having applications in areas such as energy storage devices, electronic devices and catalysis. To efficiently utilize the properties of MoO3 arising from its two-dimensional nature exfoliation is necessary. In this work, the exfoliation of MoO3 is carried out in 2-butanone for the first time. The achieved concentration of the dispersion is about 0.57 mg.mL(-1) with a yield of 5.7%, which are the highest values reported to date. These high values of concentration and yield can be attributed to a favorable matching of energies involved in exfoliation and stabilization of MoO3 nanosheets in 2-butanone. Interestingly, the MoO3 dispersion in 2-butanone retains its intrinsic nature even after exposure to sunlight for 24 h. The composites of MoO3 nanosheets were used as an electrode material for supercapacitors and showed a high specific capacitance of 201 F.g(-1) in a three-electrode configuration at a scan rate of 50 mV.s(-1).</description><subject>2-butanone</subject><subject>Boiling points</subject><subject>Carbon black</subject><subject>Dispersion</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Electronic devices</subject><subject>Energy storage</subject><subject>Exfoliation</subject><subject>Graphene</subject><subject>Letter</subject><subject>liquid-phase exfoliation</subject><subject>low-boiling point solvent</subject><subject>Materials Science</subject><subject>Materials Science, Multidisciplinary</subject><subject>Microscopy</subject><subject>Molybdenum</subject><subject>Molybdenum oxides</subject><subject>Molybdenum trioxide</subject><subject>molybdenum trioxide (moo3)</subject><subject>Nanoscience</subject><subject>Nanoscience & Nanotechnology</subject><subject>Nanostructure</subject><subject>Nanotechnology</subject><subject>Physical Sciences</subject><subject>Physics</subject><subject>Physics, Applied</subject><subject>Science & Technology</subject><subject>Science & Technology - Other Topics</subject><subject>supercapacitors</subject><subject>Technology</subject><subject>Transition metal oxides</subject><issn>2190-4286</issn><issn>2190-4286</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><sourceid>DOA</sourceid><recordid>eNqNkctqWzEQhkVoaYKTXR9A0E2h2NX9sikUkzaBlCzaroVux5GRpdNzSdK3rxyHkHSV2cww-udjRj8A7zFaUSnIZ7ctttQVxitOjsAJwRotGVHizbP6GJyN4xa1YIgord6BY0qooJiSE_Dz_L6rOdkp1QJTgRbmegddTTmVDexrKhMca76NLdsSYMzRT0P1N3GXvM3Q9n1uxX58hLWDP-o1PQVvO5vHePaYF-D3t_Nf64vl1fX3y_XXq2Wgkk_LwDXRCElPkYvOB0Slj0wG6YNlgkkVXCcE9YF0zEUsFCJIc2Up91JKIugCXB64odqt6Ye0s8NfU20yD406bIwdpuRzNCp41i521jLFsKCKYh59RzglVjssG-vLgdXPbheDb_cONr-Avnwp6cZs6q2RWApNUAN8fAQM9c8cx8ns0uhjzrbEOo-GUK2wQFzt9_7wn3Rb56G0rzKEIamZ0M2gBfh0UN1FV7vRp1h8fFqoucmJ4EzvfUW4qdXr1es0PTi2rnOZ6D__zLKJ</recordid><startdate>2020</startdate><enddate>2020</enddate><creator>Sricharan, Matangi</creator><creator>Gupta, Bikesh</creator><creator>Moolayadukkam, Sreejesh</creator><creator>Matte, H. S. S. Ramakrishna</creator><general>Beilstein-Institut</general><general>Beilstein-Institut zur Föerderung der Chemischen Wissenschaften</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>3V.</scope><scope>7XB</scope><scope>88I</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ARAPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BFMQW</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>M2P</scope><scope>P5Z</scope><scope>P62</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope><scope>DOA</scope><orcidid>https://orcid.org/0000-0002-1046-447X</orcidid><orcidid>https://orcid.org/0000-0001-8279-8447</orcidid></search><sort><creationdate>2020</creationdate><title>Exfoliation in a low boiling point solvent and electrochemical applications of MoO3</title><author>Sricharan, Matangi ; Gupta, Bikesh ; Moolayadukkam, Sreejesh ; Matte, H. S. S. Ramakrishna</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-d375t-d5929007c30bebcd037ce47d7cda46478dbf663cd2f4be168020958a35c777263</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>2-butanone</topic><topic>Boiling points</topic><topic>Carbon black</topic><topic>Dispersion</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Electronic devices</topic><topic>Energy storage</topic><topic>Exfoliation</topic><topic>Graphene</topic><topic>Letter</topic><topic>liquid-phase exfoliation</topic><topic>low-boiling point solvent</topic><topic>Materials Science</topic><topic>Materials Science, Multidisciplinary</topic><topic>Microscopy</topic><topic>Molybdenum</topic><topic>Molybdenum oxides</topic><topic>Molybdenum trioxide</topic><topic>molybdenum trioxide (moo3)</topic><topic>Nanoscience</topic><topic>Nanoscience & Nanotechnology</topic><topic>Nanostructure</topic><topic>Nanotechnology</topic><topic>Physical Sciences</topic><topic>Physics</topic><topic>Physics, Applied</topic><topic>Science & Technology</topic><topic>Science & Technology - Other Topics</topic><topic>supercapacitors</topic><topic>Technology</topic><topic>Transition metal oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sricharan, Matangi</creatorcontrib><creatorcontrib>Gupta, Bikesh</creatorcontrib><creatorcontrib>Moolayadukkam, Sreejesh</creatorcontrib><creatorcontrib>Matte, H. S. S. Ramakrishna</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>ProQuest Central (Corporate)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Advanced Technologies & Aerospace Database (1962 - current)</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Continental Europe Database</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>ProQuest Science Journals</collection><collection>ProQuest Advanced Technologies & Aerospace Database</collection><collection>ProQuest Advanced Technologies & Aerospace Collection</collection><collection>Access via ProQuest (Open Access)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><collection>Directory of Open Access Journals</collection><jtitle>Beilstein journal of nanotechnology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sricharan, Matangi</au><au>Gupta, Bikesh</au><au>Moolayadukkam, Sreejesh</au><au>Matte, H. S. S. Ramakrishna</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Exfoliation in a low boiling point solvent and electrochemical applications of MoO3</atitle><jtitle>Beilstein journal of nanotechnology</jtitle><stitle>BEILSTEIN J NANOTECH</stitle><date>2020</date><risdate>2020</risdate><volume>11</volume><issue>1</issue><spage>662</spage><epage>670</epage><pages>662-670</pages><issn>2190-4286</issn><eissn>2190-4286</eissn><abstract>MoO3 is a versatile two-dimensional transition metal oxide having applications in areas such as energy storage devices, electronic devices and catalysis. To efficiently utilize the properties of MoO3 arising from its two-dimensional nature exfoliation is necessary. In this work, the exfoliation of MoO3 is carried out in 2-butanone for the first time. The achieved concentration of the dispersion is about 0.57 mg.mL(-1) with a yield of 5.7%, which are the highest values reported to date. These high values of concentration and yield can be attributed to a favorable matching of energies involved in exfoliation and stabilization of MoO3 nanosheets in 2-butanone. Interestingly, the MoO3 dispersion in 2-butanone retains its intrinsic nature even after exposure to sunlight for 24 h. The composites of MoO3 nanosheets were used as an electrode material for supercapacitors and showed a high specific capacitance of 201 F.g(-1) in a three-electrode configuration at a scan rate of 50 mV.s(-1).</abstract><cop>FRANKFURT AM MAIN</cop><pub>Beilstein-Institut</pub><pmid>32363132</pmid><doi>10.3762/bjnano.11.52</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-1046-447X</orcidid><orcidid>https://orcid.org/0000-0001-8279-8447</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2190-4286 |
| ispartof | Beilstein journal of nanotechnology, 2020, Vol.11 (1), p.662-670 |
| issn | 2190-4286 2190-4286 |
| language | eng |
| recordid | cdi_webofscience_primary_000526549000001 |
| source | Directory of Open Access Journals; PubMed Central Open Access; PubMed (Medline); Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" />; Free E-Journal (出版社公開部分のみ）; Free Full-Text Journals in Chemistry |
| subjects | 2-butanone Boiling points Carbon black Dispersion Electrode materials Electrodes Electrolytes Electronic devices Energy storage Exfoliation Graphene Letter liquid-phase exfoliation low-boiling point solvent Materials Science Materials Science, Multidisciplinary Microscopy Molybdenum Molybdenum oxides Molybdenum trioxide molybdenum trioxide (moo3) Nanoscience Nanoscience & Nanotechnology Nanostructure Nanotechnology Physical Sciences Physics Physics, Applied Science & Technology Science & Technology - Other Topics supercapacitors Technology Transition metal oxides |
| title | Exfoliation in a low boiling point solvent and electrochemical applications of MoO3 |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-13T20%3A52%3A26IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_webof&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Exfoliation%20in%20a%20low%20boiling%20point%20solvent%20and%20electrochemical%20applications%20of%20MoO3&rft.jtitle=Beilstein%20journal%20of%20nanotechnology&rft.au=Sricharan,%20Matangi&rft.date=2020&rft.volume=11&rft.issue=1&rft.spage=662&rft.epage=670&rft.pages=662-670&rft.issn=2190-4286&rft.eissn=2190-4286&rft_id=info:doi/10.3762/bjnano.11.52&rft_dat=%3Cproquest_webof%3E2407946932%3C/proquest_webof%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2407946932&rft_id=info:pmid/32363132&rft_doaj_id=oai_doaj_org_article_8dc4631baa4841638315ecf2532a9b17&rfr_iscdi=true |