Ring‐Strain‐Promoted Ultrafast Diaryltetrazole–Alkyne Photoclick Reactions Triggered by Visible Light

By exploiting the scope of dipolarophiles, we discovered that endo‐bicyclo[6.1.0]non‐4‐yn‐9‐ylmethanol (BCN) is an appropriate chemical reporter for the 2,5‐diaryltetrazole (DATet) based photoclick reaction, which proceeds via an ultrafast cycloaddition rate (∼105 M−1 s−1). Introduction of a 2,6‐(CF...

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Veröffentlicht in:	ChemPhotoChem 2020-05, Vol.4 (5), p.327-331
Hauptverfasser:	Jiang, Shichao, Wu, Xueting, Liu, Hui, Deng, Jiajie, Zhang, Xiaocui, Yao, Zhuojun, Zheng, Yuanqin, Li, Bo, Yu, Zhipeng
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry, Physical cycloaddition fluorescent probes phototrigger Physical Sciences protein modifications ring-strained alkyne Science & Technology
Online-Zugang:	Volltext
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