化学沉积Ni?P/Ni?Mo?P镀层的残余应力和腐蚀行为评价
通过化学沉积法制备Ni?P、Ni?Mo?P单镀层以及与其成分相同的Ni?P/Ni?Mo?P双镀层.采用纳米压痕法和AFM分析测量镀层表面和截面的残余应力,并用电化学法评估镀层在10％HCl溶液中的腐蚀行为,以获得镀层残余应力与腐蚀行为之间的关系.结果表明:Ni?P单镀层和Ni?P/Ni?Mo?P双镀层表现为残余压应力,分别为241和206 MPa;Ni?Mo?P单镀层呈现出257 MPa的残余拉应力.残余压应力阻止镀层中孔洞的生长,保护镀层的完整性.Ni?P/Ni?Mo?P双镀层比它们的单镀层具有更好的耐蚀性.此外,镀层的应力状态影响其腐蚀形式....
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| Veröffentlicht in: | 中国有色金属学报（英文版） 2018, Vol.28 (12), p.2499-2510 |
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| container_title | 中国有色金属学报（英文版） |
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| creator | 刘宏 钱代数 |
| description | 通过化学沉积法制备Ni?P、Ni?Mo?P单镀层以及与其成分相同的Ni?P/Ni?Mo?P双镀层.采用纳米压痕法和AFM分析测量镀层表面和截面的残余应力,并用电化学法评估镀层在10％HCl溶液中的腐蚀行为,以获得镀层残余应力与腐蚀行为之间的关系.结果表明:Ni?P单镀层和Ni?P/Ni?Mo?P双镀层表现为残余压应力,分别为241和206 MPa;Ni?Mo?P单镀层呈现出257 MPa的残余拉应力.残余压应力阻止镀层中孔洞的生长,保护镀层的完整性.Ni?P/Ni?Mo?P双镀层比它们的单镀层具有更好的耐蚀性.此外,镀层的应力状态影响其腐蚀形式. |
| doi_str_mv | 10.1016/S1003-6326(18)64896-4 |
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| title | 化学沉积Ni?P/Ni?Mo?P镀层的残余应力和腐蚀行为评价 |
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