Ammonia nitrogen removal from aqueous solution using zeolite modified by microwave-sodium acetate

The characteristics of the zeolite modified by microwave and sodium acetate and its sorption of ammonia-nitrogen from simulated water sample were investigated. The results show that the modified zeolite by microwave-sodium acetate (SMMZ) has a high sorption efficiency and removal performance. The am...

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Veröffentlicht in:Journal of Central South University 2016-06, Vol.23 (6), p.1345-1352
1. Verfasser: 董颖博 林海
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description The characteristics of the zeolite modified by microwave and sodium acetate and its sorption of ammonia-nitrogen from simulated water sample were investigated. The results show that the modified zeolite by microwave-sodium acetate (SMMZ) has a high sorption efficiency and removal performance. The ammonia-nitrogen removal rate of SMMZ reaches 92.90%. The surface of SMMZ becomes loose and some pores appear, the specific surface area, total pore volume and average pore diameter increase after modification. Compared to the natural zeolite, SMMZ has a more concentrated pore size distribution in the range of 0?10 nm. The cation exchange capacity (CEC) of SMMZ is higher than that of the natural zeolite. And the ammonia nitrogen removal rate is consistent with the change of CEC. The SMMZ possesses rapid sorption and slow balance characteristics and ammonia-nitrogen sorption is consistent with both Langmuir adsorption isotherm model and Freundlich adsorption isotherm model. The adsorption kinetics of ammonia-nitrogen follows the pseudo-second order kinetic model.
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The results show that the modified zeolite by microwave-sodium acetate (SMMZ) has a high sorption efficiency and removal performance. The ammonia-nitrogen removal rate of SMMZ reaches 92.90%. The surface of SMMZ becomes loose and some pores appear, the specific surface area, total pore volume and average pore diameter increase after modification. Compared to the natural zeolite, SMMZ has a more concentrated pore size distribution in the range of 0?10 nm. The cation exchange capacity (CEC) of SMMZ is higher than that of the natural zeolite. And the ammonia nitrogen removal rate is consistent with the change of CEC. The SMMZ possesses rapid sorption and slow balance characteristics and ammonia-nitrogen sorption is consistent with both Langmuir adsorption isotherm model and Freundlich adsorption isotherm model. The adsorption kinetics of ammonia-nitrogen follows the pseudo-second order kinetic model.</description><identifier>ISSN: 2095-2899</identifier><identifier>EISSN: 2227-5223</identifier><identifier>DOI: 10.1007/s11771-016-3186-x</identifier><language>eng</language><publisher>Changsha: Central South University</publisher><subject>Chemical and Environmental Engineering ; Engineering ; Materials ; Metallic Materials ; Metallurgy ; 吸附性能 ; 微波 ; 改性沸石 ; 氨氮去除率 ; 水溶液 ; 等温吸附模型 ; 醋酸钠 ; 阳离子交换量</subject><ispartof>Journal of Central South University, 2016-06, Vol.23 (6), p.1345-1352</ispartof><rights>Central South University Press and Springer-Verlag Berlin Heidelberg 2016</rights><rights>Copyright © Wanfang Data Co. Ltd. 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Cent. South Univ</addtitle><addtitle>Journal of Central South University of Technology</addtitle><description>The characteristics of the zeolite modified by microwave and sodium acetate and its sorption of ammonia-nitrogen from simulated water sample were investigated. The results show that the modified zeolite by microwave-sodium acetate (SMMZ) has a high sorption efficiency and removal performance. The ammonia-nitrogen removal rate of SMMZ reaches 92.90%. The surface of SMMZ becomes loose and some pores appear, the specific surface area, total pore volume and average pore diameter increase after modification. Compared to the natural zeolite, SMMZ has a more concentrated pore size distribution in the range of 0?10 nm. The cation exchange capacity (CEC) of SMMZ is higher than that of the natural zeolite. And the ammonia nitrogen removal rate is consistent with the change of CEC. The SMMZ possesses rapid sorption and slow balance characteristics and ammonia-nitrogen sorption is consistent with both Langmuir adsorption isotherm model and Freundlich adsorption isotherm model. 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Cent. South Univ</stitle><addtitle>Journal of Central South University of Technology</addtitle><date>2016-06-01</date><risdate>2016</risdate><volume>23</volume><issue>6</issue><spage>1345</spage><epage>1352</epage><pages>1345-1352</pages><issn>2095-2899</issn><eissn>2227-5223</eissn><abstract>The characteristics of the zeolite modified by microwave and sodium acetate and its sorption of ammonia-nitrogen from simulated water sample were investigated. The results show that the modified zeolite by microwave-sodium acetate (SMMZ) has a high sorption efficiency and removal performance. The ammonia-nitrogen removal rate of SMMZ reaches 92.90%. The surface of SMMZ becomes loose and some pores appear, the specific surface area, total pore volume and average pore diameter increase after modification. Compared to the natural zeolite, SMMZ has a more concentrated pore size distribution in the range of 0?10 nm. The cation exchange capacity (CEC) of SMMZ is higher than that of the natural zeolite. And the ammonia nitrogen removal rate is consistent with the change of CEC. The SMMZ possesses rapid sorption and slow balance characteristics and ammonia-nitrogen sorption is consistent with both Langmuir adsorption isotherm model and Freundlich adsorption isotherm model. The adsorption kinetics of ammonia-nitrogen follows the pseudo-second order kinetic model.</abstract><cop>Changsha</cop><pub>Central South University</pub><doi>10.1007/s11771-016-3186-x</doi><tpages>8</tpages></addata></record>
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subjects Chemical and Environmental Engineering
Engineering
Materials
Metallic Materials
Metallurgy
吸附性能
微波
改性沸石
氨氮去除率
水溶液
等温吸附模型
醋酸钠
阳离子交换量
title Ammonia nitrogen removal from aqueous solution using zeolite modified by microwave-sodium acetate
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