Hydrazide‐Catalyzed Polyene Cyclization: Asymmetric Organocatalytic Synthesis of cis‐Decalins

Polyene cyclizations offer rapid entry into terpenoid ring systems. Although enantioselective cyclizations of (E)‐polyenes to form trans‐decalin ring systems are well precedented, highly enantioselective cyclizations of (Z)‐polyenes to form the corresponding cis‐decalins have not been reported. Here...

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Veröffentlicht in:	Angewandte Chemie International Edition 2020-01, Vol.59 (1), p.253-258
Hauptverfasser:	Plamondon, Samuel J., Warnica, Josephine M., Kaldre, Dainis, Gleason, James L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Antifungal agents asymmetric catalysis Catalysis Catalysts Chemical synthesis cis-decalin Decalin Enantiomers hydrazide Hydrazides Initiators organocatalysis polyene cyclization Polyenes Substrates
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