Assembly of cerium-based coordination polymer into variant polycrystalline 2D-3D CeO2-x nanostructures

Precise control over the morphology of nanomaterials is critical yet challenging. The present work reports an efficient approach to tailor the architecture of nanostructures. The process involves rapid disassembly/reassembly of an unstable metal-based coordination polymer (MCP) by controlling the kinetics of the reassembly process. The synthesis procedure delivers unprecedented polycrystalline nanostructures, e.g., holey 2D CeO2-x nanosheets, with precisely tailored thicknesses in the range of 10-100 nm, and hollow 3D pseudo-octahedra and spheres. The consequent high surface areas and pore volumes, short diffusion distances, and high defect densities of the holey 2D CeO2-x indicate significant densities of active sites. This holey architecture exhibits rapid CO conversion and outstanding solar light photocatalytic performance. This approach of directed assembly offers a template-free, controllable, and cost-effective approach to achieve engineered CeO2-x architectures, which are nearly impossible through existing approaches.