Ultrathin Films of Porous Metal–Organic Polyhedra for Gas Separation
Ultrathin films of a robust RhII‐based porous metal–organic polyhedra (MOP) have been obtained. Homogeneous and compact monolayer films (ca. 2.5 nm thick) were first formed at the air–water interface, deposited onto different substrates and characterized using spectroscopic methods, scanning transmi...
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| Veröffentlicht in: | Chemistry : a European journal 2020-01, Vol.26 (1), p.143-147 |
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| container_title | Chemistry : a European journal |
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| creator | Andrés, Miguel A. Carné‐Sánchez, Arnau Sánchez‐Laínez, Javier Roubeau, Olivier Coronas, Joaquín Maspoch, Daniel Gascón, Ignacio |
| description | Ultrathin films of a robust RhII‐based porous metal–organic polyhedra (MOP) have been obtained. Homogeneous and compact monolayer films (ca. 2.5 nm thick) were first formed at the air–water interface, deposited onto different substrates and characterized using spectroscopic methods, scanning transmission electron microscopy and atomic force microscopy. As a proof of concept, the gas separation performance of MOP‐supported membranes has also been evaluated. Selective MOP ultrathin films (thickness ca. 60 nm) exhibit remarkable CO2 permeance and CO2/N2 selectivity, demonstrating the great combined potential of MOP and Langmuir‐based techniques in separation technologies.
Fabrication of compact and dense porous metal–organic polyhedra (MOP) ultrathin films offers several advantages for the development of MOP‐based applications in gas separation. MOP‐supported membranes obtained by successive RhII‐based MOP monolayer deposition can be applied for efficient CO2 separation (see figure). |
| doi_str_mv | 10.1002/chem.201904141 |
| format | Article |
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Fabrication of compact and dense porous metal–organic polyhedra (MOP) ultrathin films offers several advantages for the development of MOP‐based applications in gas separation. MOP‐supported membranes obtained by successive RhII‐based MOP monolayer deposition can be applied for efficient CO2 separation (see figure).</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201904141</identifier><identifier>PMID: 31692089</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Atomic force microscopy ; Carbon dioxide ; Chemistry ; CO2 separation ; Electronics ; Gas separation ; Langmuir–Blodgett technique ; Membranes ; metal–organic polyhedra ; Microscopy ; Polyhedra ; scanning electron microscopy ; Scanning transmission electron microscopy ; Selectivity ; Substrates ; Thickness ; Thin films ; Transmission electron microscopy</subject><ispartof>Chemistry : a European journal, 2020-01, Vol.26 (1), p.143-147</ispartof><rights>2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5161-370be0df13f2633cc8606dc8a44a0f886f91d09ef82aeb62d8f22643aac024a63</citedby><cites>FETCH-LOGICAL-c5161-370be0df13f2633cc8606dc8a44a0f886f91d09ef82aeb62d8f22643aac024a63</cites><orcidid>0000-0003-3691-3437 ; 0000-0001-6627-0079 ; 0000-0002-8569-6208 ; 0000-0003-1325-9161 ; 0000-0003-2095-5843 ; 0000-0003-1512-4500 ; 0000-0002-3492-6456</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201904141$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201904141$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/31692089$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Andrés, Miguel A.</creatorcontrib><creatorcontrib>Carné‐Sánchez, Arnau</creatorcontrib><creatorcontrib>Sánchez‐Laínez, Javier</creatorcontrib><creatorcontrib>Roubeau, Olivier</creatorcontrib><creatorcontrib>Coronas, Joaquín</creatorcontrib><creatorcontrib>Maspoch, Daniel</creatorcontrib><creatorcontrib>Gascón, Ignacio</creatorcontrib><title>Ultrathin Films of Porous Metal–Organic Polyhedra for Gas Separation</title><title>Chemistry : a European journal</title><addtitle>Chemistry</addtitle><description>Ultrathin films of a robust RhII‐based porous metal–organic polyhedra (MOP) have been obtained. Homogeneous and compact monolayer films (ca. 2.5 nm thick) were first formed at the air–water interface, deposited onto different substrates and characterized using spectroscopic methods, scanning transmission electron microscopy and atomic force microscopy. As a proof of concept, the gas separation performance of MOP‐supported membranes has also been evaluated. Selective MOP ultrathin films (thickness ca. 60 nm) exhibit remarkable CO2 permeance and CO2/N2 selectivity, demonstrating the great combined potential of MOP and Langmuir‐based techniques in separation technologies.
