Quantitative composition determination by Mössbauer spectroscopy

Quantitative Fe content determination of powders by Mössbauer spectroscopy is described. In this method, powder samples and internal standard are combined homogeneously in a plastic film ensuring a thin absorber. This method was verified by quantifying the Fe content of a series of samples and indep...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	MRS communications 2020-03, Vol.10 (1), p.123-128, Article 2159685919001587
Hauptverfasser:	Scott, B., Brown, C. A. M., Dunlap, R. A., Obrovac, M. N.
Format:	Artikel
Sprache:	eng
Schlagworte:	Ball milling Biomaterials Characterization and Evaluation of Materials Contamination Emission analysis Fluorides Gamma rays Glass substrates Grain size Inductively coupled plasma Iron Materials Engineering Materials Science Materials Science, Multidisciplinary Mossbauer spectroscopy Nanotechnology Polymer films Polymer Sciences Research Letter Science & Technology Size reduction Stainless steel Technology
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Quantitative Fe content determination of powders by Mössbauer spectroscopy is described. In this method, powder samples and internal standard are combined homogeneously in a plastic film ensuring a thin absorber. This method was verified by quantifying the Fe content of a series of samples and independently confirming by inductively coupled plasma optical emission spectroscopic analysis. Additionally, for the first time, Fe contamination in ball-milled Si as a function of milling time was quantified. It was found that Fe contamination increased with time but surprisingly became steady state at 1.12 ± 0.04 at.% Fe after grain size reduction.
ISSN:	2159-6859 2159-6867
DOI:	10.1557/mrc.2019.158