Topochemical anion insertion into one-dimensional Bi channels in Bi2PdO4

Topochemical anion insertion into one-dimensional Bi channels in Bi2PdO4

We show anion intercalation reaction to ternary palladate Bi2PdO4 (P4/ncc) with one-dimensional (1D) channels comprised of Bi3+ ions. By low-temperature treatment with XeF2, fluoride anions are inserted in the 1D pores (4b site), giving Bi2PdO4Fx (x ​

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Veröffentlicht in:Journal of solid state chemistry 2020-06, Vol.286, p.121273, Article 121273
Hauptverfasser: Takeiri, Fumitaka, Yajima, Takeshi, Hosokawa, Saburo, Matsushita, Yoshitaka, Kageyama, Hiroshi
Format: Artikel
Sprache:eng
Schlagworte:
Anion diffusion
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Physical
Mixed anion oxides
Oxyfluoride
Physical Sciences
Science & Technology
Topochemical synthesis
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Zusammenfassung:We show anion intercalation reaction to ternary palladate Bi2PdO4 (P4/ncc) with one-dimensional (1D) channels comprised of Bi3+ ions. By low-temperature treatment with XeF2, fluoride anions are inserted in the 1D pores (4b site), giving Bi2PdO4Fx (x ​
ISSN:0022-4596
1095-726X
DOI:10.1016/j.jssc.2020.121273