Fabrication of compact and dense porous metal–organic polyhedra (MOP) ultrathin films offers several advantages for the development of MOP‐based applications in gas separation. MOP‐supported membranes obtained by successive RhII‐based MOP monolayer deposition can be applied for efficient CO2 separation (see figure).</description><subject>Atomic force microscopy</subject><subject>Carbon dioxide</subject><subject>Chemistry</subject><subject>CO2 separation</subject><subject>Electronics</subject><subject>Gas separation</subject><subject>Langmuir–Blodgett technique</subject><subject>Membranes</subject><subject>metal–organic polyhedra</subject><subject>Microscopy</subject><subject>Polyhedra</subject><subject>scanning electron microscopy</subject><subject>Scanning transmission electron microscopy</subject><subject>Selectivity</subject><subject>Substrates</subject><subject>Thickness</subject><subject>Thin films</subject><subject>Transmission electron microscopy</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkMtKAzEUhoMotla3LmXAjZupJ5dJJ0spvQgtFbTrIc0kdkpmpiYdpDvfwTf0SUxpreDG1YHDd36-8yN0jaGLAci9WuqySwALYJjhE9TGCcEx7fHkFLVBsF7MEypa6ML7FQAITuk5alHMBYFUtNFwbjdObpZFFQ0LW_qoNtFT7erGR1O9kfbr43PmXmVVqLC226XOnYxM7aKR9NGzXstwXNTVJToz0np9dZgdNB8OXvrjeDIbPfYfJrFKMN95wUJDbjA1JJgolXLguUolYxJMmnIjcA5Cm5RIveAkTw0hnFEpFRAmOe2gu33u2tVvjfabrCy80tbKSgfnjFBMEpYyIQJ6-wdd1Y2rgl2gKO6F_xMSqO6eUq723mmTrV1RSrfNMGS7hrNdw9mx4XBwc4htFqXOj_hPpQEQe-C9sHr7T1zWHw-mv-HfH4-HDw</recordid><startdate>20200102</startdate><enddate>20200102</enddate><creator>Andrés, Miguel A.</creator><creator>Carné‐Sánchez, Arnau</creator><creator>Sánchez‐Laínez, Javier</creator><creator>Roubeau, Olivier</creator><creator>Coronas, Joaquín</creator><creator>Maspoch, Daniel</creator><creator>Gascón, Ignacio</creator><general>Wiley Subscription Services, Inc</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-3691-3437</orcidid><orcidid>https://orcid.org/0000-0001-6627-0079</orcidid><orcidid>https://orcid.org/0000-0002-8569-6208</orcidid><orcidid>https://orcid.org/0000-0003-1325-9161</orcidid><orcidid>https://orcid.org/0000-0003-2095-5843</orcidid><orcidid>https://orcid.org/0000-0003-1512-4500</orcidid><orcidid>https://orcid.org/0000-0002-3492-6456</orcidid></search><sort><creationdate>20200102</creationdate><title>Ultrathin Films of Porous Metal–Organic Polyhedra for Gas Separation</title><author>Andrés, Miguel A. ; 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Homogeneous and compact monolayer films (ca. 2.5 nm thick) were first formed at the air–water interface, deposited onto different substrates and characterized using spectroscopic methods, scanning transmission electron microscopy and atomic force microscopy. As a proof of concept, the gas separation performance of MOP‐supported membranes has also been evaluated. Selective MOP ultrathin films (thickness ca. 60 nm) exhibit remarkable CO2 permeance and CO2/N2 selectivity, demonstrating the great combined potential of MOP and Langmuir‐based techniques in separation technologies.
Fabrication of compact and dense porous metal–organic polyhedra (MOP) ultrathin films offers several advantages for the development of MOP‐based applications in gas separation. MOP‐supported membranes obtained by successive RhII‐based MOP monolayer deposition can be applied for efficient CO2 separation (see figure).</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>31692089</pmid><doi>10.1002/chem.201904141</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-3691-3437</orcidid><orcidid>https://orcid.org/0000-0001-6627-0079</orcidid><orcidid>https://orcid.org/0000-0002-8569-6208</orcidid><orcidid>https://orcid.org/0000-0003-1325-9161</orcidid><orcidid>https://orcid.org/0000-0003-2095-5843</orcidid><orcidid>https://orcid.org/0000-0003-1512-4500</orcidid><orcidid>https://orcid.org/0000-0002-3492-6456</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Atomic force microscopy Carbon dioxide Chemistry CO2 separation Electronics Gas separation Langmuir–Blodgett technique Membranes metal–organic polyhedra Microscopy Polyhedra scanning electron microscopy Scanning transmission electron microscopy Selectivity Substrates Thickness Thin films Transmission electron microscopy |
| title | Ultrathin Films of Porous Metal–Organic Polyhedra for Gas Separation |
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