Phase selection of ternary intermetallic compounds during solidification of high zinc magnesium alloy

The phase selection of ternary intermetallic compound τ phase (Mg 32(Al, Zn) 49) and Φ phase (Al 2Mg 5Zn 2) in high zinc magnesium alloys was studied by using scanning electron microscope, X-ray diffractometer and differential scanning calorimeter, etc. The results indicate that, when adding element...

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Veröffentlicht in:Transactions of Nonferrous Metals Society of China 2008-06, Vol.18 (3), p.593-597
Hauptverfasser: GUAN, Shao-kang, ZHANG, Chun-xiang, WANG, Li-guo, WU, Li-hong, CHEN, Pei-lei, TANG, Ya-li
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container_title Transactions of Nonferrous Metals Society of China
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creator GUAN, Shao-kang
ZHANG, Chun-xiang
WANG, Li-guo
WU, Li-hong
CHEN, Pei-lei
TANG, Ya-li
description The phase selection of ternary intermetallic compound τ phase (Mg 32(Al, Zn) 49) and Φ phase (Al 2Mg 5Zn 2) in high zinc magnesium alloys was studied by using scanning electron microscope, X-ray diffractometer and differential scanning calorimeter, etc. The results indicate that, when adding element Si in Mg-8Zn-4Al-0.3Mn (ZA84) alloy, Φ phase is promoted, whereas τ phase is inhibited. The Chinese script-type Mg 2Si and matrix microstructure are greatly refined, the formation of τ phase is facilitated and Φ phase is restrained when modifier Al-AlP master alloy is added in ZA84 alloy containing Si. The kinetics study of phase selection indicates that there is a critical degree of undercooling of the melt. If the undercooling exceeds the critical value, τ phase preferentially forms while Φ phase is restrained; otherwise, Φ phase preferentially forms while τ phase is restrained.
doi_str_mv 10.1016/S1003-6326(08)60103-X
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subjects AlP
high-zinc magnesium alloy
kinetics
phase selection
title Phase selection of ternary intermetallic compounds during solidification of high zinc magnesium alloy
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